Electrochemical oxidation of aromatic aldehydes in acidic media
Methods for electrochemically oxidizing aromatic aldehydes, such as furfural and furfural derivatives, to carboxylic acids in acidic solutions are provided. Also provided are electrochemical cells for carrying out the oxidation reactions. The electrochemical oxidations may be conducted in aqueous media at ambient pressure and mild temperatures.
1. A method for the electrochemical oxidation of furfural in an electrochemical cell comprising: an anode comprising manganese oxide in an anode electrolyte solution; and a cathode in a cathode electrolyte solution, wherein the anode electrolyte solution comprises the furfural and has a pH lower than 7, the method comprising: applying an anode potential to the anode that induces the electrochemical oxidation of the furfural to maleic acid.
2. The method of claim 1 , wherein the maleic acid is formed with a product yield of at least 20%.
3. The method of claim 1 , wherein the maleic acid is formed with a product yield of at least 30%.
4. The method of claim 1 , wherein the maleic acid is formed with a product yield in the range from 20% to 40%.