Boron carbide bilayer foam solar evaporator and method for preparing thereof
The present invention provides a solar absorber incorporated bilayer foam solar evaporator for seawater and wastewater purification including a plurality of solar absorbers partially incorporated into a porous polymer framework and partially forming a thermal insulation layer proximal to solar irradiation. In particular, low-cost commercially available B 4 C powders are embedded into a porous polymer foam in a one-pot method to form a scaffold of boron carbide bilayer foam (BCBF) with good hydrophilic wettability, heat-shielding, and solar-thermal conversion. The boron carbide bilayer foam (BCBF) of the present invention enables a high cost-performance seawater desalination and wastewater purification at a high evaporation rate of 2.8 kg/m 2 /h with 93% solar evaporation efficiency under 1 sun illumination (or 1 kW/m 2 ). The present invention thereby provides an excellent and cost-effective solar evaporator tool for industrial-level water purification. Following the present method to prepare the BCBF solar evaporator, the fabrication cost can be as low as 3.6 $/m 2 .
1. A method for preparing a scaffold of a solar absorber incorporated bilayer foam for seawater desalination and wastewater purification, the method comprising:
dissolving a plurality of solar absorbers into a solvent thoroughly;
mixing the plurality of solar absorbers dissolved in solvent with one or more polymers vigorously to form a gelation formation mixture;
adding the gelation formation mixture into a solution of hydrochloric acid and glutaraldehyde dropwisely to have an in-situ gelation to form a hydrogel;
settling the hydrogel at a low temperature;
freeze-drying the hydrogel until an aerogel is obtained which is the scaffold of the solar absorber incorporated bilayer foam.
2. The method of claim 1 , wherein said mixing the plurality of solar absorbers dissolved in solvent with the one or more polymers vigorously is by sonication for about 1 to 60 minutes until the gelation formation mixture is formed.
3. The method of claim 1 , wherein said adding the gelation formation mixture into the solution of hydrochloric acid and glutaraldehyde dropwisely comprises mild stirring during said adding for about 0.5 to 6 hours until the hydrogel is formed.
4. The method of claim 1 , wherein said settling the hydrogel is carried out by immersing the hydrogel in water for overnight at about 5 to −30 degrees Celsius.
5. The method of claim 1 , wherein the plurality of solar absorbers is selected from boron carbide.
6. The method of claim 1 , wherein the one or more polymers comprise polyvinyl alcohol (PVA), polydimethylsiloxane (PDMS), polyurethane (PU) and melamine.
7. The method of claim 5 , wherein boron carbide dissolved into the solvent is mixed with the one or more polymers in a weight ratio of 1:2-19, and wherein the one or more polymers is selected from polyvinyl alcohol.
8. The method of claim 7 , wherein boron carbide at more than 0 to about 50% w/w with respect to polyvinyl alcohol is dissolved in the solvent.
9. The method of claim 8 , wherein the solvent is an organic solvent selected from ethanol, methanol, acetone, or tetrahydrofuran.