Translucent and transparent separators
Provided herein are detect-free solid-state separators which are useful as Li | ion-conducting electrolytes in electro-chemical cells and devices, such as, but not limited to, rechargeable batteries. In some examples, the separators have a Li + ion-conductivity greater than 1*10 −3 S/cm at room temperature.
1. A Li + ion-conducting separator,
wherein the separator:
is polycrystalline;
has a thickness from 10 nm to 1 mm;
comprises grains having a d 90 grain size ranges from 0.1 to 20 μm; and
has a 10% total reflectance for light wavelengths for 400 nm to 700 nm.
2. The Li + ion-conducting separator of claim 1 , wherein less than 10% of the total reflectance is diffuse reflectance and the remainder of the total reflectance is specular reflectance.
3. The Li + ion-conducting separator of claim 1 , wherein the separator has a surface roughness (Ra) less than 5 μm.
4. The Li + ion-conducting separator of claim 1 , wherein the separator has a transmission coefficient greater than 0.5 for incident light at wavelengths in the range 300-700 nm.
5. The Li + ion-conducting separator of claim 1 , wherein the separator has a transmission percentage greater than 50% for incident light at 500 nm wavelength.
6. The Li + ion-conducting separator of claim 1 , wherein the separator is selected from an oxide, a sulfide, a sulfide-halide, LIRAP, and a borohydride.
7. The Li + ion-conducting separator of claim 6 , wherein the separator is an oxide selected from a lithium-stuffed garnet characterized by the formula Li x La y Zr z O t ·qAl 2 O 3 , wherein 4<x<10, 1<y<4, 1<z<3, 6<t<14, 0≤q≤1.
8. The Li + ion-conducting separator of claim 7 , wherein the lithium-stuffed garnet is doped with Nb, Ga, and/or Ta.
9. The Li + ion-conducting separator of claim 7 , wherein the lithium-stuffed garnet is Li a La b Zr c Al d Me″ c O f , wherein 5<a<8.5; 2<b<4; 0<c≤2.5; 0≤d<2; 0≤e<2, and 10<f<13 and Me″ is a metal selected from Nb, Ga, Ta, or combinations thereof.
10. The Li + ion-conducting separator of claim 7 , wherein the lithium-stuffed garnet is characterized by the formula Li x La y Zr z O t ·0.11 (Al 2 O 3 ), Li x La y Zr z O t ·0.22(Al 2 O 3 ), Li x La y Zr z O t ·0.35(Al 2 O 3 ), Li x La y Zr z O t ·0.5(Al 2 O 3 ), Li x La y Zr z O t ·0.65(Al 2 O 3 ), Li x La y Zr z O t ·0.75(Al 2 O 3 ), or Li x La y Zr z O t ·(Al 2 O 3 ), wherein 5<x<8.5.
11. The Li + ion-conducting separator of claim 1 , wherein the separator comprises:
a lithium-stuffed garnet oxide characterized by the formula Li u La v Zr x O y ·zAl 2 O 3 , wherein
u is a rational number from 4 to 8;
v is a rational number from 2 to 4;
x is a rational number from 1 to 3;
y is a rational number from 10 to 14; and
z is a rational number from 0.05 to 1;
wherein u, v, x, y, and z are selected so that the lithium-stuffed garnet oxide is charge neutral.
12. The Li + ion-conducting separator of claim 1 , wherein the separator has a transmission percentage that varies by less than +10% over an area of at least 0.5 cm 2 .
13. The Li + ion-conducting separator of claim 1 , wherein the separator is transparent over an area of at least 1 cm 2 .
14. The Li + ion-conducting separator of claim 1 , wherein the separator is translucent over an area of at least 64×mm 2 .
15. The Li + ion-conducting separator of claim 1 , having a defect density less than 1/m 2 to 1/mm 2 .
16. The Li + ion-conducting separator of claim 1 , having a scattering center density that ranges from less than 1/m 2 to 1/mm 2 .
17. The Li + ion-conducting separator of claim 1 , having a geometric porosity that ranges from 10 parts-per-billion to 6%.
18. The Li + ion-conducting separator of claim 1 , having an Archimedes porosity that ranges from 10 parts-per-billion to 6%.
19. The Li + ion-conducting separator of claim 1 , wherein the lithium ion conductivity is greater than 10-4S/cm at 25° C.
20. The Li + ion-conducting separator of claim 1 , wherein the lithium interfacial area-specific resistance is less than 20 Ωcm 2 at 25° C.
21. An electrochemical cell comprising a Li + ion-conducting separator of claim 1 .
22. The electrochemical cell of claim 21 , wherein the electrochemical cell is a rechargeable battery.