Metal product, method for manufacturing the metal product, and metal composite
A metal product includes a metal substrate, at least one first hole, at least one second hole, and at least one third hole. The first hole is formed in a surface of the metal substrate. The second hole is formed in at least one of a portion of the surface of the metal substrate without the first hole and an inner surface defining the first hole. The third hole is formed in at least one of a portion of the surface of the metal substrate without the first hole and without the second hole, a portion of the inner surface defining the first hole without the second hole, and an inner surface defining the second hole. The first, second, and third holes enhance a bonding strength between the metal product and a material product. The disclosure also provides a metal composite and a method for manufacturing the metal product.
1. A metal product, comprising:
a metal substrate;
at least one first hole defined in a surface of the metal substrate and formed by chemical corrosion or electrochemical electrolysis;
a plurality of second holes defined in a portion of the surface of the metal substrate without the first hole and an inner surface defining the at least one first hole, wherein the plurality of second holes are formed by surrounding a plurality of protrusions, the plurality of protrusions are located on at least one of the portion of the surface of the metal substrate without the at least one first hole and the inner surface defining the at least one first hole, the plurality of protrusions are formed by glancing angle physical vapor deposition; and
a plurality of third holes formed by an anodic oxidation treatment and defined in a portion of the surface of the metal substrate without the at least one first hole and without the plurality of second holes, a portion of the inner surface defining the at least one first hole without the plurality of second holes, and an inner surface defining the plurality of second holes.
2. The metal product of claim 1 , wherein the plurality of third holes are formed in a surface of the plurality of protrusions, and a surface of the metal substrate exposed from the plurality of protrusions.
3. The metal product of claim 2 , wherein a material of the inner surface defining the at least one first hole and exposed from the plurality of protrusions comprises oxide.
4. The metal product of claim 1 , wherein a diameter of each of the at least one first hole is R 1 , and 50 μm≤R 1 ≤150 μm.
5. The metal product of claim 1 , wherein a diameter of each of the plurality of second holes is R 2 , and 100 nm≤R 2 ≤5000 nm.
6. The metal product of claim 1 , wherein a diameter of each of the plurality of third holes is R 3 , and 20 nm≤R 3 ≤70 nm.
7. The metal product of claim 1 , wherein the metal substrate comprises a sponge-like structure formed by the plurality of second holes and the inner surface defining the plurality of second holes.
8. The metal product of claim 1 , wherein each of the plurality of second holes comprises an opening, directions of openings of the plurality of second holes are different from each other.
9. The metal product of claim 1 , wherein shapes of the plurality of second holes are different from each other.
10. The metal product of claim 1 , wherein each of the plurality of third holes comprises an opening, directions of the openings of the plurality of third holes are different from each other.
11. A metal composite, comprising:
a metal product of claim 1 ; and
a material product formed on the metal product;
wherein the material product comprises a combining portion arranged in the at least one first hole, the plurality of second holes, and the plurality of third holes to be combined with the metal product.
12. The metal composite of claim 11 , wherein the material product is made of a material selected form a group consisting of plastic, metal, ceramic, glass, oxide, and any combination thereof.
13. The metal composite of claim 12 , wherein the combining portion comprises at least one first part embedded into the at least one first hole, at least one second part diverging from the at least one first part, and at least one third part diverging from the at least one first part and the at least one second part; the at least one second part is embedded into the plurality of second holes, the at least one third part is embedded into the plurality of third holes.
14. The metal composite of claim 12 , wherein the combining portion comprises a main body and at least one branch structure diverging from the main body.
15. The metal composite of claim 14 , wherein the combining portion comprises a plurality of branch structures, shapes of the plurality of branch structures are different from each other.
16. The metal composite of claim 15 , wherein the combining portion comprises a plurality of branch structures, divergence directions of the plurality of branch structures are different from each other.