Sm—Fe—N-based magnet powder, Sm—Fe—N-based sintered magnet, and production method therefor
A Sm—Fe—N-based magnet powder that includes a Sm—Fe—N-based magnetic material powder, wherein an average particle size of the Sm—Fe—N-based magnetic material powder is not larger than 5 μm, and a full width at half maximum of a diffraction peak of a (220) plane in an X-ray diffraction profile of the Sm—Fe—N-based magnetic material powder is not larger than 0.0033 Å. Also disclosed is a Sm—Fe—N-based sintered magnet that includes a sintered body of a Sm—Fe—N-based magnetic material, wherein an average grain size of crystal grains of the Sm—Fe—N-based magnetic material is not larger than 5 μm, and a full width at half maximum of a diffraction peak of a (220) plane in an X-ray diffraction profile of the Sm—Fe—N-based magnetic material is not larger than 0.0033 Å.
1. A Sm—Fe—N-based magnet powder, comprising:
a Sm—Fe—N-based magnetic material powder, wherein
an average particle size of the Sm—Fe—N-based magnetic material powder is not larger than 5 μm,
the particle size of the Sm—Fe—N-based magnetic material powder is 0.04 μm or more, and
a full width at half maximum of a diffraction peak of a (220) plane in an X-ray diffraction profile of the Sm—Fe—N-based magnetic material powder is not larger than 0.0033 Å.
2. The Sm—Fe—N-based magnet powder according to claim 1 , wherein the average particle size of the Sm—Fe—N-based magnetic material powder is not larger than 3 μm.
3. The Sm—Fe—N-based magnet powder according to claim 1 , wherein the Sm—Fe—N-based magnetic powder is Sm 2 Fe 17 N 3 .
4. The Sm—Fe—N-based magnet powder according to claim 1 , wherein the full width at half maximum of the diffraction peak of the (220) plane in the X-ray diffraction profile of the Sm—Fe—N-based magnetic material powder is 0.0001 Å to 0.0033 Å.
5. The Sm—Fe—N-based magnet powder according to claim 1 , wherein the Sm—Fe—N-based magnetic material powder has an oxygen content ratio of not larger than 0.7% by mass.
6. A Sm—Fe—N-based sintered magnet, comprising:
a sintered body of a Sm—Fe—N-based magnetic material, wherein
an average grain size of crystal grains of the Sm—Fe—N-based magnetic material is not larger than 5 μm,
the grain size of the crystal grains of the Sm—Fe—N-based magnetic material powder is 0.04 μm or more, and
a full width at half maximum of a diffraction peak of a (220) plane in an X-ray diffraction profile of the Sm—Fe—N-based magnetic material is not larger than 0.0033 Å.
7. The Sm—Fe—N-based sintered magnet according to claim 6 , wherein the full width at half maximum of the diffraction peak of the (220) plane in the X-ray diffraction profile of the Sm—Fe—N-based magnetic material is not larger than 0.0026 Å.
8. The Sm—Fe—N-based sintered magnet according to claim 6 , wherein an oxygen content ratio of the Sm—Fe—N-based magnetic material is not larger than 0.7% by mass.
9. The Sm—Fe—N-based sintered magnet according to claim 6 , wherein the average particle size of the Sm—Fe—N-based magnetic material is not larger than 3 μm.
10. A method for producing a Sm—Fe—N-based sintered magnet, the method comprising:
pressure-sintering a Sm—Fe—N-based magnetic material powder under an atmosphere of an oxygen concentration not larger than 10 ppm, wherein
an average particle size of the Sm—Fe—N-based magnetic material powder is not larger than 5 μm,
the particle size of the Sm—Fe—N-based magnetic material powder is 0.04 μm or more, and
a full width at half maximum of a diffraction peak of a (220) plane in an X-ray diffraction profile of the Sm—Fe—N-based magnetic material powder is not larger than 0.0033 Å.
11. The method for producing the Sm—Fe—N-based sintered magnet according to claim 10 , further comprising subjecting the Sm—Fe—N-based magnetic material powder to a magnetic field before the pressure-sintering.
12. The method for producing the Sm—Fe—N-based sintered magnet according to claim 11 , wherein the magnetic field is a static magnetic field of 2 T or more.
13. The method for producing the Sm—Fe—N-based sintered magnet according to claim 10 , wherein a pressure of the pressure-sintering is 600 MPa to 1.5 GPa.
14. The method for producing the Sm—Fe—N-based sintered magnet according to claim 10 , wherein a temperature of the pressure-sintering is 400° C. to 600° C.
15. The method for producing the Sm—Fe—N-based sintered magnet according to claim 14 , wherein a time of the pressure-sintering is 30 seconds to 10 minutes.
16. The method for producing the Sm—Fe—N-based sintered magnet according to claim 10 , wherein the average particle size of the Sm—Fe—N-based magnetic material powder is not larger than 3 μm.