Iron-based nanoparticles and grains
Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.
1. A nanoparticle comprising:
an iron-based core, wherein the iron-based core comprises elemental iron and a″-Fe 16 N 2 ; and
a shell, wherein the shell comprises an anti-ferromagnetic material, wherein the shell has a thickness of about 10 nm;
wherein the nanoparticle has a coercivity of at least about 600 Oe.
2. The nanoparticle of claim 1 , wherein the shell comprises at least one of manganese nitride or ferromanganese.
3. The nanoparticle of claim 1 , wherein the core has a major dimension between about 20 nm and about 100 nm.
4. The nanoparticle of claim 1 , wherein the core is an ellipsoid with a ratio of a maximum diameter to a minimum diameter of at least about 2.
5. A bulk magnetic material comprising a plurality of the nanoparticles of claim 1 .
6. The nanoparticle of claim 1 , formed by depositing a shell on an iron-based core to form a core-shell nanoparticle by at least milling the iron-based core with a salt composition for a predetermined period of time; wherein the salt composition comprises at least one of precursors of silica, aluminum oxide, silicon nitride, aluminum nitride, manganese nitride, zinc oxide, iron oxide, ferromanganese, Fe 4 N, and Fe 16 N 2 .
7. The nanoparticle of claim 6 , wherein the salt composition comprises at least one of a solid, a slurry, a paste, a suspension, a liquid, a solution, a polymer, or a gel.
8. The nanoparticle of claim 6 , wherein the nanoparticle is formed by a method further comprising, after depositing the shell:
filtering the core-shell nanoparticle from the salt composition, and
drying the core-shell nanoparticle.
9. The nanoparticle of claim 6 , wherein the nanoparticle is formed by a method further comprising, after depositing the shell, nitriding the core-shell nanoparticle.
10. The nanoparticle of claim 9 , wherein nitriding the core-shell nanoparticle comprises autoclaving the core-shell nanoparticle at a predetermined pressure, at a predetermined temperature, for a predetermined period of time, in a nitrogen-rich environment, wherein the predetermined pressure is greater than 100 atmospheres.
11. The nanoparticle of claim 10 , wherein the nitrogen-rich environment is generated by a nitrogen source comprising at least one of ammonia, ammonium nitrate, an amide-containing material, or a hydrazine-containing material.
12. The nanoparticle of claim 6 , wherein the nanoparticle is formed by a method further comprising, after depositing the shell, annealing the core-shell nanoparticle in the presence of an applied magnetic field, wherein the annealing the core-shell nanoparticle in the presence of an applied magnetic field comprises exposing the core-shell nanoparticle to a magnetic field having a predetermined strength at a predetermined temperature for a predetermined period of time.