Electrochemical cells and/or components thereof comprising nitrogen-containing species, and methods of forming them
Articles and methods related to electrochemical cells and/or electrochemical cell components (such as electrodes) comprising species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or reaction products of such species are generally provided. The electrochemical cell may comprise an electrode (e.g., a cathode) comprising a protective layer comprising a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof.
1. An electrochemical cell, comprising:
a first electrode;
a second electrode; and
a protective layer disposed on the second electrode, wherein the protective layer disposed on the second electrode comprises a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof, and wherein the species comprises an additional nitrogen atom.
2. The electrochemical cell of claim 1 , further comprising a protective layer disposed on the first electrode, wherein the protective layer disposed on the first electrode comprises the species and/or a reaction product thereof.
3. The electrochemical cell of claim 1 , wherein the species comprises substituted or unsubstituted 1,2,4-triazole, 1,2,3-triazole, 1,3,4-triazole, pyrazole, imidazole, tetrazole, benzimidazole, indazole, and/or benzotriazole.
4. The electrochemical cell of claim 1 , wherein the second electrode comprises a transition metal.
5. The electrochemical cell of claim 4 , wherein the protective layer comprises the reaction product, and the reaction product comprises a reaction product between the transition metal and the species.
6. The electrochemical cell of claim 1 , wherein an electron withdrawing substituent is absent from the species.
7. The electrochemical cell of claim 1 , wherein:
(a) the reaction product comprises a reaction product between the species and a second species, wherein the second species comprises a labile halogen atom; and/or
(b) the second electrode comprise a transition metal, and the reaction product comprises a reaction product between the species, the transition metal, and the second species.
8. The electrochemical cell of claim 1 , wherein the first electrode comprises lithium metal.
9. An electrochemical cell, comprising:
a first electrode comprising lithium metal; and
a protective layer disposed on the first electrode, wherein the protective layer disposed on the first electrode comprises a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom and/or a reaction product thereof, wherein an electron-withdrawing substituent is absent from the species, and wherein the species comprises an additional nitrogen atom.
10. The electrochemical cell of claim 9 , wherein the species comprises substituted or unsubstituted 1,2,4-triazole, 1,2,3-triazole, 1,3,4-triazole, pyrazole, imidazole, tetrazole, benzimidazole, indazole, and/or benzotriazole.
11. The electrochemical cell of claim 9 , further comprising an electrolyte, wherein the electrolyte comprises the species.
12. The electrochemical cell of claim 9 , wherein the protective layer comprises the reaction product, and wherein the reaction product comprises a reaction product between lithium metal and the species.
13. The electrochemical cell of claim 9 , further comprising a second electrode, wherein a second protective layer is disposed on the second electrode, and wherein the second protective layer comprises the species and/or a second reaction product thereof.
14. The electrochemical cell of claim 13 , wherein the second electrode comprises a transition metal, wherein the second protective layer comprises the second reaction product, and wherein the second reaction product comprises a reaction product between the transition metal and the species.
15. A method, comprising:
exposing an electrode to a preliminary solution comprising a transition metal;
exposing the electrode to a solution comprising a species comprising a conjugated, negatively-charged ring comprising a nitrogen atom; and
forming a protective layer disposed on the electrode, wherein the protective layer comprises the species and/or a reaction product thereof.
16. The method of claim 15 , wherein the preliminary solution comprises greater than or equal to 0.5 wt. % and less than or equal to 10 wt. % of a transition metal salt.
17. The method of claim 16 , wherein the preliminary solution comprises greater than or equal to 3 wt. % and less than or equal to 5 wt. % of the transition metal salt.
18. The method of claim 15 , wherein the protective layer comprises the species.
19. The method of claim 15 , wherein the solution further comprises a second species comprising a labile halogen atom.
20. The method of claim 19 , wherein the solution comprises greater than or equal to 5 wt % and less than or equal to 50 wt. % of the second species.