IP Library › Granted Patent US 12,136,703
Granted Patent B2
US 12,136,703 · App. 17/497,136 · Granted Nov 5, 2024

Lithium-ion secondary battery

Inventors: Takumi Hiasa (Kyoto, JP); Kazunari Motohashi (Kyoto, JP)
Assignee: Murata Manufacturing Co., Ltd.
H01M10/0568H01M4/362H01M10/0525H01M10/0563H01M2004/028
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,136,703
App. No.
17/497,136
Granted
Nov 5, 2024
Kind
B2
Abstract

A lithium-ion secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode includes a positive electrode active material. The electrolytic solution includes a cyclic sulfuric acid ester compound, a cyclic ether compound, and a chain alkyl dinitrile compound. A ratio of a weight (mg) of the cyclic sulfuric acid ester compound to a weight (g) of the positive electrode active material is from 0.01 to 2.

Claims (42)

1. A lithium-ion secondary battery comprising:

a positive electrode that includes a positive electrode active material;

a negative electrode; and

an electrolytic solution that includes a cyclic sulfuric acid ester compound represented by Formula (1), a cyclic ether compound represented by Formula (2), and a chain alkyl dinitrile compound represented by Formula (3),

wherein a ratio of a weight in milligrams of the cyclic sulfuric acid ester compound to a weight in grams of the positive electrode active material is from 0.01 to 2,

wherein

each of R1 to R6 represents one of a hydrogen group and a monovalent hydrocarbon group, and

n1 is an integer of 0 or greater,

wherein

each of R7 to R12 represents one of a hydrogen group and a monovalent hydrocarbon group, and

each of n2 and n3 is an integer of 1 or greater, and

wherein

each of R13 to R16 represents one of a hydrogen group and a monovalent hydrocarbon group, and

n4 is an integer of 0 or greater.

2. The lithium-ion secondary battery according to claim 1 , wherein a ratio of a weight in milligrams of the cyclic ether compound to the weight in milligrams of the cyclic sulfuric acid ester compound is from 0.2 to 5.

3. The lithium-ion secondary battery according to claim 1 , wherein a content of the chain alkyl dinitrile compound in the electrolytic solution is from 0.1 weight percent to 5 weight percent.

4. The lithium-ion secondary battery according to claim 2 , wherein a content of the chain alkyl dinitrile compound in the electrolytic solution is from 0.1 weight percent to 5 weight percent.

5. The lithium-ion secondary battery according to claim 1 , wherein

n1 in Formula (1) is 2 or less,

each of n2 and n3 in Formula (2) is 2 or less, and

n4 in Formula (3) is 7 or less.

6. The lithium-ion secondary battery according to claim 2 , wherein

n1 in Formula (1) is 2 or less,

each of n2 and n3 in Formula (2) is 2 or less, and

n4 in Formula (3) is 7 or less.

7. The lithium-ion secondary battery according to claim 3 , wherein

n1 in Formula (1) is 2 or less,

each of n2 and n3 in Formula (2) is 2 or less, and

n4 in Formula (3) is 7 or less.

8. The lithium-ion secondary battery according to claim 1 , wherein the positive electrode active material includes

a center part that includes a lithium composite oxide, and

a covering part that covers at least a portion of a surface of the center part and that includes a compound having a composition different from the lithium composite oxide.

9. The lithium-ion secondary battery according to claim 2 , wherein the positive electrode active material includes

a center part that includes a lithium composite oxide, and

a covering part that covers at least a portion of a surface of the center part and that includes a compound having a composition different from the lithium composite oxide.

10. The lithium-ion secondary battery according to claim 3 , wherein the positive electrode active material includes

a center part that includes a lithium composite oxide, and

a covering part that covers at least a portion of a surface of the center part and that includes a compound having a composition different from the lithium composite oxide.

11. The lithium-ion secondary battery according to claim 5 , wherein the positive electrode active material includes

a center part that includes a lithium composite oxide, and

a covering part that covers at least a portion of a surface of the center part and that includes a compound having a composition different from the lithium composite oxide.

12. The lithium-ion secondary battery according to claim 8 , wherein the compound having the composition different from the lithium composite oxide includes at least one of (1) another lithium composite oxide having a composition that is different from the lithium composite oxide; a lithium phosphoric acid compound; a metallic phosphoric acid salt; a halide; or a chalcogenide other than an oxide.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 8, 2021
From: HIASA, TAKUMI; MOTOHASHI, KAZUNARI
To: MURATA MANUFACTURING CO., LTD.
Reel/Frame 057742/0429 →
Priority Claims (1)
JP 2019-074934 · Apr 10, 2019 · national
Continuity (2)
Continuation PCTJP2020015608 · Apr 7, 2020
Related Publication 20220029201A1 · Jan 27, 2022