Laundry care additive particles
Laundry care additive particles and a dryer sheet that include a water soluble carrier and capsules characterized by substantially inorganic shells, for example silica-based shells. The present disclosure further relates to methods of making and using such compositions.
1. A composition comprising a plurality of individual particles, wherein said individual particles comprise:
about 25% to about 99% by weight water soluble carrier; and
a plurality of capsules dispersed in said water soluble carrier, wherein said capsules comprise a core and a shell surrounding said core and said core comprises perfume raw materials;
wherein said shell comprises from about 90% to 100% by weight of said shell of an inorganic material.
2. The composition according to claim 1 , wherein said inorganic material is selected from metal oxide, semi-metal oxides, metals, minerals, and mixtures thereof.
3. The composition according to claim 1 , wherein said shell comprises a first shell component comprising a condensed layer and a nanoparticle layer, wherein said condensed layer comprises a condensation product of a precursor, and wherein said nanoparticle layer comprises inorganic nanoparticles, and wherein said condensed layer is disposed between said core and said nanoparticle layer, and a second shell component surrounding said first shell component, wherein said second shell component surrounds said nanoparticle layer.
4. The composition according to claim 1 , wherein said capsules are characterized by one or more of the following:
a mean volume weighted capsule diameter of 10 μm to 200 μm;
an average shell thickness of 170 nm to 1000 nm;
a volumetric core-shell ratio of from about 50:50 to 99:1; and
the first shell component comprises no more than 5 wt % of organic content, by weight of the first shell component.
5. The composition according to claim 1 , wherein said shell comprises:
a substantially inorganic first shell component comprising a condensed layer and a nanoparticle layer,
wherein said condensed layer comprises a condensation product of a precursor,
wherein said nanoparticle layer comprises inorganic nanoparticles, and
wherein said condensed layer is disposed between said core and said nanoparticle layer; and
an inorganic second shell component surrounding said first shell component,
wherein said second shell component surrounds said nanoparticle layer;
wherein said precursor comprises at least one compound selected from Formula (I), Formula (II), and a mixture thereof;
wherein Formula (I) is (M v O z Y n ) w ;
wherein Formula (II) is (M v O z Y n R 1 p ) w ;
wherein for Formula (I), Formula (II), or the mixture thereof, each M is independently selected from silicon, titanium, and aluminum, v is the valence number of M and is 3 or 4, z is from 0.5 to 1.6, each Y is independently selected from —OH, —OR 2 , halogen,
NH 2 , —NHR 2 , —N(R 2 ) 2 , and
wherein R 2 is a C 1 to C 20 alkyl, C 1 to C 20 alkylene, C 6 to C 22 aryl, or a 5-12 membered heteroaryl,
wherein said heteroaryl comprises from 1 to 3 ring heteroatoms selected from O, N, and S,
wherein R 3 is a H, C 1 to C 20 alkyl, C 1 to C 20 alkylene, C 6 to C 22 aryl, or a 5-12 membered heteroaryl,
wherein said heteroaryl comprises from 1 to 3 ring heteroatoms selected from O, N, and S, w is from 2 to 2000;
wherein for Formula (I) n is from 0.7 to (v−1); and
wherein for Formula (II) n is from 0 to (v−1), each R 1 is independently selected from a C 1 to C 30 alkyl, a C 1 to C 30 alkylene, a C 1 to C 30 alkyl substituted with one or more of a halogen, —OCF 3 , —NO 2 , —CN, —NC, —OH, —OCN, —NCO, alkoxy, epoxy, amino, mercapto, acryloyl, CO 2 H, CO 2 alkyl, aryl, and heteroaryl, and a C 1 to C 30 alkylene substituted with one or more of a halogen, —OCF 3 , —NO 2 , —CN, —NC, —OH, —OCN, —NCO, alkoxy, epoxy, amino, mercapto, acryloyl, CO 2 H, CO 2 alkyl, aryl, and heteroaryl, and p is a positive number up to pmax,
wherein pmax=60/[9*Mw(R 1 )+8], wherein Mw(R 1 ) is the molecular weight of the R 1 group.
6. The composition according to claim 5 , wherein said precursor comprises at least one compound according to Formula (I).
7. The composition according to claim 6 , wherein said precursor is free of compounds according to Formula (II).
8. The composition according to claim 5 , wherein said precursor comprises at least one compound according to Formula (II).
9. The composition according to claim 5 , wherein the compounds of Formula (I), Formula (II), or both are characterized by one or more of the following:
a Polystyrene equivalent Weight Average Molecular Weight (Mw) of from about 700 Da to about 30,000 Da;
a degree of branching of 0.2 to about 0.6; and
a molecular weight polydispersity index of about 1 to about 20.
10. The composition according to claim 5 , wherein M is silicon.
11. The composition according to claim 5 , wherein for Formula (I), Formula (II), or both Formula (I) and Formula (II), Y is OR, wherein R is selected from a methyl group, an ethyl group, a propyl group, and a butyl group.
12. The composition according to claim 5 , wherein said second shell component comprises a material selected from calcium carbonate, silica, and a combination thereof.
13. The composition according to claim 5 , wherein said inorganic nanoparticles of said first shell component comprise at least one of metal nanoparticles, mineral nanoparticles, metal-oxide nanoparticles or semi-metal oxide nanoparticles.
14. The composition according to claim 5 , wherein said inorganic second shell component comprises at least one of SiO 2 , TiO 2 , Al 2 O 3 , CaCO 3 , Ca 2 SiO 4 , Fe 2 O 3 , Fe 3 O 4 , iron, silver, nickel, gold, copper, or clay.
15. The composition according to claim 1 , wherein said water soluble carrier is a water soluble polymer.
16. The composition according to claim 1 , wherein said water soluble carrier is selected from polyalkylene oxide, polyethylene glycol, sodium acetate, sodium bicarbonate, sodium chloride, sodium silicate, polypropylene glycol polyoxoalkylene, polyethylene glycol fatty acid ester, polyethylene glycol ether, sodium sulfate, starch, and mixtures thereof.
17. The composition according to claim 1 , wherein said plurality of capsules is present at a level of about 0.1% to about 20%, by weight of the composition.
18. A process for treating laundry comprising the steps of:
providing an article of laundry in a washing machine;
dispensing said plurality of individual particles according to claim 1 into said washing machine; and
contacting said article of laundry during a wash sub-cycle of said washing machine with said plurality of individual particles.
19. The process according to claim 18 further comprising a step of dispensing into said washing machine a laundry detergent comprising from about 3% to about 60% by weight anionic or nonionic surfactant.
20. The process according to claim 19 , wherein about 5 g to about 50 g of said plurality of individual particles is dispensed into said washing machine.