Tackified hotmelt adhesive composition
A hotmelt composition comprising, a low molecular weight metallocene-catalyzed polymer, a high molecular weight polymer, an amorphous polyolefin and a tackifier. The hotmelt composition is particularly useful in absorbent articles such as diapers. The hotmelt composition provides especially good nonwoven-film bonds but can also be used for nonwoven-nonwoven bonds.
1. A hotmelt composition comprising:
a low molecular weight metallocene-catalyzed polymer having a peak molecular weight below 130,000 g/mol, wherein the peak molecular weight is measured according to the Peak Molecular Weight (Mp) Measurement Method;
a high molecular weight polyolefin having a peak molecular weight of from about 130,000 g/mol to about 700,000 g/mol, according to the Peak Molecular Weight (Mp) Measurement Method;
an amorphous polyolefin having an enthalpy of crystallization of less than 10 J/g, wherein the enthalpy of crystallization is measured according to the Enthalpy of Crystallization Test Method; and
a tackifier;
wherein the low molecular weight metallocene-catalyzed polymer comprises:
a first low molecular weight metallocene-catalyzed propylene-ethylene copolymer having an enthalpy of crystallization below 20 J/g; and
a second low molecular weight metallocene-catalyzed propylene-ethylene copolymer having an enthalpy of crystallization above 20 J/g.
2. The hotmelt composition according to claim 1 , wherein the low molecular weight metallocene-catalyzed polymer is a propylene-based polymer.
3. The hotmelt composition according to claim 1 , wherein the first low molecular weight metallocene propylene-ethylene copolymer has an enthalpy of crystallization ranging from about 5 J/g to about 15 J/g.
4. The hotmelt composition according to claim 3 , wherein the second low molecular weight metallocene-catalyzed propylene-ethylene copolymer has an enthalpy of crystallization ranging from about 25 J/g to about 45 J/g.
5. The hotmelt composition according to claim 2 , wherein the low molecular weight metallocene-catalyzed polymer consists of a single low molecular weight metallocene-catalyzed propylene-based polymer, having an enthalpy of crystallization in the range of from about 20 J/g to about 30 J/g and a peak molecular weight between 25,000 and 35,000 g/mol.
6. The hotmelt composition according to claim 1 , wherein the high molecular weight polyolefin is a metallocene-catalyzed propylene-based polymer.
7. The hotmelt composition according to claim 6 , wherein the high molecular weight metallocene-catalyzed propylene-based polymer is a propylene-ethylene copolymer comprising greater than 80% by weight of polypropylene units.
8. The hotmelt composition according to claim 1 , wherein the high molecular weight polyolefin has a peak molecular weight ranging from about 130,000 g/mol to about 410,000 g/mol.
9. The hotmelt composition according to claim 1 , wherein the high molecular weight polyolefin has a peak molecular weight ranging from about 150,000 g/mol to about 360,000 g/mol.
10. A hotmelt composition comprising:
a low molecular weight metallocene-catalyzed polymer having a peak molecular weight below 130,000 g/mol, wherein the peak molecular weight is measured according to the Peak Molecular Weight (Mp) Measurement Method;
a high molecular weight polyolefin having a peak molecular weight of from about 130,000 g/mol to about 700,000 g/mol, according to the Peak Molecular Weight (Mp) Measurement Method;
an amorphous polyolefin having an enthalpy of crystallization of less than 10 J/g, wherein the enthalpy of crystallization is measured according to the Enthalpy of Crystallization Test Method; and
a tackifier;
wherein the amorphous polyolefin is a metallocene-catalyzed propylene-based polymer; wherein the amorphous polyolefin has a weight-average molecular weight Mw of less than about 10 000 g/mol, as measured by ISO 16014 and has a viscosity below 500 mPa·s at 170° C. as measured by the Viscosity Test Method described herein, and no melting point detectable by DSC.
11. The hotmelt composition according to claim 1 , comprising by weight of the hotmelt composition:
from about 10% to about 70% of the low molecular weight metallocene catalyzed polymer(s),
from about 1% to about 20% of the high molecular weight polyolefin(s),
from about 1% to about 30% of the amorphous polyolefin(s),
from about 20% to about 70% of the tackifier(s).
12. The hotmelt composition according to claim 11 , comprising by weight of the hotmelt composition:
from about 30% to about 60% of the low molecular weight metallocene catalyzed polymer(s),
from about 2% to about 15% of the high molecular weight polyolefin(s),
from about 5% to about 25% of the amorphous polyolefin(s),
from about 30% to about 60% of the tackifier(s).
13. The hotmelt composition according to claim 1 , which comprises less than 10% by weight of a mineral oil.
14. The hotmelt composition according to claim 1 , wherein the viscosity of the hotmelt composition at 170° C. is in the range from about 1,000 mPa·s to about 7,000 mPa·s, as measured according to the Viscosity Test Method.
15. The hotmelt composition according to claim 1 , wherein the composition has one or more properties selected from the group below:
a storage modulus (G′) at 37° C. smaller than 9.5 MPa, as measured in the cold to hot temperature ramp by the Oscillatory Rheometry Test Method disclosed herein; and/or
a Yield Stress at 37° C. smaller than 1.5 MPa, as measured by Extension Test Method disclosed herein; and/or
a Toughness above 2 MJ/m 3 , as measured by the Extension Test Method disclosed herein; and/or
a Cross Over temperature below 70° C. as measured in the hot to cold temperature ramp according to the Oscillatory Rheometry Test Method disclosed herein.
16. An absorbent article comprising a first substrate and a second substrate, wherein the first substrate and the second substrate are at least partially bonded by the hotmelt composition according to claim 1 , and wherein either a) the first substrate is a first nonwoven and the second substrate is a second nonwoven or b) the first substrate is a nonwoven and the second substrate is a plastic film.
17. A process for bonding a first substrate to a second substrate, the process comprising the steps of applying the hotmelt composition according to claim 1 at least on the first substrate or the second substrate by a contact applicator or a spray applicator, and then pressing the two substrates together before the hotmelt composition solidifies to create a bond between the two substrates.
18. The process according to claim 17 , wherein the hotmelt composition is applied on the first or second substrate at a line speed of more than 2 m/s.