Methanation and recovery method, system, and apparatus
View Patent ↗A method, a system, and an apparatus of certain embodiments are provided to recover water and carbon dioxide from combustion emissions. The recovery includes, among other things, electrolysis and carbon dioxide capture in a suitable solvent. The recovered water and carbon dioxide are subject to reaction, such as a catalytic methanation reaction, to generate at least methane.
1. A method comprising:
receiving a hydrocarbon combustion exhaust stream comprising water and carbon dioxide in a first chamber containing liquid water;
conveying methanation reaction products through a first heat exchanger of the first chamber to transfer heat from the methanation reaction products to the liquid water; and
subjecting the heated liquid water to electrolysis in the first chamber to generate hydrogen and oxygen.
2. The method of claim 1 , further comprising:
capturing the carbon dioxide in a solvent;
heating the solvent and the captured carbon dioxide in a second heat exchanger of the first chamber, wherein the first and second heat exchangers comprise a common heat exchanger or different heat exchangers; and
separating at least a portion of the carbon dioxide from the heated solvent.
3. The method of claim 2 , wherein the capturing of the carbon dioxide in a solvent takes place in a carbon dioxide absorber, and wherein the separating at least a portion of the carbon dioxide from the heated solvent takes place in a carbon dioxide desorber.
4. The method of claim 3 , further comprising:
discharging a first stream comprising carbon dioxide and a different second stream comprising heated solvent from the carbon dioxide desorber; and
cooling the first and second streams in the carbon dioxide absorber.
5. The method of claim 3 , wherein the carbon dioxide absorber is positioned substantially concentrically outside of the carbon dioxide desorber.
6. The method of claim 2 , further comprising reacting at least the hydrogen generated by the electrolysis and the carbon dioxide separated from the heated solvent in a methanation reactor to generate the methanation reaction products.
7. The method of claim 6 , further comprising:
heating a thermal mass with heat generated by the reacting of at least the hydrogen and the carbon dioxide in the methanation reactor; and
preheating the hydrogen generated by the electrolysis and the carbon dioxide separated from the heated solvent in a methanation pre-heater heated with the thermal mass prior to conveying the hydrogen and the carbon dioxide to the methanation reactor.
8. The method of claim 7 , wherein the methanation pre-heater is positioned substantially concentrically within the methanation reactor.
9. The method of claim 7 , further comprising:
the capturing of the carbon dioxide in a solvent takes place in a carbon dioxide absorber; and
the separating at least a portion of the carbon dioxide from the heated solvent takes place in a desorber.
10. The method of claim 9 , wherein:
the methanation reactor is positioned substantially concentrically outside of the methanation pre-heater;
the first chamber is positioned substantially concentrically outside of the methanation pre-heater;
the carbon dioxide desorber is positioned substantially concentrically outside of the first chamber; and
the carbon dioxide absorber is positioned substantially concentrically outside of the carbon dioxide desorber.
11. The method of claim 1 , further comprising separating methane from the water of the methanation reaction products in a second chamber that is different than the first chamber.
12. The method of claim 11 , wherein the first chamber and the second chamber are contained in a common tank.
13. The method of claim 12 , wherein the second chamber is positioned substantially concentrically outside of the first chamber.
14. The method of claim 1 , wherein the hydrocarbon combustion exhaust stream comprises gaseous water, and wherein the method further comprises condensing at least a portion of the gaseous water in the first chamber to add to the liquid water in the first chamber.
15. A method comprising:
subjecting liquid water in a first chamber to electrolysis to generate hydrogen and oxygen;
capturing carbon dioxide in a solvent;
conveying the solvent and the captured carbon dioxide through a first heat exchanger of the first chamber; and
conveying methanation reaction products through a second heat exchanger of the first chamber to transfer heat from the methanation reaction products to the liquid water in the first chamber and to the solvent conveyed through the first heat exchanger of the first chamber, wherein the first and second heat exchangers comprise a common heat exchanger or different heat exchangers.
16. The method of claim 15 , further comprising separating at least a portion of the carbon dioxide from the heated solvent, wherein the capturing is conducted in a carbon dioxide absorber and the separating is conducted in a carbon dioxide desorber.
17. The method of claim 16 , wherein the carbon dioxide desorber is positioned substantially concentrically outside of the first chamber, and the carbon dioxide absorber is positioned substantially concentrically outside of the carbon dioxide desorber.
18. The method of claim 15 , further comprising separating methane from water of the methanation reaction products in a second chamber that is different than the first chamber.
19. The method of claim 18 , wherein the second chamber is positioned substantially concentrically outside of the first chamber.
20. A method comprising:
receiving a hydrocarbon combustion exhaust stream comprising water and carbon dioxide in a chamber containing liquid water;
passing methanation reaction products through a first heat exchanger of the chamber to transfer heat from the methanation reaction products to the liquid water, the methanation reaction products comprising methane and gaseous water;
subjecting the heated liquid water to electrolysis in the chamber to generate hydrogen and oxygen;
capturing the carbon dioxide in a solvent;
heating the solvent with the captured carbon dioxide in a second heat exchanger of the chamber, wherein the first and second heat exchangers comprise a common heat exchanger or different heat exchangers;
separating at least a portion of the carbon dioxide from the heated solvent; and
reacting at least the hydrogen generated by the electrolysis and the carbon dioxide separated from the heated solvent in a methanation reactor to generate one or more hydrocarbons.