IP Library Granted Patent US 11,649,542
Granted Patent B2
US 11,649,542 · App. 17/529,788 · Granted May 16, 2023

Multi-layered zinc alloy plated steel having excellent spot weldability and corrosion resistance

Inventors: Young-Jin Kwak (Gwangyang-si, KR); Goo-Hwa Kim (Pohang-si, KR); Mun-Jong Eom (Gwangyang-si, KR); Seok-Jun Hong (Gwangyang-si, KR); Kyoung-Pil Ko (Gwangyang-si, KR); Yong-Hwa Jung (Gwangyang-si, KR); Dong-Yoeul Lee (Gwangyang-si, KR); Tae-Yeob Kim (Gwangyang-si, KR); Kyung-Hoon Nam (Gwangyang-si, KR)
Assignee: POSCO CO., LTD
C23C14/16B32B15/01B32B15/013B32B15/04B32B15/043B32B15/18C22C18/00C22C23/00C22C23/04C22C38/02C22C38/04C22C38/06C22C38/60C23C2/00C23C2/04C23C2/06C23C2/26C23C2/28C23C2/40C23C14/14C23C14/165C23C14/24C23C28/02C23C28/021C23C28/023C23C28/025C23C28/32C23C28/321C23C28/322C23C28/3225C23C30/00C23C30/005C21D2211/001Y10T428/12785Y10T428/12799Y10T428/12951Y10T428/12972Y10T428/12979
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Quick Facts
Patent No.
US 11,649,542
App. No.
17/529,788
Granted
May 16, 2023
Kind
B2
Abstract

Provided is a multilayer zinc alloy plated steel material comprising a base steel material and multiple plating layers formed on the base steel material, wherein each of the multiple plating layers includes one of a Zn plating layer, a Mg plating layer, and a Zn—Mg alloy plating layer, and the ratio of the weight of Mg contained in the multiple plating layers to the total weight of the multiple plating layers is from 0.13 to 0.24.

Claims (17)

1. A multilayer zinc alloy plated steel material comprising:

a base steel material having a thickness; and

multiple plating layers formed on the base steel material,

wherein a ratio of a weight of Mg contained in the multiple plating layers to a total weight of the multiple plating layers is from 0.13 to 0.24,

wherein the multiple plating layers comprise a first plating layer formed on the base steel material and a second plating layer formed on the first plating layer, the first plating layer comprises a Zn—Mg alloy phase, and the second plating layer comprises a Zn single phase or a Zn single phase and a Zn—Mg alloy phase and has a Mg content within a range of 2 wt % or less.

2. The multilayer zinc alloy plated steel material of claim 1 , wherein, when a GDS profile is measured at a thicknesswise center portion of each of the multiple plating layers, a Mg content in the each of the multiple plating layers deviates within a range of ±5% in a width direction of the each of the multiple plating layers which is a direction perpendicular to a rolling direction of the base steel material.

3. The multilayer zinc alloy plated steel material of claim 1 , wherein grains of the multiple plating layers have an average diameter of 100 nm or less (excluding 0 nm).

4. The multilayer zinc alloy plated steel material of claim 1 , wherein a total plating amount of the multiple plating layers is 40 g/m 2 or less (excluding 0 g/m 2 ).

5. The multilayer zinc alloy plated steel material of claim 1 , wherein, when spot welding is performed on the multilayer zinc alloy plated steel material, the multiple plating layers are configured to be changed to a single alloy layer in a weld zone, and the single alloy layer comprises: a MgZn 2 alloy phase in an area fraction of 90% or greater (including 100%).

6. The multilayer zinc alloy plated steel material of claim 1 , wherein, when spot welding is performed in accordance with SEP 1220-2, an average length of type B cracks is equal to or less than 0.1 times the thickness of the base steel material.

7. The multilayer zinc alloy plated steel material of claim 1 , wherein the base steel material comprises, by wt %, C: 0.10% to 1.0%, Si: 0.5% to 3%, Mn: 1.0% to 25%, Al: 0.01% to 10%, P: 0.1% or less (excluding 0%), S: 0.01% or less (excluding 0%), and a balance of Fe and inevitable impurities, and

wherein the contents of C, Si, Mn, P, and S satisfy Condition 1 below:

[C]+[Mn]/20+[Si]/30+2[P]+4[S]≥0.3  Condition 1:

where each of [C], [Mn], [Si], [P], and [S] refers to a content (wt %) of a corresponding element.

8. The multilayer zinc alloy plated steel material of claim 1 , wherein a sum of plating amounts of the first and second plating layers is within a range of 40 g/m 2 or less (excluding 0 g/m 2 ), and a plating amount of the second plating layer is within a range of 2 g/m 2 or greater.

9. The multilayer zinc alloy plated steel material of claim 1 , wherein the ratio is from 0.157 to 0.20.

10. The multilayer zinc alloy plated steel material of claim 1 , wherein a total plating amount of the multiple plating layers is within a range of 10 g/m 2 to 35 g/m 2 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061773/0658 →
CHANGE OF NAME Recorded Sep 19, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061476/0736 →
Priority Claims (1)
KR 10-2016-0178834 · Dec 26, 2016 · national
Continuity (2)
Division 16471943
Related Publication 20220074040A1 · Mar 10, 2022