Engineered coating for filters and methods of manufacture thereof
Disclosed herein is a porous membrane comprising a porous substrate; a porous ceramic coating disposed on the porous substrate; where an average pore size of pores in the porous substrate are larger than an average pore size of pores in the porous coating. Disclosed herein is a method of manufacturing a porous membrane comprising disposing upon a porous substrate a porous ceramic coating, where the porous ceramic coating has an average pore size that is less than an average pore size of the porous substrate.
1. A porous membrane comprising:
a porous substrate;
a porous ceramic coating disposed on the porous substrate; where an average pore size of pores in the porous substrate are larger than an average pore size of pores in the porous coating; and wherein fabricating the porous membrane is conducted at a temperature less than an oxidation temperature of the substrate, while not reducing any existing oxide coating on the membrane or wherein fabricating the membrane is conducted in an inert atmosphere with low air/oxygen partial pressures and at temperatures between 400 and 1200° C. and wherein the oxygen partial pressure is from 10 −9 atm to 10 −3 atm;
wherein the porous ceramic coating comprises different oxides of the same metal, and the metal is titanium;
wherein the different oxides are TiO 2 and Ti 2 O 3 ; and
wherein the metal oxide comprises 50 to 80 wt % of TiO 2 and 20 to 50 wt % of Ti 2 O 3 , based on the total weight of the metal oxide.
2. The porous membrane of claim 1 , where the porous substrate has a thickness that is greater than the thickness of the porous coating.
3. The porous membrane of claim 1 , where the porous substrate has an average pore size of 0.1 to 100 micrometers.
4. The porous membrane of claim 1 , where the porous ceramic coating has an average pore size of 0.05 nanometers to 5 micrometers.
5. The porous membrane of claim 1 , where the porous ceramic coating covers a portion of a cell present in the porous substrate.
6. The porous membrane of claim 1 , where the porous substrate comprises a metal, a metal alloy, a glass, a ceramic or a cermet.
7. The porous membrane of claim 1 , where the porous substrate comprises stainless steel.
8. The porous membrane of claim 1 , where the porous substrate and the porous ceramic coating have a different chemical composition from each other.
9. The porous membrane of claim 1 , where the porous ceramic coating further comprises a nitride, a carbide, a silicate, a titanate, a zirconate, or a combination thereof.
10. The porous membrane of claim 1 , where the porous ceramic coating further comprises a metal nitride, a metal carbide, a silicate, a titanate, a zirconate, an aluminate, or a combination thereof.
11. The porous membrane of claim 1 , where the metal oxide comprises 69 wt % of TiO 2 and 31 wt % of Ti 2 O 3 , based on the total weight of the metal oxide.
12. The porous membrane of claim 1 , where the porous ceramic coating is manufactured by anodization of a metal layer disposed on the porous substrate.
13. The porous membrane of claim 1 , where the porous ceramic coating is manufactured from an enamel frit-based composition.
14. The porous membrane of claim 1 , wherein the metal oxide comprises 65 to 75 wt % of TiO 2 and 20 to 33 wt % of Ti 2 O 3 , based on the total weight of the metal oxide.
15. A method of manufacturing the porous membrane of claim 1 , the method comprising:
disposing a titania precursor on the substrate; and
manufacturing the porous membrane below an oxidation temperature of the substrate, while not reducing any existing oxide coating on the membrane; or
manufacturing the membrane in an inert atmosphere with low air/oxygen partial pressures and at temperatures between 400 and 1200° C.; wherein the oxygen partial pressure is from 10 −9 atm to 10 −3 atm.
16. The method of claim 15 , where the porous substrate comprises a metal, a metal alloy, a glass, a ceramic or a cermet.
17. The method of claim 15 , where the porous ceramic coating comprises a metal oxide, a metal nitride, a metal carbide, a silicate, a titanate, a zirconate, an aluminate, or a combination thereof.
18. The method of claim 15 , where the oxidation occurs via thermal oxidation.
19. The method of claim 15 , where the oxidation occurs via hydrothermal oxidation.
20. The porous membrane of claim 1 , where the porous ceramic coating protrudes into a portion of a cell present in the porous substrate.
21. The porous membrane of claim 1 , where the porous ceramic coating does not protrude into a portion of a cell present in the porous substrate.