Silicon particles for battery electrodes
Silicon particles for active materials and electro-chemical cells are provided. The active materials comprising silicon particles described herein can be utilized as an electrode material for a battery. In certain embodiments, the composite material includes greater than 0% and less than about 90% by weight of silicon particles. The silicon particles have an average particle size between about 0.1 μm and about 30 μm and a surface including nanometer-sized features. The composite material also includes greater than 0% and less than about 90% by weight of one or more types of carbon phases. At least one of the one or more types of carbon phases is a substantially continuous phase.
1. A method of forming a composite material, the method comprising:
providing a mixture comprising a precursor and silicon particles, wherein an average particle size of the silicon particles is greater than 0.5 μm; and
pyrolysing the mixture to convert the precursor into one or more types of carbon phases to form the composite material,
wherein at least one of the one or more types of carbon phases comprises a continuous phase that holds the composite material together such that the silicon particles are distributed throughout the composite material, and
wherein the composite material comprises a material including silicon and carbon between the silicon particles and the one or more types of carbon phases.
2. The method of claim 1 , wherein the material including silicon and carbon comprises silicon carbide.
3. The method of claim 1 , wherein providing the mixture comprises providing a mixture comprising greater than 0% to about 90% by weight of the silicon particles, and about 5% to about 80% by weight of the precursor.
4. The method of claim 1 , wherein providing the mixture comprises providing conductive particles in the mixture.
5. The method of claim 1 , wherein providing the mixture comprises providing metal particles in the mixture.
6. The method of claim 1 , wherein the silicon particles are homogeneously distributed throughout the composite material.
7. The method of claim 1 , wherein the silicon particles are in contact with the continuous phase.
8. The method of claim 1 , wherein the silicon particles have an average largest dimension of 1 μm to 40 μm.
9. The method of claim 1 , wherein the continuous phase of the at least one of the one or more types of carbon phases is electrochemically active and electrically conductive.
10. The method of claim 1 , wherein the one or more types of carbon phases comprises graphite particles.
11. The method of claim 1 , wherein the composite material is electrochemically active.
12. The method of claim 1 , wherein the composite material comprises the silicon particles at about 50% to about 90% by weight.
13. The method of claim 1 , comprising
casting the mixture on a substrate;
drying the mixture;
removing the dried mixture from the substrate; and
placing the dried mixture in a hot press.
14. A method of forming a battery cell, the method comprising:
forming an anode of the battery cell, the anode comprising a composite material, wherein:
the composite material comprises one or more types of carbon phases and silicon particles;
an average particle size of the silicon particles is greater than 0.5 μm;
at least one of the one or more types of carbon phases comprises a continuous phase that holds the composite material together such that the silicon particles are distributed throughout the composite material, and
the composite material comprises a material including silicon and carbon between the silicon particles and the one or more types of carbon phases; and
separating the anode from a cathode of the battery cell with a separator and electrolyte of the battery cell.
15. The method of claim 14 , wherein the forming the anode comprises pyrolysing a mixture comprising a precursor and the silicon particles to convert the precursor into the one or more types of carbon phases.
16. The method of claim 15 , wherein the mixture comprises greater than 0% to about 90% by weight of the silicon particles, and about 5% to about 80% by weight of the precursor.
17. The method of claim 15 , wherein the mixture comprises conductive particles.
18. The method of claim 15 , wherein the mixture comprises metal particles.
19. The method of claim 15 , wherein the forming of the anode comprises:
casting the mixture on a substrate;
drying the mixture;
removing the dried mixture from the substrate; and
placing the dried mixture in a hot press.
20. The method of claim 14 , wherein the forming the anode homogeneously distributes the silicon particles throughout the composite material.
21. The method of claim 14 , wherein the silicon particles are in contact with the continuous phase.
22. The method of claim 14 , wherein the silicon particles have an average largest dimension of 1 μm to 40 μm.
23. The method of claim 14 , wherein the composite material is electrochemically active.
24. The method of claim 14 , wherein the composite material comprises the silicon particles at about 50% to about 90% by weight.
25. The method of claim 14 , wherein the material including silicon and carbon comprises silicon carbide.