IP Library Granted Patent US 11,746,442
Granted Patent B2
US 11,746,442 · App. 17/551,142 · Granted Sep 5, 2023

Ultra high molecular weight polyethylene multifilament yarn

Inventors: Jacobus Johannes Mencke (Echt, NL); Johannes Hendrikus Marie Heijnen (Echt, NL); Harm Van Der Werff (Echt, NL)
Assignee: AVIENT PROTECTIVE MATERIALS B.V.
D01F6/04D02G3/02D01D5/06D07B1/025D07B2201/1096D07B2201/2009D07B2205/2014D07B2501/2038D07B2501/2061D10B2321/0211Y10T428/1369Y10T428/24124Y10T428/249921Y10T428/298Y10T428/31913Y10T442/60
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Quick Facts
Patent No.
US 11,746,442
App. No.
17/551,142
Granted
Sep 5, 2023
Kind
B2
Abstract

Multifilament yarn containing n filaments are provided, wherein the filaments are obtained by spinning an ultra-high molecular weight polyethylene (UHMWPE), said yarn having a tenacity (Ten) as expressed in cN/dtex of Ten(cN/dtex)=f×n −0.05 ×dpf −0.15 , wherein Ten is at least 39 cN/dtex, n is at least 25, f is a factor of at least 58 and dpf is the dtex per filament.

Claims (32)

1. A panel comprising a plurality of sheets, wherein each sheet comprises at least 2 monolayers, wherein each of the monolayers comprises unidirectionally aligned yarn spun from an ultra-high molecular weight polyethylene (UHMWPE), wherein the yarn has a tenacity (Ten) as expressed in cN/dtex according to Formula 1:

Ten(cN/dtex)= f×n −0.05 ×dpf −0.15   (Formula 1)

wherein Ten is at least 39 cN/dtex, n is at least 50, f is a factor of at least 62.0 and dpf is the dtex per filament.

2. The panel according to claim 1 , wherein each sheet comprises at least 4 monolayers.

3. The panel according to claim 1 , wherein each sheet comprises at most 8 monolayers.

4. The panel according to claim 1 , wherein the factor f is at least 64.0.

5. The panel according to claim 1 , wherein the factor f is at least 67.0.

6. The panel according to claim 1 , wherein the sheets and/or the monolayers comprise a matrix material in an amount of at most 25 mass %, based on the total weight of the panel.

7. The panel according to claim 1 , wherein the sheets and/or the monolayers comprise a matrix material in an amount of at least 5 mass %, based on the total weight of the panel.

8. The panel according to claim 1 , wherein each of the sheets comprises a stack of the monolayers and a pair of polymeric films which sandwich the stack of monolayer.

9. The panel according to claim 8 , wherein the polymeric films are polyethylene films.

10. The panel according to claim 9 , wherein the polymeric films are low density polyethylene (LDPE) films.

11. A rigid panel comprising:

a stack of sheets, wherein

each of the sheets comprises at least 2 monolayers, wherein

each of the monolayers comprises unidirectionally aligned yarn spun from an ultra-high molecular weight polyethylene (UHMWPE), wherein the yarn has a tenacity (Ten) as expressed in cN/dtex according to Formula 1:

Ten(cN/dtex)= f×n −0.05 ×dpf −0.15   (Formula 1)

wherein Ten is at least 39 cN/dtex, n is at least 50, f is a factor of at least 62 and dpf is the dtex per filament, and wherein

the rigid panel has (i) a flexural strength of at least 10 MPa as measured before impact and (ii) an Eabs (J/[kg/m 2 ]) of at least 170 against an AK47 FMJ MSC projectile as determined for an areal density of the panel of about 15.5 kg/m 2 .

12. A method of making the ridged panel according to claim 11 , wherein the method comprises compressing the stack of the sheets to a pressure of at least 50 bars and to a temperature below a melting temperature of the yarns.

13. A flexible panel comprising:

a stack of uncompressed sheets, wherein

each of the sheets comprises at least 2 monolayers, wherein

each of the monolayers comprises unidirectionally aligned yarn spun from an ultra-high molecular weight polyethylene (UHMWPE), wherein the yarn has a tenacity (Ten) as expressed in cN/dtex according to Formula 1:

Ten(cN/dtex)= f×n −0.05 ×dpf −0.15   (Formula 1)

wherein Ten is at least 39 cN/dtex, n is at least 50, f is a factor of at least 62 and dpf is the dtex per filament.

14. The flexible panel according to claim 13 , wherein the sheets are stitched or glued together.

15. The flexible panel according to claim 14 , wherein the sheets are spot-glued together.

16. The flexible panel according to claim 13 , which comprises a bag containing the stack of sheets for holding the stack of sheets together.

17. The flexible panel according to claim 13 , wherein the flexible panel has an Eabs (J/[kg/m 2 ]) of at least 370 against a 0.357 Magnum JSP projectile as determined for an areal density of the panel of about 3.1 Kg/m 2 .

18. The flexible panel according to claim 13 , wherein the flexible panel has an Eabs (J/[kg/m 2 ]) against an 9 mm FMJ Parabellum projectile of at least 220 as determined for a flexible panel having an areal density of about 3.1 Kg/m 2 .

19. The flexible panel according to claim 13 , wherein the flexible panel has an Eabs (J/[kg/m 2 ]) against a 17 grain FSP projectile of at least 35 as determined for an areal density of the panel of about 3.1 Kg/m 2 .

Assignments (2)
CHANGE OF NAME Recorded Mar 17, 2023
From: DSM PROTECTIVE MATERIALS B.V.
To: AVIENT PROTECTIVE MATERIALS B.V.
Reel/Frame 063115/0134 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2022
From: DSM IP ASSETS B.V.
To: DSM PROTECTIVE MATERIALS B.V.
Reel/Frame 061897/0987 →
Priority Claims (1)
EP 11193491 · Dec 14, 2011 · regional
Continuity (2)
Continuation 14364910
Related Publication 20220143950A1 · May 12, 2022