Ligand exchange of nanocrystal films
A method includes at least partially submerging a substrate in a colloidal mixture of nanocrystals and a first solvent. The nanocrystals have first ligands coupled thereto. The method also includes applying an electric field to the colloidal mixture to form a solvated nanocrystal film and removing the solvated nanocrystal film from the first solvent. The method further includes applying a second solvent to the solvated nanocrystal film for ligand exchange. The second solvent comprises second ligands. A nanocrystal film product formed by one-step ligand exchange includes at least one dimension greater than 100 nm and ordered nanocrystals characterized as having a domain size of greater than 100 nm.
1. A method for one-step ligand exchange, the method comprising:
at least partially submerging a substrate in a colloidal mixture of nanocrystals and a first solvent, wherein the nanocrystals have first ligands coupled thereto;
applying an electric field to the colloidal mixture to form a solvated nanocrystal film having a thickness in a range of greater than 100 nm and less than about 2 microns;
removing the solvated nanocrystal film from the first solvent; and
applying a second solvent to the solvated nanocrystal film for ligand exchange,
wherein the second solvent comprises second ligands,
wherein the second solvent is applied to the solvated nanocrystal film for five minutes or less.
2. The method of claim 1 , wherein the first ligands are relatively longer than the second ligands.
3. The method of claim 1 , wherein the first solvent comprises a first component and a second component, wherein the first component and the second component of the first solvent are miscible, polar/non-polar pairs, wherein the second solvent comprises a first component and a second component, wherein the first component and the second component of the second solvent are miscible, polar/non-polar pairs.
4. The method of claim 1 , wherein applying the second solvent to the solvated nanocrystal film for the ligand exchange includes forming a resulting nanocrystal film product, wherein the nanocrystal film product has at least one dimension greater than 100 nm.
5. The method of claim 4 , wherein the solvated nanocrystal film is physically characterized as having a lattice constant in a range of about 10% to about 20% larger than the lattice constant of the nanocrystal film product.
6. The method of claim 4 , wherein the nanocrystal film product comprises ordered nanocrystals characterized as having a domain size of greater than 100 nm.
7. The method of claim 4 , comprising forming an optoelectronic device having the nanocrystal film product, the optoelectronic device being selected from the group consisting of: a sensor, a solar cell, a light emitting diode, and a photodetector.
8. The method of claim 1 , wherein the nanocrystals comprise a material selected from the group consisting of: Ag, Au, Ni, SiO 2 , and TiO 2 .
9. The method of claim 1 , wherein the substrate is a material selected from the group consisting of: silicon-based materials, metal-based materials, and indium tin oxide (ITO) coated substrates.
10. The method of claim 1 , wherein a concentration of the nanocrystals in the first solvent is in a range of about 2 mg/mL to about 40 mg/mL.
11. The method of claim 1 , wherein the first solvent and/or the second solvent include an additive selected from the group consisting of: methanol and dimethyl sulfoxide (DMSO).
12. The method of claim 1 , wherein the thickness of the solvated nanocrystal film is a deposition thickness measured in a direction perpendicular to a surface of the solvated nanocrystal film.
13. The method of claim 1 , wherein the thickness of the solvated nanocrystal film is greater than 500 nm.
14. The method of claim 1 , wherein the ligand exchange occurs throughout the entire thickness of the solvated nanocrystal film.
15. The method of claim 1 , wherein the second solvent is applied to the solvated nanocrystal film for three minutes or less.
16. The method of claim 15 , wherein the ligand exchange occurs throughout the entire thickness of the solvated nanocrystal film in the three minutes or less.
17. The method of claim 1 , wherein an order of the nanocrystals in the solvated nanocrystal film is retained during the ligand exchange.
18. The method of claim 1 , comprising drying the solvated nanocrystal film after the ligand exchange for creating a dried nanocrystal film, wherein the solvated nanocrystal film is physically characterized as having a lattice constant in a range of about 10% to about 20% larger than a lattice constant of the dried nanocrystal film.
19. The method of claim 3 , wherein the first component of the first solvent is different than the first component of the second solvent.