Wavelength converting layer patterning for LED arrays
A method includes depositing a layer comprising a photoinitiator and a curable material onto a surface and applying a nanoimprint mold on the layer of curable material to form a mesh comprising intersecting walls defining cavities. After applying the nanoimprint mold, the mesh is illuminated with light causing decarboxylation of the photoinitiator to initiate curing of the curable material. After curing the curable material, the nanoimprint mold is removed and a wavelength converting material is deposited in the cavities to form an array of wavelength converting pixels.
1. A method comprising:
forming a mesh having intersecting walls defining cavities, the mesh comprising a photoinitiator and a curable material;
after forming the mesh, illuminating the mesh with light causing decarboxylation of the photoinitiator to initiate curing of the curable material; and
after curing the curable material, depositing a wavelength converting material in the cavities to form an array of wavelength converting pixels.
2. The method of claim 1 , wherein the pixels in the array have widths of 100 microns or less and adjacent pixels are spaced apart by 20 microns or less.
3. The method of claim 1 , comprising aligning an array of light emitting semiconductor diodes with the array of wavelength converting pixels and attaching each wavelength converting pixel to a corresponding light emitting semiconductor diode.
4. The method of claim 1 , wherein the curable material comprises one or more of a siloxane material, a polysilazane, or a sol-gel material.
5. The method of claim 1 , wherein the photoinitiator is a salt.
6. The method of claim 1 , wherein the decarboxylated photoinitiator catalyzes reaction of chain ends or cross-linkable substrates of the curable material.
7. The method of claim 1 , wherein the decarboxylated photoinitiator catalyzes a condensation polymerization or a ring opening polymerization of the curable material.
8. The method of claim 1 , wherein the decarboxylation produces a super base.
9. The method of claim 8 , comprising removing the super base by evaporation or thermal decomposition of the super base after curing of the curable material.
10. The method of claim 1 , wherein:
the curable material comprises one or more of a siloxane material, a polysilazane, or a sol-gel material;
the photoinitiator is a salt;
illuminating the mesh with light comprises illuminating the mesh with ultraviolet light absorbed by the photoinitiator to cause the decarboxylation of the photoinitiator; and
decarboxylation of the photoinitiator produces a super base.
11. A wavelength converting structure comprising:
a mesh having intersecting walls, the mesh comprising a decarboxylated photoinitiator and a cured binder; and
a plurality of wavelength converting layers in contact with the mesh walls forming an array of wavelength converting pixels.
12. The wavelength converting structure of claim 11 , wherein the pixels in the array have widths of 100 microns or less and adjacent pixels are spaced apart by 20 microns or less.
13. A light emitting device comprising:
the wavelength converting structure of claim 11 ; and
an array of light emitting semiconductor diodes where each wavelength converting pixels of the wavelength converting structure is attached to a corresponding light emitting semiconductor diode.
14. The wavelength converting structure of claim 11 , wherein the cured binder comprises one or more of a cured siloxane material, a cured polysilazane, or a cured sol-gel material.
15. The wavelength converting structure of claim 11 , wherein the decarboxylated photoinitiator comprises a super base.
16. A wavelength converting structure comprising:
a plurality of wavelength converting elements forming an array of wavelength converting pixels, each wavelength converting element comprising a decarboxylated photoinitiator and a cured binder.
17. The wavelength converting structure of claim 16 , wherein the pixels in the array have widths of 100 microns or less and adjacent pixels are spaced apart by 20 microns or less.
18. A light emitting device comprising:
the wavelength converting structure of claim 16 ; and
an array of light emitting semiconductor diodes where each wavelength converting pixels of the wavelength converting structure is attached to a corresponding light emitting semiconductor diode.
19. The wavelength converting structure of claim 16 , wherein the cured binder comprises one or more of a cured siloxane material, a cured polysilazane, or a cured sol-gel material.
20. The wavelength converting structure of claim 16 , wherein the decarboxylated photoinitiator comprises a super base.