IP Library Granted Patent US 12,180,391
Granted Patent B2
US 12,180,391 · App. 17/591,886 · Granted Dec 31, 2024

Preinstalled sealant for prefab components

Inventors: Diana Hun (Oak Ridge, TN); Pengfei Cao (Oak Ridge, TN); Xiao Zhao (Oak Ridge, TN); Zoriana Demchuk (Oak Ridge, TN); Jiancheng Luo (Oak Ridge, TN); Tomonori Saito (Oak Ridge, TN)
Assignee: UT-BATTELLE, LLC
C09J133/12C09J5/00C09J11/08C09J133/08C09J2433/00C09J2463/00C09J2475/00
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Quick Facts
Patent No.
US 12,180,391
App. No.
17/591,886
Granted
Dec 31, 2024
Kind
B2
Abstract

A joint sealing system for prefabricated building components is provided. The joint sealing system includes a first component including a first surface, and a second component including a second surface that is mateable with the first surface. The first and second surfaces define a joint. A sealant composition is disposed on one of the first surface or the second surface. Pressure exerted when the second surface is mated with the first surface triggers curing of the sealant composition to join the first and second components and to seal the joint between the first and second components. A method of joining and sealing two prefabricated building components is also provided.

Claims (41)

1. A joint sealing system for prefabricated building components comprising:

a first component including a first surface;

a second component including a second surface that is mateable with the first surface, said first and second surfaces defining a joint; and

a sealant composition disposed on one of the first surface or the second surface, the sealant composition comprising:

a first component including a curing agent and a polymer matrix, the curing agent including one or more of diamine-type curing agents and diol-type curing agents; and

a second component that includes a microcapsule having a resin encapsulated inside a shell, the resin including one or more of epoxy-based resins, acrylic-based resins, aliphatic isocyanate-based resins, and aromatic isocyanate-based resins, and the microcapsule being dispersed in the first component;

wherein breaking of the microcapsule shell by an applied force allows the curing agent to react with the resin to cure the sealant composition;

wherein pressure exerted when the second surface is mated with the first surface triggers curing of the sealant composition to join the first and second components and to seal the joint between the first and second components.

2. The joint sealing system of claim 1 , wherein the first surface includes a male connector and the second surface includes a female connector.

3. The joint sealing system of claim 2 , wherein the sealant composition is either: (i) disposed in the female connector; or (ii) disposed adjacent the male connector.

4. The joint sealing system of claim 1 , wherein the joint is one selected from (i) a tongue-and-groove joint; or (ii) a butt joint.

5. The joint sealing system of claim 1 , wherein the sealant composition is a preinstalled sealant that is disposed on the first surface or the second surface during manufacturing of the first or second component.

6. The joint sealing system of claim 1 , wherein the polymer matrix is a healable polymer that is a copolymer including an acrylate monomer unit having a low glass transition temperature (T g ) and a methacrylate monomer unit having a high glass transition temperature (T g ).

7. The joint sealing system of claim 6 , wherein the healable polymer includes one or both of butyl acrylate (BA) and 2-ethylhexyl acrylate (2-EHA) combined with methyl methacrylate (MMA) in a ratio of between 95:5 and 50:50.

8. The joint sealing system of claim 1 , wherein the curing agent is one or more selected from a PPG/PEG-diamine, a PPG-di (secondary amine), a PPG/PEG-triamine, a polyethyleneimine (PEI), and a PPG/PEG-diol.

9. The joint sealing system of claim 8 , wherein the curing agent is (i) a combination of a PPG/PEG-triamine and polyethyleneimine (PEI) wherein the amount of PEI is between 0 and 40% by weight; (ii) a combination of a PPG/PEG-diamine and a PPG/PEG-diol wherein the amount of PPG/PEG-diol is between 0 and 60% by weight; and (iii) a combination of a PPG-di (secondary amine) and a PPG/PEG-diol wherein the amount of PPG/PEG-diol is between 0 and 60% by weight.

10. The joint sealing system of claim 1 , wherein the resin is one or more selected from a bisphenol A epoxy, a novolac epoxy, an acrylated novolac epoxy, a bio-based epoxy, an aliphatic di-isocyanate, an aromatic di-isocyanate, a bio-based di-isocyanate, a diacrylate, and a triacrylate.

11. The joint sealing system of claim 1 , wherein the curing agent cures the resin in less than 8 hours and the resin is fully cured within 21 days at temperature between 2° and 100° F.

12. The joint sealing system of claim 1 , wherein the cured sealant composition has an adhesion strength of at least 15 pounds/inch.

13. The joint sealing system of claim 1 , wherein the microcapsule has a diameter in the range of 10 to 1000 μm and a shell thickness of between 1 and 50 μm.

14. A method of joining and sealing two prefabricated building components, the method comprising:

providing a first component having a first surface;

providing a second component having a second surface that is mateable with the first surface, the first and second surfaces defining a joint;

disposing a sealant composition on one of the first surface or the second surface, the sealant composition comprising:

a first component including a curing agent and a polymer matrix, the curing agent including one or more of diamine-type curing agents and diol-type curing agents; and

a second component that includes a microcapsule having a resin encapsulated inside a shell, the resin including one or more of epoxy-based resins, acrylic-based resins, aliphatic isocyanate-based resins, and aromatic isocyanate-based resins, and the microcapsule being dispersed in the first component;

wherein breaking of the microcapsule shell by an applied force allows the curing agent to react with the resin to cure the sealant composition; and

joining the first component with the second component by mating the first surface with the second surface, whereby a force is applied to the sealant composition, causing the microcapsules to rupture such that the resin mixes with the curing agent and the sealant composition cures to seal the joint between the first component and the second component.

15. The method of claim 14 , wherein one or both of the components are fabricated at a location different than the location at which the components are assembled together, and the sealant composition is preinstalled by being disposed on one of the components at the said different location at which the components are fabricated.

16. A joint sealing system for prefabricated building components comprising:

a first component including a first surface;

a second component including a second surface that is mateable with the first surface, said first and second surfaces defining a joint; and

a sealant composition disposed on one of the first surface or the second surface, the sealant composition comprising:

a first component including a curing agent and a polymer matrix, the polymer matrix being a healable polymer that is a copolymer including an acrylate monomer unit having a low glass transition temperature (T g ) and a methacrylate monomer unit having a high glass transition temperature (T g ); and

a second component that includes a microcapsule having a resin encapsulated inside a shell, the microcapsule being dispersed in the first component;

wherein breaking of the microcapsule shell by an applied force allows the curing agent to react with the resin to cure the sealant composition;

wherein pressure exerted when the second surface is mated with the first surface triggers curing of the sealant composition to join the first and second components and to seal the joint between the first and second components.

17. The joint sealing system of claim 16 , wherein the healable polymer includes one or both of butyl acrylate (BA) and 2-ethylhexyl acrylate (2-EHA) combined with methyl methacrylate (MMA) in a ratio of between 95:5 and 50:50.

18. The joint sealing system of claim 16 , wherein the curing agent cures the resin in less than 8 hours and the resin is fully cured within 21 days at temperature between 2° and 100° F.

19. The joint sealing system of claim 16 , wherein the cured sealant composition has an adhesion strength of at least 15 pounds/inch.

20. The joint sealing system of claim 16 , wherein the microcapsule has a diameter in the range of 10 to 1000 μm and a shell thickness of between 1 and 50 μm.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 8, 2022
From: HUN, DIANA; CAO, PENGFEI; ZHAO, XIAO; DEMCHUK, ZORIANA; LUO, JIANCHENG; SAITO, TOMONORI
To: UT-BATTELLE, LLC
Reel/Frame 061684/0330 →
CONFIRMATORY LICENSE Recorded Apr 14, 2022
From: UT-BATTELLE, LLC
To: U. S. DEPARTMENT OF ENERGY
Reel/Frame 059594/0614 →
Continuity (2)
Provisional Application 63145517 · Feb 4, 2021
Related Publication 20220243103A1 · Aug 4, 2022