Polarizing plate and optical display apparatus comprising same
A polarizing plate and an optical display apparatus including the same. The polarizing plate includes: a polarizer; a first retardation layer; and a second retardation layer, the first retardation layer and the second retardation layer being sequentially laminated on a lower surface of the polarizer, wherein the first retardation layer has a short wavelength dispersion of about 1 to about 1.03, a long wavelength dispersion of about 0.98 to about 1, and an in-plane retardation of about 220 nm to about 270 nm at a wavelength of about 550 nm, the second retardation layer has a short wavelength dispersion of about 1 to about 1.1, a long wavelength dispersion of about 0.96 to about 1, and an in-plane retardation of about 80 nm to about 130 nm at a wavelength of about 550 nm, and a ratio (Rth/d) of out-of-plane retardation (Rth, unit:nm) of the second retardation layer at a wavelength of about 550 nm to thickness (d, unit:μm) of the second retardation layer ranges from about −33 nm/μm to about −15 nm/μm.
1. A polarizing plate comprising:
a polarizer; a first retardation layer; and a second retardation layer, the first retardation layer and the second retardation layer being sequentially laminated on a lower surface of the polarizer,
wherein the first retardation layer has a short wavelength dispersion of 1 to 1.03, a long wavelength dispersion of 0.98 to 1, and an in-plane retardation of 220 nm to 270 nm at a wavelength of 550 nm,
the second retardation layer has a short wavelength dispersion of 1 to 1.1, a long wavelength dispersion of 0.96 to 1, and an in-plane retardation of 80 nm to 130 nm at a wavelength of 550 nm,
a ratio (Rth/d) of out-of-plane retardation (Rth, unit:nm) of the second retardation layer at a wavelength of 550 nm to thickness (d, unit:μm) of the second retardation layer is from −33 nm/μm to −15 nm/μm, and
the second retardation layer has a thickness of 2 μm to 8 μm and an out-of-plane retardation of −200 nm to −100 nm at a wavelength of 550 nm.
2. The polarizing plate according to claim 1 , wherein the first retardation layer is an obliquely stretched film and the second retardation layer is an obliquely stretched coating layer.
3. The polarizing plate according to claim 1 , wherein the second retardation layer is directly formed on the first retardation layer.
4. The polarizing plate according to claim 1 , wherein a slow axis of the first retardation layer is disposed at an angle of +65° to +75° or −65° to −75° with respect to a transmission axis of the polarizer.
5. The polarizing plate according to claim 1 , wherein an angle defined between a slow axis of the first retardation layer and a slow axis of the second retardation layer is from 58° to 70°.
6. The polarizing plate according to claim 1 , wherein a ratio of short wavelength dispersion of the second retardation layer to short wavelength dispersion of the first retardation layer is from 1 to 1.08.
7. The polarizing plate according to claim 1 , wherein a ratio of long wavelength dispersion of the second retardation layer to long wavelength dispersion of the first retardation layer is from 0.96 to 1.
8. The polarizing plate according to claim 1 , wherein the first retardation layer has a degree of biaxiality of 1 to 1.4 at a wavelength of 550 nm and the second retardation layer has a degree of biaxiality of −2 to 0 at a wavelength of 550 nm.
9. The polarizing plate according to claim 1 , wherein the second retardation layer is a non-liquid crystal layer.
10. The polarizing plate according to claim 9 , wherein the second retardation layer is formed of a composition for the second retardation layer, the composition comprising at least one selected from the group of a cellulose ester polymer and a styrene polymer, wherein the cellulose ester polymer and the styrene polymer are each independently substituted with at least one selected from the group of a halogen, a nitro group, and an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group, a heteroaryl group, an alkoxy group, and a halogen-containing functional group.
11. The polarizing plate according to claim 10 , wherein a laminate of the first retardation layer and the second retardation layer has a variance in out-of-plane retardation (ΔRth) of 10 nm or less, as calculated according to Equation 1:
ΔRth=|Rth(0 hr)−Rth(120 hr)|, (1)
where Rth(0 hr) denotes an absolute value (unit: nm) of initial Rth of the laminate of the first retardation layer and the second retardation layer, as measured at a wavelength of 550 nm, and Rth(120 hr) denotes an absolute value (unit: nm) of Rth of the laminate of the first retardation layer and the second retardation layer, as measured at a wavelength of 550 nm after irradiation of the laminate with light having a wavelength of 360 nm at a fluence of 720 mJ/cm 2 for 120 hours.
12. The polarizing plate according to claim 1 , wherein a slow axis of the second retardation layer is disposed at an angle of +6° to +8° or −6° to −8° with respect to a transmission axis of the polarizer.
13. The polarizing plate according to claim 1 , further comprising:
a primer layer formed on a lower surface of the first retardation layer.
14. The polarizing plate according to claim 13 , wherein the primer layer contains particles having an average particle diameter (D50) of 1 nm to 500 nm.
15. The polarizing plate according to claim 14 , wherein the particles comprise at least one selected from the group of silicon oxide and titanium oxide.
16. The polarizing plate according to claim 1 , further comprising:
a protective film laminated on an upper surface of the polarizer.
17. An optical display apparatus comprising the polarizing plate according to claim 1 .
18. The polarizing plate according to claim 1 , wherein the thickness of the second retardation layer is 4 μm to 6 μm.
19. The polarizing plate according to claim 1 , wherein the out-of-plane retardation of the second retardation layer is −150 nm to −105 nm at a wavelength of 550 nm.