Transparent conducting film
Provided is a transparent conducting film having a preferable optical property, a preferable electrical property, and further, a superior durability of folding. The transparent conducting film comprises a transparent substrate and a transparent conducting layer formed on at least one of main faces of the transparent substrate, wherein the transparent conducting layer contains a binder resin and a conducting fiber, a cut portion of the transparent conducting film has a straightness of 0.050 mm or less. Preferably, the transparent substrate is a resin film having an elongated resin film or cut out from an elongated film, and can be folded in with a folding axis in the direction perpendicular to the longitudinal direction of the elongated resin film.
1. A transparent conducting film comprising:
a transparent substrate, and
a transparent conducting layer formed on at least one of main faces of the transparent substrate,
wherein a cut portion of the transparent conducting film has a straightness of 0.050 mm or less in accordance with JIS B063, and
when a resistance value (R0) and a resistance value (R) respectively represent resistance values of the transparent conducting film before and after a folding test of 200,000 times of folding using a clamshell type durability tester in which a curvature radius is set to 2.0 mm, the ratio (R/R0) is 2.0 or less.
2. A transparent conducting film according to claim 1 , wherein when a resistance value (R0) and a resistance value (R) respectively represent resistance values of the transparent conducting film before and after a folding test of 200,000 times of folding using a clamshell type durability tester in which a curvature radius is set to 0.5 mm, the ratio (R/R0) is 2.0 or less.
3. A transparent conducting film according to claim 1 , wherein the transparent conducting layer contains at least a binder resin and a conducting fiber, and a protective layer is provided on the transparent conducting layer.
4. A transparent conducting film according to claim 3 , wherein the conducting fiber is a metal nanowire.
5. A transparent conducting film according to claim 4 , wherein the metal nanowire is a silver nanowire.
6. A transparent conducting film according to claim 3 , wherein the binder resin is soluble in alcohol, water, or a mixed solvent of alcohol and water.
7. A transparent conducting film according to claim 3 , wherein the binder resin contains one selected from a group consisting of poly-N-vinylpyrrolidone, hydrophilic cellulose-based resin, butyral resin, and poly-N-vinylacetamide.
8. A transparent conducting film according to claim 1 , wherein the transparent substrate is a cyclo-olefin polymer (COP) film.
9. A transparent conducting film according to claim 8 , wherein the cyclo-olefin polymer (COP) film has a thickness of 1 to 50 μm.
10. A transparent conducting film according to claim 9 , wherein the cyclo-olefin polymer (COP) film has a thickness of 5 to 25 μm.
11. A transparent conducting film according to claim 7 , wherein the cyclo-olefin polymer (COP) film has a glass transition temperature (Tg) of 100 to 170° C.
12. A transparent conducting film according to claim 3 , wherein the protective layer is a cured layer of a curable resin composite, and a content of an aromatic ring-containing compound in a solid content of the curable resin composite is 15% by mass or less.
13. A transparent conducting film according to claim 1 , wherein the transparent substrate is an elongated resin film or a resin film cut out from an elongated resin film, and is foldable with a direction perpendicular to a longitudinal direction of the elongated resin film as a folding axis.
14. A transparent conducting film according to claim 2 , wherein the transparent conducting layer contains at least a binder resin and a conducting fiber, and a protective layer is provided on the transparent conducting layer.
15. A transparent conducting film according to claim 14 , wherein the conducting fiber is a metal nanowire.
16. A transparent conducting film according to claim 15 , wherein the metal nanowire is a silver nanowire.
17. A transparent conducting film according to claim 14 , wherein the binder resin is soluble in alcohol, water, or a mixed solvent of alcohol and water.
18. A transparent conducting film according to claim 14 , wherein the binder resin contains one selected from a group consisting of poly-N-vinylpyrrolidone, hydrophilic cellulose-based resin, butyral resin, and poly-N-vinylacetamide.
19. A transparent conducting film according to claim 14 , wherein the protective layer is a cured layer of a curable resin composite, and a content of an aromatic ring-containing compound in a solid content of the curable resin composite is 15% by mass or less.
20. A transparent conducting film according to claim 2 , wherein the transparent substrate is an elongated resin film or a resin film cut out from an elongated resin film, and is foldable with a direction perpendicular to a longitudinal direction of the elongated resin film as a folding axis.