An ion analyzer includes a reaction chamber into which precursor ions derived from a sample component are introduced, a radical irradiation unit that generates and emits a predetermined type of radicals, a standard substance supply unit that individually supplies kinds of standard substances to the reaction chamber, where activation energy of radical addition reaction is known for each of the kinds of standard substances, and the activation energies are different in magnitude, an ion measurement unit that measures an amount of predetermined product ions generated from precursor ions derived from the standard substance by irradiation with the radicals, and a radical temperature calculation unit that obtains an amount of radicals that caused the radical addition reaction from the amount of the predetermined product ions and obtains a radical temperature based on a relationship between the amount of the radicals obtained for each kind of standard substance and activation energy.
1. An ion analyzer for analyzing product ions generated by irradiating precursor ions with a predetermined kind of radicals, the precursor ions being derived from a sample component, the ion analyzer comprising:
a reaction chamber into which the precursor ions are introduced;
a radical irradiation unit configured to generate the a-predetermined kind of radicals and emit the predetermined kind of radicals to an inside of the reaction chamber;
a standard substance supply unit configured to supply a plurality of kinds of standard substances to the reaction chamber, where respective activation energies of reactions of the predetermined kind of radicals with each of the plurality of kinds of standard substances are known, and the activation energies are different in magnitude;
an ion measurement unit configured to measure an amount of predetermined product ions generated from precursor ions derived from each of the plurality of kinds of standard substances by irradiation with the predetermined kind of radicals; and
a radical temperature calculation unit configured to obtain an amount of the predetermined kind of radicals that caused a radical addition reaction based on the measured amount of the predetermined product ions and obtain a radical temperature based on a relationship between the amount of the predetermined kind of radicals obtained for each of the plurality of kinds of standard substances and the activation energies.
2. The ion analyzer according to claim 1 , wherein the predetermined product ions measured by the ion measurement unit are radical adduct ions obtained by adding the predetermined kind of radicals to the precursor ions.
3. The ion analyzer according to claim 1 , wherein the predetermined kind of radicals are hydrogen radicals, oxygen radicals, or nitrogen radicals.
4. The ion analyzer according to claim 1 , further comprising:
an information storage unit;
a radical irradiation condition input receiving unit configured to receive an input of a radical irradiation condition of the radical irradiation unit; and
a radical temperature information saving unit configured to save radical temperature information in the information storage unit, where the radical irradiation condition and a radical temperature obtained for the radical irradiation condition are associated with each other in the radical temperature information.
5. The ion analyzer according to claim 4 , further comprising:
a radical temperature input receiving unit configured to receive an input of radical temperature of the predetermined kind of radicals with which the precursor ions are irradiated; and
a radical irradiation condition determination unit configured to determine, based on the radical temperature information, a condition under which irradiation with the predetermined kind of radicals is performed.