Positive electrode for lithium ion secondary battery, positive electrode sheet for lithium ion secondary battery, and method for manufacturing the same
Provided is a positive electrode for a lithium ion secondary battery including a metal foil ( 9 ) (current collector), a first mixture layer ( 11 ) which is provided on one surface of the metal foil ( 9 ) and contains a positive electrode active material, and a second mixture layer ( 12 ) which is partially covered by the first mixture layer ( 11 ) and includes, as a main component, particles different from the active material, in which the second mixture layer ( 12 ) is provided on one end ( 11 a ) side of the first mixture layer ( 11 ) in a boundary portion between a formed area of the first mixture layer ( 11 ) and a non-formed area of the first mixture layer ( 11 ), one end ( 12 a ) of the second mixture layer ( 12 ) is positioned between the one surface of the metal foil ( 9 ) and a lower surface of the first mixture layer ( 11 ) in the formed area of the first mixture layer ( 11 ), and the other end ( 12 b ) is positioned in the non-formed area, and the first mixture layer ( 11 ) and the second mixture layer ( 12 ) contain a dispersed conductive substance.
1 . A positive electrode for a lithium ion secondary battery, comprising:
a current collector;
a first mixture layer which is provided on at least one surface of the current collector and contains at least a positive electrode active material, the positive electrode active material being particles; and
a second mixture layer which is partially covered by the first mixture layer and includes, as a main component, particles different from the particles of the positive electrode active material, the particles contained in the second mixture layer being a non-active material,
wherein the second mixture layer is provided on at least one end side of the first mixture layer in a boundary portion between a formed area where the first mixture layer is formed and a non-formed area where the first mixture layer is not formed,
wherein one end of the second mixture layer is positioned between the at least one surface of the current collector and a lower surface of the first mixture layer in the formed area of the first mixture layer, and the other end is positioned in the non-formed area,
wherein the first mixture layer further contains a first conductive substance dispersed therein and the second mixture layer further contains a second conductive substance dispersed therein,
wherein a resistivity of the second mixture layer is in a range of 1 time or more and 100 times or less of a resistivity of the first mixture layer,
wherein the second conductive substance dispersed in the second mixture layer is contained in an amount of 0.1 parts by mass or more and 20.0 parts by mass or less with respect to a total amount of the second mixture layer,
wherein the second mixture layer further contains a binding agent dispersed therein, and an amount of the binding agent contained in the second mixture layer is 0.5 parts by mass or more and 60 parts by mass or less with respect to a total amount of the second mixture layer,
wherein an average particle size of the non-active material particles contained in the second mixture layer as a main component is in a range of 0.1 μm or more and 3.0 μm or less, and
wherein the average particle size is a particle size at an integrated value of 50% in a particle size distribution determined by a laser diffraction/scattering method, and proportions of particles having a particle size of 0.2 μm or less and particles having a particle size of 2 μm or more which are contained in the second mixture layer as the main component are each 10% by volume or less.
2 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein the first conductive substance dispersed in the first mixture layer and the second conductive substance dispersed in the second mixture layer are a same substance.
3 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein the first conductive substance and the second conductive substance includes at least one or more types of carbon materials selected from the group consisting of carbon nanotube, carbon nanohorn, graphene, carbon nanobrush, carbon black, acetylene black, and Ketjenblack.
4 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein a maximum thickness of the second mixture layer is thinner than a minimum thickness of the first mixture layer.
5 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein an average thickness of the second mixture layer is in a range of 3 μm or more and 90% or less of an average thickness of the first mixture layer.
6 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein a density of the second mixture layer is in a range of 0.5 g/cm3 or more and 3.0 g/cm3 or less.
7 . The positive electrode for the lithium ion secondary battery according to claim 6 ,
wherein the density of the second mixture layer is in a range of 0.9 g/cm3 or more and 3.0 g/cm3 or less.
8 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein the particles contained in the second mixture layer as a main component include one or more materials selected from the group consisting of alumina, silica, a thermoplastic resin, an ionizing radiation-curable resin, a thermosetting resin, and an insulating ink.
9 . The positive electrode for the lithium ion secondary battery according to claim 1 ,
wherein the first mixture layer contains a binding agent,
wherein the binding agent contained in the second mixture layer is of the same type as the binding agent contained in the first mixture layer, and
wherein a proportion of the binding agent contained in the second mixture layer to a total amount of the second mixture layer is larger than a proportion of the binding agent contained in the first mixture layer to a total amount of the first mixture layer.
10 . The positive electrode for the lithium ion secondary battery according to claim 1 , wherein the amount of the second conductive substance dispersed in the second mixture layer is more than 5 parts by mass and equal to or less than 20.0 parts by mass with respect to the total amount of the second mixture layer.
11 . A positive electrode sheet for a lithium ion secondary battery, having
a first mixture layer which contains at least a positive electrode active material, the positive electrode active material being particles, and
a second mixture layer which is partially covered by the first mixture layer and includes, as a main component, non-active material particles different from the positive electrode active material formed, on both surfaces or one surface of a current collector, which is a strip-shaped sheet wound around a roll, continuously in a lengthwise direction of the sheet, and formed in parallel with each other and parallel to the lengthwise direction of the sheet, and
at least one end of the first mixture layer on a widthwise direction side of the sheet is formed to cover a part of the second mixture layer,
wherein the first mixture layer further contains a first conductive substance dispersed therein and the second mixture layer further contains a second conductive substance dispersed therein,
wherein a resistivity of the second mixture layer is in a range of 1 time or more and 100 times or less of a resistivity of the first mixture layer,
wherein the second conductive substance dispersed in the second mixture layer is contained in an amount of 0.1 parts by mass or more and 20.0 parts by mass or less with respect to a total amount of the second mixture layer,
wherein the second mixture layer further contains a binding agent dispersed therein, and an amount of the binding agent contained in the second mixture layer is 0.5 parts by mass or more and 60 parts by mass or less with respect to a total amount of the second mixture layer,
wherein an average particle size of the non-active material particles contained in the second mixture layer as a main component is in a range of 0.1 μm or more and 3.0 μm or less, and
wherein the average particle size is a particle size at an integrated value of 50% in a particle size distribution determined by a laser diffraction/scattering method, and proportions of particles having a particle size of 0.2 μm or less and particles having a particle size of 2 μm or more which are contained in the second mixture layer as the main component are each 10% by volume or less.
12 . A positive electrode sheet for a lithium ion secondary battery, having
a first mixture layer which contains at least a positive electrode active material, the positive electrode active material being particles, and
a second mixture layer which is partially covered by the first mixture layer and includes, as a main component, non-active material particles different from the positive electrode active material intermittently formed on both surfaces or one surface of a current collector, which is a strip-shaped sheet wound around a roll, and formed in a lengthwise direction of the sheet,
wherein the second mixture layer is provided on at least one end side of the first mixture layer in the lengthwise direction of the sheet in a boundary portion between a formed area where the first mixture layer is formed and a non-formed area where the first mixture layer is not formed, and
one end of the second mixture layer is positioned between the at least one surface of the current collector and a lower surface of the first mixture layer in the formed area of the first mixture layer, and the other end is positioned in the non-formed area, and
wherein the first mixture layer further contains a first conductive substance dispersed therein and the second mixture layer further contains a second conductive substance dispersed therein,
wherein a resistivity of the second mixture layer is in a range of 1 time or more and 100 times or less of a resistivity of the first mixture layer,
wherein the second conductive substance dispersed in the second mixture layer is contained in an amount of 0.1 parts by mass or more and 20.0 parts by mass or less with respect to a total amount of the second mixture layer,
wherein the second mixture layer further contains a binding agent dispersed therein, and an amount of the binding agent contained in the second mixture layer is 0.5 parts by mass or more and 60 parts by mass or less with respect to a total amount of the second mixture layer,
wherein an average particle size of the non-active material particles contained in the second mixture layer as a main component is in a range of 0.1 μm or more and 3.0 μm or less, and
wherein the average particle size is a particle size at an integrated value of 50% in a particle size distribution determined by a laser diffraction/scattering method, and proportions of particles having a particle size of 0.2 μm or less and particles having a particle size of 2 μm or more which are contained in the second mixture layer as the main component are each 10% by volume or less.