Exhaust gas cleaning catalyst structure and production method therefor
Provided are an exhaust gas purifying catalyst structure that inhibits foil elongation and improves structural durability and a production method therefor. The exhaust gas purifying catalyst structure has a metal support configured by using an mantle and a metal foil provided in the mantle and forming an exhaust gas flow path, and a catalyst layer provided on a surface forming the flow path of the metal foil, wherein the catalyst layer contains a noble metal, an OSC material containing cerium and a rare earth element other than cerium (non-Ce rare earth element), and alumina, and a content of the non-Ce rare earth element with respect to 100% by mass of the catalyst layer is 2.52% by mass or more and 4.62% by mass or less in terms of an oxide.
1. An exhaust gas purifying catalyst structure comprising:
a metal support comprising a mantle and a metal foil provided inside the mantle and forming an exhaust gas flow path; and
a catalyst layer provided on a surface forming the flow path of the metal foil, wherein
the catalyst layer comprises a noble metal, an OSC material comprising cerium and a rare-earth element other than cerium (non-Ce rare-earth element), and alumina, and a content of the non-Ce rare-earth element with respect to 100% by mass of the catalyst layer is 2.52% by mass or more and 4.62% by mass or less in terms of an oxide,
the metal foil is made of stainless steel comprising aluminum, and
a content of aluminum in the metal foil is 3.0% by mass or more and 6.0% by mass or less.
2. The exhaust gas purifying catalyst structure according to claim 1 , wherein the non-Ce rare-earth element comprises neodymium, and a content of neodymium with respect to 100% by mass of the catalyst layer is 1.48% by mass or more and 4.20% by mass or less in terms of an oxide.
3. The exhaust gas purifying catalyst structure according to claim 2 , wherein the non-Ce rare-earth element comprises lanthanum, and a content of lanthanum with respect to 100% by mass of the catalyst layer is 0.42% by mass or more and 1.23% by mass or less in terms of an oxide.
4. The exhaust gas purifying catalyst structure according to claim 1 , wherein the non-Ce rare-earth element comprises lanthanum, and a content of lanthanum with respect to 100% by mass of the catalyst layer is 0.42% by mass or more and 1.23% by mass or less in terms of an oxide.
5. The exhaust gas purifying catalyst structure according to claim 1 , wherein the noble metal comprises palladium and rhodium.
6. The exhaust gas purifying catalyst structure according to claim 1 , wherein the metal support comprises a flat metal foil and a corrugated metal foil.
7. The exhaust gas purifying catalyst structure according to claim 1 , a ratio of a content (% by mass) of the non-Ce rare-earth element in the catalyst layer to the content (% by mass) of aluminum (Al) in the metal foil (non-Ce rare-earth element/Al) is 0.46 or more and 0.84 or less.
8. The exhaust gas purifying catalyst structure according to claim 1 , wherein a thickness of the metal foil is 20 μm or more and 60 μm or less.
9. The exhaust gas purifying catalyst structure according to claim 1 , wherein the exhaust gas purifying catalyst structure is for saddle-ridden type vehicles.
10. A method for producing the exhaust gas purifying catalyst structure according to claim 1 , comprising:
a step of adding alumina to a solution comprising a first noble metal and supporting the first noble metal on the alumina to form a first slurry comprising the alumina supporting the first noble metal, adding the OSC material comprising the cerium and the rare-earth element other than cerium (non-cerium rare-earth element) and a solution comprising a second noble metal to the first slurry in this order, and supporting the second noble metal on the OSC material to form a second slurry further comprising the OSC material supporting the second noble metal; and
a step of attaching the second slurry to the metal support comprising the mantle and the metal foil provided inside the mantle and forming the exhaust gas flow path to form the catalyst layer, wherein
the catalyst layer comprises the non-Ce rare-earth element in a content with respect to 100% by mass of the catalyst layer of 2.52% by mass or more and 4.62% by mass or less in terms of an oxide.
11. The method for producing the exhaust gas purifying catalyst structure according to claim 10 , wherein the first noble metal is palladium and the second noble metal is rhodium.
12. The method for producing the exhaust gas purifying catalyst structure according to claim 10 , wherein the non-Ce rare-earth element in the catalyst layer comprises neodymium, and a content of neodymium with respect to 100% by mass of the catalyst layer is 1.48% by mass or more and 4.20% by mass or less in terms of an oxide.
13. The method for producing the exhaust gas purifying catalyst structure according to claim 10 , wherein the non-Ce rare-earth element in the catalyst layer comprises lanthanum, and a content of lanthanum with respect to 100% by mass of the catalyst layer is 0.42% by mass or more and 1.23% by mass or less in terms of an oxide.
14. The method for producing the exhaust gas purifying catalyst structure according to claim 10 , a ratio of a content (% by mass) of the non-Ce rare-earth element in the catalyst layer to a content (% by mass) of aluminum (Al) in the metal foil (non-Ce rare-earth element/Al) is 0.46 or more and 0.84 or less.