Curing composition
The present disclosure relates to a curing composition comprising: a) a condensation product of at least one carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups and/or at least one ester derived from a carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups; and at least one polyoxyalkyleneamine, wherein the polyoxyalkyleneamine includes: I) at least two oxyalkylene moieties; and II) at least two primary amino groups; and b) at least one amine having at least one amino group. Also provided are an adhesive composition comprising the curing composition, usage of the adhesive, a turbine blade for wind energy comprising the adhesive composition, and a method for manufacturing the curing composition.
1. A curing composition, consisting of:
a) a condensation product of:
at least one carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups and/or at least one ester derived from a carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups; and
at least one polyoxyalkyleneamine, wherein the polyoxyalkyleneamine includes:
I) at least two oxyalkylene moieties; and
II) at least two primary amino groups,
wherein the carboxylic acid and polyoxyalkyleneamine are within a mole ratio of 0.01-0.8:1; and
b) at least one amine having at least one primary amino group.
2. The curing composition according to claim 1 , wherein the carboxylic acid is a dimerized fatty acid.
3. The curing composition according to claim 1 , wherein the amine is cyclic.
4. The curing composition according to claim 1 , wherein the amine has at least two amino groups.
5. The curing composition according to claim 1 , wherein the carboxylic acid is a dimerized C16-C20 fatty acid.
6. The curing composition according to claim 1 , wherein the oxyalkylene moieties include at least one oxyethylene, oxypropylene, or oxybutylene moiety.
7. The curing composition according to claim 1 , wherein the polyoxyalkyleneamine includes
wherein x is an integer ranging from 2 to 70.
8. The curing composition according to claim 1 , wherein the polyoxyalkyleneamine includes three primary amino groups.
9. The curing composition according to claim 1 , the polyoxyalkyleneamine including
and wherein,
R is a radical selected from H, CH 3 , CH 2 CH 3 , CH 2 CH 2 CH 3 , or CH (CH 3 ) 2 ;
n is 0 or 1;
x, y, and z are integers independently ranging from 1 to 30; and
the sum of x, y, and z is ranging from 3 to 90.
10. The curing composition according to claim 1 , wherein the carboxylic acid and the polyoxyalkyleneamine are within a mole ratio of 0.1-0.5:1.
11. The curing composition according to claim 1 , wherein the amine has a weight percentage of 1-99 wt. % in the curing composition.
12. The curing composition according to claim 1 , wherein the amine includes at least one five-membered or six-membered ring.
13. The curing composition according to claim 1 , wherein the amine includes one or more selected from the group consisting of:
14. An adhesive composition comprising the curing composition according to claim 1 and an epoxy resin.
15. A turbine blade for wind energy comprising the adhesive composition according to claim 14 .
16. A method for manufacturing a curing composition, comprising:
1) heating
a) at least one carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups and/or at least one ester derived from a carboxylic acid having 20-60 carbon atoms and at least two carboxyl groups; and
b) at least one polyoxyalkyleneamine, wherein the polyoxyalkyleneamine includes at least one oxyalkylene moiety and at least two primary amino groups to a temperature of 120° C. to 280° C. for 0.5 to 10 hours, wherein the carboxylic acid and polyoxyalkyleneamine are within a mole ratio of 0.1-0.4; and
2) mixing the condensation product with at least one amine having at least one primary amino group.
17. The method according to claim 16 , wherein the heating condition is under a non-oxidative atmosphere.
18. The method according to claim 16 , further comprising mixing the condensation product and the at least one amine with one or more additives selected from the group consisting of fillers, reinforcing agents, coupling agents, toughening agents, defoamers, dispersants, lubricants, colorants, marking materials, dyes, pigments, IR absorbers, antistats, anti-blocking agents, nucleating agents, crystallization accelerators, crystallization delayers, conductivity additives, carbon black, graphite, carbon nanotubes, graphene, desiccants, de-moulding agents, levelling auxiliaries, flame retardants, separating agents, optical lighteners, rheology additives, photochromic additives, softeners, adhesion promoters, anti-dripping agents, metallic pigments, stabilizers, metal glitters, metal coated particles, porosity inducers, plasticizers, glass fibers, nanoparticles, and flow assistants.
19. The method according to claim 18 , wherein the one or more additives constitute a proportion of not greater than 90 wt. %, with respect to a total weight of the curing composition.
20. The method according to claim 16 , further comprising mixing the condensation product and the at least one amine with one or more catalysts.