Thermoplastic compositions, methods of their manufacture, and articles thereof
A thermoplastic composition includes: 40 to 75 wt % of a poly(carbonate-siloxane-arylate); 5 to 45 wt % of a poly(carbonate-siloxane) present in an amount effective to provide 0.75 to 7 wt % of siloxane units; 10 to 40 wt % of a polycarbonate homopolymer; 5 to 15 wt % of an organophosphorus compound in an amount effective to provide 0.1 to 1 wt % of phosphorus; and optionally, 0.1 to 10 wt % of an additive composition. The thermoplastic composition has a melt volume flow rate of greater than 6 cm 3 /10 min. An article molded from the thermoplastic composition has a 2-minute integrated heat release rate of less than or equal to 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 and a notched Izod impact resistance of greater than 30 kJ/m 2 or greater than 700 J/m 2 .
1. A thermoplastic composition comprising: 40 to 75 wt % of a poly(carbonate-siloxane-arylate);
5 to 45 wt % of a poly(carbonate-siloxane) present in an amount effective to provide 0.75 to 7 wt % of siloxane units;
10 to 40 wt % of a polycarbonate homopolymer;
5 to 15 wt % of an organophosphorus compound in an amount effective to provide 0.1 to 1 wt % of phosphorus; and
optionally, 0.1 to 10 wt % of an additive composition,
wherein each amount is based on the total weight of the poly(carbonate-siloxane-arylate), poly(carbonate-siloxane), polycarbonate homopolymer, flame retardant, and optional additive composition, which does not exceed 100%; and
Wherein
the thermoplastic composition has a melt volume flow rate of greater than 6 cm 3 /10 min when measured in accordance with the ISO-1133-1:2011 standard at 300° C. under a load of 1.2 kg with a residence time of 300 seconds; and
an article molded from the thermoplastic composition has
a 2-minute integrated heat release rate of less than or equal to 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 as measured using the method according to Part IV, OSU Heat Release of FAR/JAR 25.853,
Amendment 25-116; and
a notched Izod impact resistance of greater than 30 KJ/m2 determined in accordance with ISO 180:2000 on notched 4 millimeter thick ISO bars at 23° C., with a 5.5 J hammer;
a notched Izod impact resistance of greater than 700 J/m2 measured on notched 3.2 mm bars at 23° C., in accordance with the ASTM-D256-10 (2018) standard.
2. The thermoplastic composition of claim 1 , wherein the poly(carbonate-siloxane-arylate) comprises:
0.2 to 10 wt % of siloxane units based on the total weight of the poly(carbonate-siloxane-arylate);
50 to 99.6 mol % arylate units, and
0.2 to 49.8 mol % carbonate units, each based on the sum of the moles of the siloxane units, the arylate units, and carbonate units in the poly(carbonate-siloxane-arylate).
3. The thermoplastic composition of claim 1 , wherein the poly(carbonate-siloxane) comprises bisphenol A carbonate units and polydimethylsiloxane units.
4. The thermoplastic composition of claim 1 , wherein the polycarbonate homopolymer comprises a linear bisphenol A polycarbonate homopolymer having a weight average molecular weight of 15,000 to 20,000 Dalton, as measured by gel permeation chromatography (GPC) using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A polycarbonate references.
5. The thermoplastic composition of claim 1 , wherein the polycarbonate homopolymer comprises a branched polycarbonate comprising bisphenol A carbonate units and moieties derived from a branching agent comprising trimellitic acid, trimellitic anhydride, tris-phenol TC (1,3,5-tris((p-hydroxyphenyl)isopropyl)benzene), tris-phenol PA (4(4(1,1-bis(p-hydroxyphenyl)-ethyl) alpha, alpha-dimethyl benzyl)phenol), 4-chloroformyl phthalic anhydride, trimesic acid, benzophenone tetracarboxylic acid, or a combination thereof.
6. The thermoplastic composition of claim 5 , wherein the branched polycarbonate comprises bisphenol A carbonate units and 3 to 10 mol %, based on the total moles of the branched polycarbonate, of a moiety derived from 1,1,1-tris(4-hydroxyphenyl)ethane; and optionally the branched polycarbonate has a weight average molecular weight of 28,000 to 40,000 Dalton, as measured by gel permeation chromatography (GPC) using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A polycarbonate references.
7. The thermoplastic composition of claim 1 , wherein the aromatic organophosphorus compound is of the formula
wherein
R 16 , R 17 , R 18 and R 19 are each independently C 1-8 alkyl, C 5-6 cycloalkyl, C 6-20 aryl, or C 7-12 arylalkylene, each optionally substituted by C 1-12 alkyl, and
X is a mono- or poly-nuclear aromatic C 6-30 moiety or a linear or branched C 2-30 aliphatic moiety, each of which can be OH-substituted and can contain up to 8 ether bonds, provided that at least one of R 16 , R 17 , R 18 , R 19 , and X is aromatic,
n is each independently 0 or 1, and
q is from 0.5 to 30.
8. The thermoplastic composition of claim 1 , wherein the aromatic organophosphorus compound is of the formula
wherein q is 1 to 5.
9. The thermoplastic composition of claim 1 , comprising
60 to 65 wt % of the poly(carbonate-siloxane-arylate), wherein the poly(carbonate-siloxane-arylate) comprises, based on the total weight of the poly(carbonate-siloxane-arylate)
0.2 to 10 wt % of siloxane units of the formula
wherein E has an average value of 5 to 20,
50 to 99.6 mol % isophthalate-terephthalate-resorcinol ester units, and
0.2 to 49.8 mol % bisphenol A carbonate units;
5 to 15 wt % of the poly(carbonate-siloxane), wherein the poly(carbonate-siloxane) has a siloxane content of 15 to 25 wt % based on the total weight of the poly(carbonate-siloxane), and comprises
bisphenol A carbonate units, and
siloxane units of the formula
wherein E has an average value of 20 to 80; and
15 to 25 wt % of the polycarbonate homopolymer, wherein the polycarbonate homopolymer comprises a branched polycarbonate comprising bisphenol A carbonate units and 3 to 10 mol %, based on the total moles of the branched polycarbonate, of a moiety derived from 1,1,1-tris(4-hydroxyphenyl)ethane, and endcapping groups derived from p-cyanophenol; and the branched polycarbonate has a weight average molecular weight of 30,000 to 35,000 Dalton, as measured by gel permeation chromatography (GPC) using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A polycarbonate references;
5 to 8 wt % of the organophosphorus compound, wherein the organophosphorus compound has the formula
wherein q is 1 to 5; and
0.1 to 3 wt % of the additive composition, wherein the additive composition comprises a mold release agent and a heat stabilizer.
10. The thermoplastic composition of claim 1 , comprising
60 to 65 wt % of the poly(carbonate-siloxane-arylate), wherein the poly(carbonate-siloxane-arylate) comprises, based on the total weight of the poly(carbonate-siloxane-arylate),
0.2 to 10 wt % siloxane units of the formula
wherein E has an average value of 5 to 20,
50 to 99.6 mol % isophthalate-terephthalate-resorcinol ester units, and
0.2 to 49.8 mol % bisphenol A carbonate units;
5 to 15 wt % of the poly(carbonate-siloxane), wherein the poly(carbonate-siloxane) has a siloxane content of 15 to 25 wt % based on the total weight of the poly(carbonate-siloxane), and comprises
bisphenol A carbonate units, and
siloxane units of the formula
wherein E has an average value of 20 to 80;
15 to 25 wt % of the polycarbonate homopolymer, wherein the polycarbonate homopolymer comprises a linear bisphenol A polycarbonate homopolymer having a weight average molecular weight of 15,000 to 20,000 Dalton, as measured by gel permeation chromatography (GPC) using a crosslinked styrene-divinylbenzene column and calibrated to bisphenol A polycarbonate references;
5 to 8 wt % of the organophosphorus compound, based on the total weight of the thermoplastic composition wherein the organophosphorus compound has the formula
wherein q is 1 to 5 to 5; and
0.1 to 3 wt % of the additive composition, wherein the additive composition comprises a mold release agent and a heat stabilizer.
11. The thermoplastic composition of claim 1 , further comprising a mineral filler, glass, carbon, or a combination comprising at least one of the foregoing; and optionally wherein the mineral filler, glass, carbon, or a combination comprising at least one of the foregoing are present in an amount of 5 to 45 wt %, based on the total weight of the thermoplastic composition.
12. A powder, filament, or composite comprising the thermoplastic composition of claim 1 .
13. A composite comprising the thermoplastic composition of claim 1 , and a fibrous material comprising glass fiber, carbon fiber, basalt fiber; optionally wherein the fibrous material is a woven fiber, a non-woven fiber, or a uni-directional fiber tape.
14. An article comprising the composition of claim 1 , selected from a molded article, a thermoformed article, an extruded film, an extruded sheet, a foamed article, a layer of a multi-layer article, a substrate for a coated article, and a substrate for a metallized article.
15. A method of manufacture of an article, the method comprising additively manufacturing the article using a powder or filament comprising the thermoplastic compositions of claim 1 .