Gasoline fuel composition
Use of a gasoline fuel composition comprising (a) a major portion of gasoline blending components (b) from 0 vol % to 25 vol % of oxygenated hydrocarbon and (c) from 0.01 vol % to 5 vol % of a diene compound for the purpose of increasing the injection duration at the end of a 48 hour deposit formation phase in a direct injection spark ignition engine by at least 10%.
1. A method for increasing the injection duration at the end of a 48 hour deposit formation phase in a direct injection spark ignition engine by at least 10%, wherein the method comprises fueling the direct injection engine with a gasoline fuel composition comprising (a) greater than 50% m/m of gasoline blending components comprising a blend of (i) saturated hydrocarbons comprising C5 paraffins selected from isopentane and n-pentane, and mixtures thereof, wherein the C5 paraffins are present at a level of 10 vol % to 20 vol %, based on the gasoline fuel composition, (ii) aromatic hydrocarbons selected from toluene and xylene, and mixtures thereof, wherein the aromatic hydrocarbons are present at a level of 20 vol % to 40 vol %, based on the gasoline fuel composition, (iii) heavy reformate, (iv) alkylate or alkylate blend and (v) LCC; (b) from 1 vol % to 10 vol % of oxygenated hydrocarbon wherein the oxygenated hydrocarbon is ethanol and (c) from 0.15 vol % to 3 vol % of a diene compound, wherein the 48 hour deposit formation phase is the 48 hour dirty-up phase of the CEC TDG-F-113 test.
2. A method according to claim 1 wherein the injection duration at the end of a 48 hour deposit formation phase in a direct injection spark ignition engine is increased by at least 15%.
3. A method according to claim 1 wherein the injection duration at the end of a 48 hour deposit formation phase in a direct injection spark ignition engine is increased by at least 20%.
4. A method according to claim 1 wherein the gasoline fuel composition comprises from 0.2 to 3 vol % of the diene compound.
5. A method according to claim 1 wherein the diene compound is selected from 1,3-butadiene, 2-methyl-1,3-butadiene (isoprene), 1,3-pentadiene, 1,3-hexadiene, 1,5-hexadiene, 2,4-hexadiene, 2-methyl-1,3-pentadiene, 2-methyl-2,4-pentadiene, dicyclopentadiene, cyclopentadiene, 7-methyl-3-methylen-1,6-octadiene, and mixtures thereof.
6. A method according to claim 1 wherein the diene compound is dicyclopentadiene.
7. A method according to claim 1 wherein the gasoline fuel composition meets the EN228 specification for gasoline fuels.
8. A method according to claim 1 wherein the gasoline fuel composition comprises from 0.2 vol % to 0.8 vol % of the diene compound.