Polyester film, laminated film, and use thereof
Provided are a polyester film, a laminated film, and the like for protecting an organic EL module of a foldable display each of which is free of occurrence of a crack at a folding portion thereof, in order to provide a foldable display excellent in mass productivity, and free of a risk of causing distortion in an image displayed at a folding portion thereof after being repeatedly folded. The polyester film for protecting an organic EL module of a foldable display satisfies the following conditions: (1) a refractive index in a bending direction is from 1.590 to 1.620; (2) a refractive index in a folding portion direction is from 1.670 to 1.700; (3) a refractive index in a thickness direction is 1.520 or less; and (4) a density is 1.380 g/cm 3 or more, wherein the bending direction refers to a direction orthogonal to a folding portion of the polyester film at a time when the polyester film is folded.
1. A polyester film for protecting an organic EL module of a foldable display, the polyester film satisfying the following conditions:
(1) a refractive index in a bending direction is from 1.591 to 1.606;
(2) a refractive index in a folding portion direction is from 1.670 to 1.700;
(3) a refractive index in a thickness direction is 1.520 or less; and
(4) a density is 1.380 g/cm 3 or more,
wherein the bending direction refers to a direction orthogonal to a folding portion of the polyester film at a time when the polyester film is folded,
wherein the polyester film is a biaxially stretched polyethylene terephthalate film,
wherein the polyester film comprises an easy-to-adhere layer on at least one surface thereof and a hard coating layer having a thickness of from 1 μm to 50 μm, and
wherein the hard coating layer is present on the easy-to-adhere layer on at least one surface of the polyester film.
2. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the polyester film has an elastic modulus in the bending direction of 2.7 GPa or less, and an elastic modulus in the folding portion direction of 4.5 GPa or more.
3. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the polyester film has a total light transmittance of 85% or more, a haze of 3% or less, and a maximum heat shrinkage ratio of 6% or less.
4. A laminated film for protecting an organic EL module of a foldable display, the laminated film comprising:
the polyester film of claim 1 ; and
an adhesive layer on at least one surface of the polyester film.
5. The laminated film for protecting an organic EL module of a foldable display according to claim 4 , wherein the adhesive layer has a thickness of from 1 μm to 50 μm.
6. A foldable display comprising the polyester film for protecting an organic EL module of a foldable display of claim 1 as a protective film of an organic EL module, wherein the protective film of the organic EL module is a single film continuous across a folding portion of the foldable display.
7. A foldable display comprising the laminated film for protecting an organic EL module of a foldable display of claim 4 as a protective film of an organic EL module, wherein the protective film of the organic EL module is a single film continuous across a folding portion of the foldable display.
8. A mobile device comprising the foldable display of claim 6 .
9. A mobile device comprising the foldable display of claim 7 .
10. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the easy-to-adhere layer is applied in an amount from 0.005 g/m 2 to 0.20 g/m 2 .
11. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the easy-to-adhere layer comprises at least one water-soluble or water-dispersible resin selected from the group consisting of a polyester-based resin, a polyether polyurethane-based resin, a polyester polyurethane resin, a polycarbonate polyurethane resin, and an acrylic resin.
12. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the easy-to-adhere layer comprises at least one water-soluble or water-dispersible compound selected from the group consisting of a melamine compound, an isocyanate compound, an oxazoline compound, an epoxy compound, and a carbodiimide compound.
13. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the easy-to-adhere layer comprises fine particles with an average particle diameter of 2 μm or less.
14. The polyester film for protecting an organic EL module of a foldable display according to claim 13 , wherein the fine particles are at least one member selected from the group consisting of titanium dioxide, barium sulfate, calcium carbonate, calcium sulfate, silica, alumina, talc, kaolin, clay, calcium phosphate, mica, hectorite, zirconia, tungsten oxide, lithium fluoride, calcium fluoride, styrene-based particles, acrylic particles, melamine-based particles, benzoguanamine-based particles, and silicone-based particles.
15. The polyester film for protecting an organic EL module of a foldable display according to claim 1 , wherein the hard coating layer comprises at least one member selected from the group consisting of an acrylic resin, a siloxane-based resin, an inorganic hybrid-based resin, a urethane acrylate-based resin, a polyester acrylate-based resin, and an epoxy-based resin.
16. A foldable display comprising a polarizer and the polyester film for protecting an organic EL module of a foldable display of claim 1 as a protective film of an organic EL module, wherein the polyester film is provided on at least the visible side surface of the polarizer and the slow axial direction of the polyester film is in the range of 0°±10° or 90°±10° with the absorption axis direction of the polarizer.