IP Library Granted Patent US 12,637,747
Granted Patent B2
US 12,637,747 · App. 17/615,739 · Granted May 26, 2026

Non-heat treated wire rod with excellent wire drawability and impact toughness and manufacturing method therefor

Inventors: Dong Jun Mun (Pohang-si, KR); In-Gyu Park (Pohang-si, KR); Se Hong Min (Pohang-si, KR)
Assignee: POSCO CO., LTD
C22C38/38C21D8/06C21D9/525C22C38/02C22C38/06C22C38/22C22C38/24C22C38/26C21D2211/005C21D2211/009
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Quick Facts
Patent No.
US 12,637,747
App. No.
17/615,739
Granted
May 26, 2026
Kind
B2
Abstract

Provided are a non-quenched and tempered wire rod having excellent drawability and impact toughness suitable for materials for automobiles or mechanical parts and a method of manufacturing the same. According to an embodiment of the present disclosure, the non-quenched and tempered wire rod includes, in percent by weight (wt %), 0.05 to 0.35% of carbon (C), 0.05 to 0.5% of silicon (Si), 0.5 to 2.0% of manganese (Mn), 1.0% or less of chromium (Cr), 0.03% or less of phosphorus (P), 0.03% or less of sulfur (S), 0.01 to 0.07% of soluble aluminum (sol.Al), 0.01% or less of nitrogen (N), at least one of 0.1% or less of niobium (Nb), 0.5% or less of vanadium (V), and 0.1% or less of titanium (Ti), and the remainder of iron (Fe) and inevitable impurities, and includes a ferrite-pearlite layered structure, as a microstructure, in a rolling direction.

Claims (189)

1 . A non-quenched and tempered wire rod comprising: in percent by weight (wt %), 0.05 to 0.35% of carbon (C), 0.05 to 0.5% of silicon (Si), 0.5 to 2.0% of manganese (Mn), 1.0% or less of chromium (Cr), 0.03% or less of phosphorus (P), 0.03% or less of sulfur(S), 0.01 to 0.07% of soluble aluminum (sol.Al), 0.01% or less of nitrogen (N), at least one of 0.1% or less of niobium (Nb), 0.5% or less of vanadium (V), and 0.1% or less of titanium (Ti), and the remainder of iron (Fe) and inevitable impurities; and

a ferrite-pearlite layered structure, as a microstructure, in a rolling direction,

wherein an average thickness of a ferrite band in an L cross-section, as a cross-section parallel to the rolling direction, is from 10 μm to 23 μm,

wherein an average room temperature impact toughness is from 160 J to 253 J at 35% drawing, from 153 J to 221 J at 45% drawing, and from 162 J to 224 J at 55% drawing,

wherein a difference between a maximum hardness and a minimum hardness in a C cross-section perpendicular to the rolling direction, is 30 Hv or less,

wherein an average particle diameter of the ferrite in the C cross-section is from 3 μm to 20 μm, and

wherein an average lamellar space of the pearlite is from 0.03 μm to 0.3 μm,

wherein the wire rod satisfies I max −I min <40 J in 30% to 60% drawing,

wherein I max is a maximum value of average room temperature impact toughness after drawing and I min is a minimum value of average room temperature impact toughness after drawing.

2 . The non-quenched and tempered wire rod of claim 1 , wherein a fraction of the ferrite is from 30% to 90%.

3 . The non-quenched and tempered wire rod of claim 1 , wherein a carbon equivalent C eq represented by the following formula is from 0.4 to 0.6:

Ceq

=

[

C

]

+

[

Si

]

/

9

+

[

Mn

]

/

5

+

[

Cr

]

/

12

(wherein [C], [Si], [Mn], and [Cr] are contents (wt %) of corresponding elements, respectively).

4 . A method of manufacturing the non-quenched and tempered wire rod of claim 1 , the method comprising: preparing a billet comprising, in percent by weight (wt %), 0.05 to 0.35% of carbon (C), 0.05 to 0.5% of silicon (Si), 0.5 to 2.0% of manganese (Mn), 1.0% or less of chromium (Cr), 0.03% or less of phosphorus (P), 0.03% or less of sulfur(S), 0.01 to 0.07% of soluble aluminum (sol.Al), 0.01% or less of nitrogen (N), at least one of 0.1% or less of niobium (Nb), 0.5% or less of vanadium (V), and 0.1% or less of titanium (Ti), and the remainder of iron (Fe) and inevitable impurities;

reheating the billet at a reheating temperature Tr satisfying Equation (2) below;

rolling the reheated billet into a wire rod; and

coiling the rolled wire rod followed by cooling, and thereby producing the non-quenched and tempered wire rod of claim 1 ;

wherein the rolling of the reheated billet into the wire rod comprises rolling the reheated billet at a final rolling temperature Tf satisfying Equation (3) below,

T

1

Tr

1200

°

C

.

(

2

)

T

2

Tf

T

3

(

3

)

(

wherein

T

1

=

757

+

606

[

C

]

+

80

[

Nb

]

/

[

C

]

+

1023

[

Nb

]

+

330

[

V

]

,

T

2

=

955

-

396

[

C

]

+

24.6

[

Si

]

-

68.1

[

Mn

]

-

24.8

[

Cr

]

-

36.1

[

Nb

]

-

20.7

[

V

]

,

T

3

=

734

+

465

[

C

]

-

355

[

Si

]

+

360

[

Al

]

+

891

[

Ti

]

+

6800

[

Nb

]

-

650

f

[

Nb

]

+

730

[

V

]

-

2321

[

V

]

,

and

[C], [Si], [Mn], [Cr], [Al], [Ti], [Nb], and [V] are contents (wt %) of corresponding elements, respectively).

5 . The method of claim 4 , wherein the cooling comprises cooling the wire rod at an average rate of 0.1° C./s to 2° C./s.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061777/0937 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0730 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 2, 2021
From: MUN, DONG JUN; PARK, IN-GYU; MIN, SE HONG
To: POSCO
Reel/Frame 058294/0845 →
Continuity (1)
Related Publication 20220235443A1 · Jul 28, 2022
References Cited (39)
US 10889876B2 · Mun et al. · 2021 [cited by applicant]
US 10988821B2 · Mun et al. · 2021 [cited by applicant]
US 20180298464A1 · Mun · 2018 [cited by examiner]
US 20180305787A1 · Mun et al. · 2018 [cited by applicant]
CN 105671439A · 2016 [cited by applicant]
CN 106350734A · 2017 [cited by applicant]
CN 108350548A · 2018 [cited by applicant]
CN 108350549A · 2018 [cited by applicant]
JP S5356120A · 1978 [cited by applicant]
JP S62199750A · 1987 [cited by applicant]
JP H03183739A · 1991 [cited by applicant]
JP H11229090A · 1999 [cited by applicant]
JP 2003113444A · 2003 [cited by applicant]
JP 2003183733A · 2003 [cited by applicant]
JP 2004060049A · 2004 [cited by applicant]
JP 2004137542A · 2004 [cited by applicant]
JP 2017043835A · 2017 [cited by applicant]
JP 2018197375A · 2018 [cited by applicant]
JP 2018537584A · 2018 [cited by applicant]
JP 2019500489A · 2019 [cited by applicant]
JP 2019502815A · 2019 [cited by applicant]
KR 1020010060772A · 2001 [cited by applicant]
KR 1020160068048A · 2016 [cited by applicant]
KR 1020160068120A · 2016 [cited by applicant]
KR 20160068048A · 2016 [cited by examiner]
KR 20160068120A · 2016 [cited by examiner]
KR 1020170056059A · 2017 [cited by applicant]
KR 1020170072995A · 2017 [cited by applicant]
KR 1020200062439A · 2020 [cited by applicant]
Influence of Degree of Cold-Drawing on the Mechanical Properties of Low Carbon Steel (Year: 2011). [cited by examiner]
Japanese Office Action dated Jul. 4, 2023 issued in Japanese Patent Application No. 2021-574892 (with English translation). [cited by applicant]
Chinese Office Action dated Nov. 25, 2022 issued in Chinese Patent Application No. 202080043367.5 (with English translation). [cited by applicant]
Japanese Office Action dated Feb. 7, 2023 issued in Japanese Patent Application No. 2021-574892 (with English translation). [cited by applicant]
Japanese Office Action dated Dec. 19, 2024 issued in Japanese Patent Application No. 2021-574892 (English translation). [cited by applicant]
Extended European Search Report dated Mar. 1, 2023 issued in European Patent Application No. 20921609.2. [cited by applicant]
Communication dated Mar. 21, 2023 issued in European Patent Application No. 20921609.2. [cited by applicant]
International Search Report and Written Opinion dated Nov. 24, 2020 issued in International Patent Application No. PCT/KR2020/002630 (with English translation). [cited by applicant]
Korean Notice of Allowance dated May 6, 2020 issued in Korean Patent Application No. 10-2018-0147371. [cited by applicant]
Korean Office Action dated Dec. 20, 20219 issued in Korean Patent Application No. 10-2018-0147371. [cited by applicant]