IP Library Granted Patent US 10,988,821
Granted Patent B2
US 10,988,821 · App. 15/765,679 · Granted Apr 27, 2021

Wire rod having excellent cold forgeability and manufacturing method therefor

Inventors: Dong-Jun Mun (Pohang-si, KR); Geun-Soo Ryu (Pohang-si, KR); Sang-Yoon Lee (Pohang-si, KR); Jae-Seung Lee (Pohang-si, KR)
Assignee: POSCO
C21D8/065C21D8/06C21D9/52C21D9/525C22C38/001C22C38/02C22C38/04C22C38/06C22C38/18C22C38/24C22C38/26C22C38/28C21D2211/005C21D2211/009
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Quick Facts
Patent No.
US 10,988,821
App. No.
15/765,679
Granted
Apr 27, 2021
Kind
B2
Abstract

Disclosed are a wire rod and a manufacturing method therefor. The wire rod comprises in percentage by weight: 0.02 to 0.15% of C; 0.05 to 0.3% of Si; 0.5 to 1.2% of Mn; 0.3 to 0.9% of Cr; 0.02% or less of P; 0.02% or less of S; 0.01 to 0.05% of sol. Al; 0.01% or less of N; Fe as the remainder; and unavoidable impurities, wherein the wire rod satisfies following formulas 1 and 2, wherein, when the hardness of the wire rod measured in 1/2d position and in 1/4d position in the diameter direction of the wire rod is Hv, 1/2d (Hv) and Hv, 1/4d (Hv), respectively (here, d is the diameter of the wire). ( Hv, 1/2d +Hv, 1/4d )/2≤150  [Formula 1] Hv, 1/2d /Hv, 1/4d ≤1.2  [Formula 2]

Claims (35)

1. A wire rod, comprising:

carbon (C): 0.02 wt % to 0.14 wt %, silicon (Si): 0.05 wt % to 0.3 wt %, manganese (Mn): 0.5 wt % to 1.2 wt %, chrome (Cr): 0.3 wt % to 0.9 wt %, phosphorus (P): 0.02 wt % or less, sulfur (S): 0.02 wt % or less, soluble aluminum (sol. Al): 0.01 wt % to 0.05 wt %, nitrogen (N): 0.008 wt % or less, iron (Fe) as a remainder, and unavoidable impurities,

wherein, the wire rod satisfies Formula 1 and Formula 2, when the hardness of the wire rod, measured in a 1/2d position and in a 1/4d position in the diameter direction of the wire rod, are Hv, 1/2 (HV) and Hv, 1/4 (HV), respectively,

( Hv 1/2d +Hv, 1/4d )/2≤150  [Formula 1]

Hv, 1/2d /Hv 1/4d ≤1.2  [Formula 2]

where d is the diameter of the wire.

2. The wire rod of claim 1 , wherein the unavoidable impurities include titanium (Ti), niobium (Nb), and vanadium (V), and are suppressed to 0.02 wt % or less of Ti, as well as 0.06 wt % or less of Nb and V in total.

3. The wire rod of claim 1 , wherein a carbon equivalent (Ceq) defined by Equation 1 is 0.23 or more and 0.33 or less,

Ceq =[C]+[Si]/9+[Mn]/5+[Cr]/12  [Equation 1]

where each of [C], [Si], [Mn], and [Cr] is the content (%) of a corresponding element.

4. The wire rod of claim 1 , wherein the wire rod satisfies Formula 3,

1.2≤[Mn]/[Cr]≤1.8  [Formula 3]

where each of [Mn] and [Cr] is the content (%) of a corresponding element.

5. The wire rod of claim 1 , wherein the wire rod satisfies Formula 4,

9.33[C]+0.97[Mn]+0.51[Cr]+0.26[Nb]+0.66[V]≤2.1  [Formula 4]

where each of [C], [Mn], [Cr], [Nb], and [V] is the content (%) of a corresponding element.

6. The wire rod of claim 1 , including ferrite and pearlite, as a microstructure.

7. The wire rod of claim 1 , including ferrite of 70 area % or more (excluding 100 area %) and pearlite of 30 area % or less (excluding 0 area %), as a microstructure.

8. The wire rod of claim 6 , wherein an average grain size of the ferrite is 10 μm to 30 μm.

9. The wire rod of claim 1 , wherein, during wire drawing in a drawing amount (D) of 5% to 25%, hardness of the wire rod after the wire drawing satisfies Formula 5,

( Hv, 1 −10≤( Hv, D,1/2d +Hv, D,1/4d )/2≤ Hv, 1 +10  [Formula 5]

where, Hv, 1 is “(Hv, 1/2D +Hv, 1/4D )/2+85.45×{1−exp (−D/11.41)}”, and Hv, D,1/2d and Hv, D,1/4d are hardness of the wire rod, measured in a 1/2d position and a 1/4d position in the diameter direction of the wire rod after the wire drawing, respectively.

10. A method for manufacturing a wire rod, comprising:

heating a billet, including carbon (C): 0.02 wt % to 0.14 wt %; silicon (Si): 0.05 wt % to 0.3 wt %; manganese (Mn): 0.5 wt % to 1.2 wt %; chrome (Cr): 0.3 wt % to 0.9 wt %; phosphorus (p): 0.02 wt % or less; sulfur (S): 0.02 wt % or less; soluble aluminum (sol. Al): 0.01 wt % to 0.05 wt %; nitrogen (N): 0.008 wt % or less; iron (Fe) as a remainder and unavoidable impurities, in which a carbon equivalent (Ceq) defined by Equation 1 is 0.23 or more and 0.33 or less, and which satisfies Formula 3 and Formula 4;

obtaining the wire rod by hot-rolling the billet having been heated under the conditions of a finish rolling temperature of 900° C. to 1000° C.; and

cooling, after winding the wire rod,

Ceq =[C]+[Si]/9+[Mn]/5+[Cr]/12  [Equation 1]

1.2≤[Mn]/[Cr]≤1.8  [Formula 3]

9.33[C]+0.97[Mn]+0.51[Cr]+0.26[Nb]+0.66[V]≤2.1  [Formula 4]

where each of [C], [Si], [Mn], [Cr], [Nb], and [V] is the content (%) of a corresponding element, and

wherein, during the winding, a winding temperature is 800° C. to 900° C.

11. The method for manufacturing a wire rod of claim 10 , wherein the unavoidable impurities include titanium (Ti), niobium (Nb), and vanadium (V), and are suppressed to 0.02 wt % or less of Ti, as well as 0.06 wt % or less of Nb and V in total.

12. The method for manufacturing a wire rod of claim 10 , wherein, during the heating, a heating temperature is 1050° C. to 1250° C.

13. The method for manufacturing a wire rod of claim 10 , wherein, during the cooling, a cooling rate is 0.1° C./sec to 1° C./sec.

14. The wire rod of claim 7 , wherein an average grain size of the ferrite is 10 μm to 30 μm.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061778/0785 →
CHANGE OF NAME Recorded Sep 28, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061561/0923 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 3, 2018
From: MUN, DONG-JUN; RYU, GEUN-SOO; LEE, SANG-YOON; LEE, JAE-SEUNG
To: POSCO
Reel/Frame 045427/0866 →
Priority Claims (1)
KR 10-2015-0158817 · Nov 12, 2015 · national
Continuity (1)
Related Publication 20190085422A1 · Mar 21, 2019
Cited By (1)
US 12,637,747