IP Library Granted Patent US 12,325,635
Granted Patent B2
US 12,325,635 · App. 17/625,511 · Granted Jun 10, 2025

Metallic and magnetic carbon material

Inventors: Puru Jena (Richmond, VA); Hong Fang (Camden, NJ); Joel Therrien (Boston, MA)
Assignee: Virginia Commonwealth University
C01B32/05B01J23/50B01J23/52B01J23/72B01J23/755B01J27/24B01J37/0215C23C16/26C01P2006/40C01P2006/42
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Quick Facts
Patent No.
US 12,325,635
App. No.
17/625,511
Granted
Jun 10, 2025
Kind
B2
Abstract

A 3-dimensional crystalline carbon material that is magnetic and metallic under ambient conditions is provided. The material, denominated U-carbon, has been synthesized using the molecular precursor, 3, 3-dimethyl-1-butene (C 6 H 12 ). Depending on the atomic connections made between the carbon atoms of the material, U-Carbon forms structures that exhibit semiconducting and nonmagnetic to metallic and ferromagnetic behaviors. The use of selected molecular precursors (such as 3, 3-dimethyl-1-butene C 6 H 12 ) that support crystal growth based on clustered rather than individual atoms is a paradigm shift in materials development. Rationally designed metastable materials with desirable properties, including U-Carbon, can have many scientific and technological applications.

Claims (8)

1. A carbon material formed from connecting buckled sp2-sp3 hybrid layers with each layer consisting of an equal number of 4 and 6 membered carbon rings, wherein each buckled sp2-sp3 hybrid layer has three equally separated sublayers of carbon atoms containing two exterior sp2 bonded carbon sublayers and one interior sp3 bonded carbon sublayer.

2. The carbon material of claim 1 , wherein the carbon material is magnetic.

3. The carbon material of claim 1 , wherein the carbon material is electrically conductive.

4. The carbon material of claim 1 , in the form of a sheet, flake, particle, or granule.

5. The carbon material of claim 1 , configured as a magnet, ferromagnet, or magnetic dopant.

6. A composite material containing the carbon material of claim 1 .

7. An electronic or magnetic component or appliance containing the carbon material of claim 1 .

8. A device or system comprising the electronic or magnetic component or appliance of claim 7 .

Assignments (1)
CONFIRMATORY LICENSE Recorded Jun 25, 2024
From: VIRGINIA COMMONWEALTH UNIVERSITY
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 067833/0557 →
Continuity (4)
Provisional Application 62979975 · Feb 21, 2020
Provisional Application 62896827 · Sep 6, 2019
Provisional Application 62872267 · Jul 10, 2019
Related Publication 20220274834A1 · Sep 1, 2022
References Cited (4)
US 4845533A · Pryor · 1989 [cited by examiner]
US 20070158618A1 · Song · 2007 [cited by examiner]
US 20080260968A1 · Kim · 2008 [cited by examiner]
Kenneth M. Merz, Jr., Roald Hoffmann, and Alexandru T. Balaban, 3,4-Connected Carbon Nets: Through-Space and Through-Bond Interactions in the Solid State, Jan. 20, 1987, J. Am. Chem. Soc., 109, 6742-6751 (Year: 1987). [cited by examiner]