Polypropylene film with improved slip performance
The invention is related to film comprising a polypropylene composition showing improved coefficiency of friction as well as optical properties.
1 . A process for preparing a film, comprising the steps of:
i) preparing a propylene homopolymer (HPP) having a melting temperature (Tm) measured by differential scanning calorimetry (DSC) according to ISO 11357 in a range from 152 to 162° C., a xylene cold soluble fraction (XCS) determined at 25° C. according to ISO 16152 of equal or below 1.5 wt % and a content of 2,1 erythro regiodefects as determined from 13 C-NMR spectroscopy in a range from 0.01 to 1.00 mol % in a multistage process wherein a loop reactor is followed by a gas phase reactor, in the presence of a catalyst system comprising a cocatalyst comprising a compound of a group 13 metal, and a metallocene catalyst complex of formula (I):
wherein
Mt is Hf or Zr;
each X is a sigma-ligand,
each R 1 independently is the same or may be different and is a CH 2 —R 7 group, where R 7 is H or linear or branched C 1-6 -alkyl group, C 3-8 cycloalkyl group, C 6-10 aryl group,
each R 2 is independently a —CH═, —CY═, —CH2-, —CHY— or —CY2-group, wherein Y is a C 1-10 hydrocarbyl group and where n is 2-6,
each R 3 and R 4 is independently the same or may be different and is hydrogen, a linear or branched C 1 -C 6 -alkyl group, an OY group or a C 7-20 arylalkyl, C 7-20 alkylaryl group or C 6-20 aryl group, whereby at least one R 3 per phenyl group and at least one R 4 is not hydrogen, and optionally two adjacent R 3 or R 4 groups may be part of a ring including the phenyl carbons to which they are bonded,
R 5 is a linear or branched C 1 -C 6 -alkyl group, C 7-20 arylalkyl, C 7-20 alkylaryl group or C 6 -C 20 -aryl group,
R 6 is a C (R 8 ) 3 group, where R 8 is a linear or branched C 1 -C 6 alkyl group,
each R is independently a C 1 -C 20 -hydrocarbyl, C 6 -C 20 -aryl, C 7 -C 20 -arylalkyl or C 7 -C 20 -alkylaryl,
ii) forming the propylene homopolymer (HPP) obtained in step i into a film together with 0.1-0.4 wt % of a slip agent, and 0.0-0.5 wt % of an anti-block agent.
2 . The process according to claim 1 , wherein the film is a non-oriented cast or blown film.
3 . The process according to claim 1 , wherein the propylene homopolymer (HPP) has a melt flow rate MFR2 (230° C., 2.16 kg) determined according to ISO 1133 in a range of 4.0-20.0 g/10 min.
4 . The process according to claim 1 , wherein the propylene homopolymer (HPP) has a molecular weight distribution (MWD) of equal or below 4.0.
5 . The process according to claim 1 , wherein the propylene homopolymer (HPP) has 2,1-erythro regiodefects in a range from 0.20 to 0.80 mol %, determined by 13 C-NMR spectroscopy.
6 . The process according to claim 1 , wherein the propylene homopolymer (HPP) has an isotactic triad fraction (mm) determined from 13 C-NMR spectroscopy of at least 97.5%.
7 . The process according to claim 1 , wherein a polypropylene composition comprising the propylene homopolymer (HPP), the slip agent, and the anti-block agent has a coefficient of friction (CoF) determined according to ISO 829 fulfilling the equation (I):
CoF<0.658 days −0.189 (I)
when cast into a film with a thickness of 50 micrometers.
8 . The process according to claim 1 , wherein a polypropylene composition comprising the propylene homopolymer (HPP), the slip agent, and the anti-block agent has a haze of not more than 2.5%, determined according to ASTM D 1003, when cast into a film with a thickness of 50 micrometers.
9 . The process according to claim 1 , wherein the propylene homopolymer (HPP) is prepared in the presence of a metallocene catalyst complex, wherein:
Mt is Zr,
each X is independently a hydrogen atom, a halogen atom, C 1-6 alkoxy group or an R′ group, where R′ is a C 1-6 alkyl, phenyl or benzyl group,
each R is independently a C 1 -C 20 -hydrocarbyl, C 6 -C 20 -aryl, C 7 -C 20 -arylalkyl or C 7 -C 20 -alkylaryl,
each R 1 independently is the same or may be different and is a CH 2 —R 7 group, where R 7 is H or linear or branched C 1-6 -alkyl group, C 6-10 aryl group,
each R 2 is independently a —CH═, —CY═, —CH 2 -, —CHY-or-CY2-group, wherein Y is a C 1-4 hydrocarbyl group and where n is 3-4,
each R 3 and R 4 is independently the same or may be different and is hydrogen, a linear or branched C 1 -C 6 -alkyl group or a C 6-20 aryl group, whereby at least one R 3 per phenyl group and at least one R 4 is not hydrogen,
R 5 is a linear or branched C 1 -C 6 alkyl group or C 6-20 aryl group and
R 6 is a C (R 8 ) 3 group, where R 8 is a linear or branched C 1 -C 4 alkyl group.
10 . The process according to claim 1 , wherein the propylene homopolymer (HPP) is prepared in the presence of a metallocene catalyst complex, wherein:
Mt is Zr,
each X is independently a chlorine, benzyl or a methyl group,
each R is independently a C 1 -C 10 -hydrocarbyl or C 6 -C 10 -aryl group,
both R 1 are the same and are a CH 2 —R 7 group, where R 7 is H or linear or branched C 1 -C 6 -alkyl group,
each R 2 is independently a —CH═, —CY═, —CH 2 —, —CHY— or —CY 2 — group, wherein Y is a C 1-4 hydrocarbyl group and where n is 3-4,
each R 3 and R 4 is independently the same or may be different and is hydrogen, a linear or branched C 1 -C 6 -alkyl group or C 6-20 aryl groups, whereby at least one R 3 per phenyl group and at least one R 4 is not hydrogen,
R 5 is a linear or branched C 1 -C 6 alkyl group or C 6-20 aryl group and
R 6 is a C (R 8 ) 3 group, R 8 is the same and is a C 1 -C 2 -alkyl group.
11 . The process according to claim 1 , wherein the catalyst system comprises as cocatalyst alumoxane, combinations of alumoxane with Al-alkyls, boron or borate cocatalysts, or combination of alumoxanes with boron-based cocatalysts.