Electrode assembly with insulation film formed on tab, manufacturing method thereof, and lithium secondary battery comprising the same
Disclosed are an electrode assembly, a manufacturing method thereof, and a lithium secondary battery comprising the same. The electrode assembly for the lithium secondary battery includes an electrode, a separator, and an opposing electrode, wherein the electrode has a structure in which an electrode active material layer is formed on an electrode current collector including an electrode current collection substrate and a tab extending from the electrode current collection substrate, an insulation film is formed on some or all of at least one surface of the tab, and the insulation film is an organic-inorganic hybrid film including inorganic particles and a binder polymer.
1. An electrode assembly for a lithium secondary battery comprising:
an electrode, a separator, and an opposing electrode,
wherein the electrode comprises a structure in which an electrode active material layer is formed on an electrode current collector,
wherein the electrode current collector comprises an electrode current collection substrate and a tab extending from the electrode current collection substrate,
wherein an insulation film is formed on some or all of at least one surface of the tab extending from the electrode current collection substrate, and
wherein the insulation film is an organic-inorganic hybrid film comprising inorganic particles and a binder polymer.
2. The electrode assembly of claim 1 , wherein:
the electrode and the opposing electrode face each other, and
the insulation film is formed on the tab of the electrode in a direction facing the opposing electrode.
3. The electrode assembly of claim 1 , wherein:
the electrode and the opposing electrode face each other, and
the insulation film is further formed on the tab of the opposing electrode in a direction facing the electrode.
4. The electrode assembly of claim 1 , wherein:
the insulation film is formed on the whole of both sides of the tab.
5. The electrode assembly of claim 1 , wherein:
the binder polymer is at least one selected from the group consisting of polyvinylidene fluorideco-hexafluoropropylene, polyvinylidene fluoride-cotrichloroethylene, polymethylmethacrylate, polyacrylonitrile, polyvinylpyrrolidone, polyvinylacetate, polyethylene-co-vinyl acetate, polyimide, polyethylene oxide, cellulose acetate, cellulose acetate butyrate, cellulose acetate propionate, cyanoethylpullulan, cyanoethylpolyvinylalcohol, cyanoethylcellulose, cyanoethylsucrose, pullulan, carboxyl methyl cellulose, and polyvinylalcohol.
6. The electrode assembly of claim 1 , wherein:
the inorganic particles are at least one selected from the group consisting of (a) an inorganic particle having a dielectric constant of 1 or more, (b) an inorganic particle having piezoelectricity, (c) thermal conductive inorganic particles, and (d) an inorganic particle having a lithium-ion transfer capability.
7. The electrode assembly of claim 1 , wherein:
the content of the inorganic particles is 1 to 99 wt % per 100 wt % of the mixture of the inorganic particles and the binder polymer.
8. The electrode assembly of claim 1 , wherein:
the insulation film is formed in a thickness of 0.1 μm to 100 μm.
9. The electrode assembly of claim 1 , wherein:
the electrode is a positive electrode and the opposing electrode is a negative electrode.
10. The electrode assembly of claim 1 , wherein:
the electrode is a negative electrode and the opposing electrode is a positive electrode.
11. The electrode assembly of claim 1 , wherein:
the separator is a safety reinforced separator.
12. A method for manufacturing the electrode assembly according to claim 1 , comprising the steps of:
(a) preparing an electrode assembly comprising an electrode, a separator, and an opposing electrode, wherein an electrode active material layer is formed on an electrode current collector of the electrode, wherein the electrode current collector comprises an electrode current collection substrate and a tab extending from the electrode current collection substrate;
(b) preparing a laminate by coating and drying an organic-inorganic hybrid composition including inorganic particles and a binder polymer on a release film, thereby laminating an organic-inorganic hybrid film on the release film;
(c) forming an insulation film on some or all of at least one surface of the tab of the electrode by laminating the organic-inorganic hybrid film after removing the release film from the laminate or directly transferring the organic-inorganic hybrid film from the laminate; and
(d) manufacturing the electrode assembly with a separator interposed between the electrode of which the insulation film is formed on at least one surface of the tab and the opposing electrode.
13. The manufacturing method of the electrode assembly of claim 12 , wherein:
the electrode and the opposing electrode face each other, and
the insulation film is formed on the tab of the electrode facing the opposing electrode.
14. The manufacturing method of the electrode assembly of claim 13 , wherein:
the electrode and the opposing electrode face each other, and
the insulation film is further formed on the tab of the opposing electrode facing the electrode.
15. A lithium secondary battery comprising:
the electrode assembly according to claim 1 ,
and
an electrolyte.