R-T-B SERIES PERMANENT MAGNET MATERIAL, RAW MATERIAL COMPOSITION, PREPARATION METHOD AND APPLICATION
An R-T-B series permanent magnet material, a raw material composition, a preparation method, and an application. An R-T-B series permanent magnet material I comprises R, T and X, which satisfy the following relational formula: (1) the atomic ratio of (Fe+Co)/B is 12.5-13.5; (2) the atomic ratio of B/X is 2.7-4.1; and X is one or more among Al, Ga and Cu. The permanent magnet material I comprises R 2 T 14 B primary phase crystalline particles, and a secondary grain boundary phase and a rare earth rich phase between two adjacent R 2 T 14 B primary phase crystalline particles. The secondary grain boundary phase and rare earth rich phase comprise phases composed of R 6 T 13 X. R 6 T 13 X phases are formed in the R-T-B series permanent magnet material I, so that Hcj and mechanical performance can be synchronously improved.
1 . R-T-B series permanent magnet material I, wherein R-T-B series permanent magnet material I comprises R, T and X;
R is a rare earth element including at least Nd, and R includes RH, wherein RH is a heavy rare earth element, and RH includes at least one or more of Dy and Tb;
T includes at least Fe;
X is one or more of Al, Ga and Cu, and X necessarily includes Al;
R-T-B series permanent magnet material I satisfies the following relational expressions:
(1) an atomic ratio of (Fe+Co)/B of 12.5-13.5;
(2) an atomic ratio of B/X of 2.7-4.1;
R-T-B series permanent magnet material I comprises R 2 T 14 B main phase crystalline grains, a two-grain boundary phase between two adjacent R 2 T 14 B main phase crystalline grains, and a rare-earth-rich phase, wherein the two-grain boundary phase and the rare-earth-rich phase comprise a phase composed of R 6 T 13 X.
2 . R-T-B series permanent magnet material I according to claim 1 , wherein R-T-B series permanent magnet material I comprises, by mass percentage,
31.0-32.5 wt. % of R, and R includes RH,
0.20-0.50 wt. % of Cu,
0.40-0.80 wt. % of Al,
0-0.30 wt. % of Ga,
0.10-0.25 wt. % of Nb,
0.5-2.0 wt. % of Co,
0.97-1.03 wt. % of B,
wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
R is a rare earth element including at least Nd, RH is a heavy rare earth element, and RH includes at least one or more of Dy and Tb.
3 . R-T-B series permanent magnet material II, wherein R-T-B series permanent magnet material II comprises R, T and X;
R is a rare earth element including at least Nd, and R includes RH, wherein RH is a heavy rare earth element;
RH includes at least one or more of Dy and Tb;
T includes at least Fe;
X is one or more of Al, Ga and Cu, and X necessarily includes Al;
R-T-B series permanent magnet material II satisfies the following relational expressions:
(1) au atomic ratio of (Fe+Co)/B of 12.5-13.7;
(2) an atomic ratio of B/X of 2.8-4.0.
4 . R-T-B series permanent magnet material II according to claim 3 , wherein R-T-B series permanent magnet material II comprises, by mass percentage, the following components:
30.5-32 wt. % of R, and R includes RH,
0.20-0.50 wt. % of Cu,
0.40-0.80 wt. % of Al,
0-0.30 wt. % of Ga,
0.10-0.25 wt. % of Nb,
0.5-2.0 wt. % of Co, and
0.97-1.03 wt. % of B,
wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
R is a rare earth element including at least Nd;
RH is a heavy rare earth element, and RH includes at least one or more of Dy and Tb;
the balance is Fe and inevitable impurities.
5 . A raw material composition for R-T-B series permanent magnet material II, comprising, by mass percentage, the following components:
30.5-32 wt. % of R, and R includes RH,
0.20-0.50 wt. % of Cu,
0.40-0.80 wt. % of Al,
0-0.30 wt.% of Ga,
0.10-0.25 wt. % of Nb,
0.5-2.0 wt. % of Co, and
0.97-1.03 wt. % of B,
wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
R is a rare earth element including at least Nd;
RH is a heavy rare earth element, and RH includes at least one or more of Dy and Tb;
the balance is Fe and inevitable impurities.
6 . A preparation method for R-T-B series permanent magnet material II, comprising the following step: subjecting a melt of the raw material composition for R-T-B series permanent magnet material II according to claim 5 to casting, crushing, pulverization forming, and sintering.
7 . R-T-B series permanent magnet material II prepared by the preparation method according to claim 6 .
8 . A preparation method for R-T-B series permanent magnet material I, comprising subjecting the R-T-B series per lar ent magnet material II according to claim 3 to a grain boundary diffusion treatment.
9 . R-T-B series permanent magnet material I prepared by the preparation method according to claim 8 .
10 . An application of n R-T-B series permanent magnet material as an electronic component, wherein
the R-T-B series permanent magnet material is R-T-B series permanent magnet material according to claim 1 .
11 . The R-T-B series permanent magnet material I according to claim 1 , wherein, T includes Fe and Co;
or, the atomic ratio of (Fe+Co)/B is 12.8-13.39;
or, the atomic ratio of B/X is 2.8-4.
12 . The R-T-B series permanent magnet material I according to claim 1 , wherein, in the R 6 -T 13 -X phase, X is Al and Cu.
13 . The R-T-B series permanent magnet material I according to claim 2 , wherein, R further includes the element Pr;
or, the range of the content of R is 31.5-32.5 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of RH is 0.8-2.2 wt.%, wherein wt.% refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of Nb is 0.1-0.2 wt. % or 0.12-0.25 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of Co is 0.5-1.5 wt. % or 1-2 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of B is 0.97-1 wt. % or 0.99-1.03 wt. %, wherein wt.% refers to the mass percentage relative to R-T-B series permanent magnet material I.
14 . The R-T-B series permanent magnet material I according to claim 2 , wherein, the range of the content of Cu is 0.2-0.4 wt. % or 0.3-0.5 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of Al is 0.4-0.6 wt. % or 0.5-0.8 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I;
or, the range of the content of Ga is 0 wt. % or (13 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material I.
15 . R-T-B series permanent magnet material II according to claim 3 , wherein, T includes Fe and Co;
or, the atomic ratio of (Fe+Co)/B is 12.9-13;
or, the atomic ratio of B/X is 2.9-3.9.
16 . R-T-B series permanent magnet material II according to claim 4 , wherein, R further includes the element Pr;
or, the range of the content of R is 31-32 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of RH is 0.3-1.7 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of Nb is 0.1-0.2 wt. % or 0.12-0.25%, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of Co is 0.5-1.5 wt.% or 1-2 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of B is 0.97-1 wt. % or 0.99-1.03 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II.
17 . R-T-B series permanent magnet material II according to claim 4 , wherein, the range of the content of Cu is 0.2-0.4 wt. % or 0.3-0.5 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of Al is 0.4-0.6 wt. % or 0.5-0.8 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II;
or, the range of the content of Ga is 0 wt. % or 0.3 wt. %, wherein wt. % refers to the mass percentage relative to R-T-B series permanent magnet material II.
18 . The raw material composition for R-T-B series permanent magnet material II according to claim 5 , wherein, the range of the content of R is 31-32 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of RH is 0.3-1.7 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of Nb is 0.1-112 wt. % or 0.12-0.25 wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of Co is 0.5-1.5 wt. % or 1-2 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of B is 0.97-1 wt. % or 0.99-1.03 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II.
19 . The raw material composition for R-T-B series permanent magnet material II according to claim 5 , wherein, the range of the content of Cu is 0.2-0.4 wt. % or 0.3-0.5 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of Al is 0.4-0.6 wt. % or 0.5-0.8 wt.%, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II;
or, the range of the content of Ga is 0 wt. % or 0.3 wt. %, wherein wt. % refers to the mass percentage relative to the raw material composition for R-T-B series permanent magnet material II.
20 . An application of an R-T-B series permanent magnet material as an electronic component, wherein, the R-T-B series permanent magnet material is R-T-B series permanent magnet material II according to claim 3 .