Granted Patent B2

US 12,397,332 · App. 17/637,577 · Granted Aug 26, 2025

Inventors: Qunhui Zhou (Concord, CA); Se H. Kim (Baton Rouge, LA); Jon E. Miller (Baton Rouge, LA); Sascha J. Welz (Phoenix, AZ); Zhongxin Ge (Baton Rouge, LA)

Assignee: ALBEMARLE AMENDMENTS, LLC

B09B3/70B01J20/20

Abstract

Claims (51)

1. A process for reducing environmental availability of at least a portion of one or more environmental pollutants in a substance comprising one or more environmental pollutants, which process comprises

adding and/or applying an inorganic halide compound or an inorganic sulfide compound to said substance, wherein the inorganic halide compound comprises one or more inorganic fluorides, inorganic chlorides, inorganic bromides, and/or inorganic iodides, and

adding and/or applying a sorbent to said substance, wherein a substrate material of the sorbent is a bromine-containing carbonaceous material, and wherein the inorganic halide compound or inorganic sulfide compound and sorbent are not mixed or combined prior to application to the substance and an amount of the sorbent relative to the inorganic halide compound or inorganic sulfide compound is between 0.01 wt % and 0.1 wt %,

thereby reducing environmental availability of at least a portion of one or more environmental pollutants in the substance,

wherein the substance comprising the environmental pollutants is a solid, a liquid, or a combination of at least one solid and at least one liquid.

2. A process according to claim 1 wherein the carbonaceous material is activated carbon.

3. A process according to claim 1 wherein sorbent comprises an inorganic material, and wherein the inorganic material is selected from inorganic oxides, natural zeolites, inorganic carbonates, and clay minerals.

4. A process according to claim 1 wherein sorbent comprises an inorganic material,

and wherein the inorganic material is selected from chabazite, silica, calcium carbonate, kaolinite, and bentonite.

5. A process according to claim 1 wherein the inorganic halide compound is an inorganic chloride or an inorganic bromide or wherein the inorganic sulfide compound is an alkali metal sulfide or an alkaline earth sulfide.

6. A process according to claim 1 wherein the inorganic halide compound is an inorganic bromide and the sorbent is an activated carbon, or wherein the inorganic sulfide compound is an alkali metal sulfide and the sorbent is an activated carbon.

7. A process according to claim 6 wherein the inorganic halide compound is sodium bromide or calcium bromide, or wherein the inorganic sulfide compound is sodium sulfide.

8. A process according to claim 1 wherein the inorganic halide compound is in a solution, and is in an amount such that the halide is about 0.5 wt % to about 45 wt % calculated as bromide relative to the total weight of the solution.

9. A process according to claim 1 wherein the substance comprising said environmental pollutants is a solid, wherein adding and/or applying the inorganic halide compound or inorganic sulfide compound and the sorbent to the solid comprises:

(a) injecting an inorganic halide compound or inorganic sulfide compound and a sorbent into the solid;

(b) applying an inorganic halide compound or inorganic sulfide compound and a sorbent to a surface of the solid;

(c) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with at least a portion of a surface of the solid;

(d) adding an inorganic halide compound or inorganic sulfide compound and a sorbent to a contained solid;

(e) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with the solid;

(f) adding an inorganic halide compound or inorganic sulfide compound and a sorbent to a reactive barrier;

(g) forming a reactive barrier containing an inorganic halide compound or inorganic sulfide compound and a sorbent; and/or

(h) placing an inorganic halide compound or inorganic sulfide compound and a sorbent in a vacuum well in which the solid is treated.

10. A process according to claim 1 wherein the substance comprising said environmental pollutants is a liquid, wherein adding and/or applying the inorganic halide compound or inorganic sulfide compound and the sorbent to the liquid comprises:

(a) injecting an inorganic halide compound or inorganic sulfide compound and a sorbent into the liquid;

(b) applying an inorganic halide compound or inorganic sulfide compound and a sorbent to the surface of the liquid;

(c) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with the liquid;

(d) passing the liquid over a fixed bed comprising an inorganic halide compound or inorganic sulfide compound and a sorbent;

(e) passing the liquid through a filter comprising an inorganic halide compound or inorganic sulfide compound and a sorbent;

(f) adding an inorganic halide compound or inorganic sulfide compound and a sorbent to a contained volume of liquid; and/or

(g) contacting the liquid and an inorganic halide compound or inorganic sulfide compound, and pumping the liquid through a fixed bed or column containing a sorbent during or after the contacting with the inorganic halide compound or inorganic sulfide compound.

11. A process according to claim 1 wherein the substance comprising said environmental pollutants is a combination of at least one solid and at least one liquid, wherein adding and/or applying the inorganic halide compound or inorganic sulfide compound and the sorbent to the combination comprises:

(a) injecting an inorganic halide compound or inorganic sulfide compound and a sorbent into the combination;

(b) applying an inorganic halide compound or inorganic sulfide compound and a sorbent to a surface of the combination;

(c) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with at least a portion of a surface of the combination;

(d) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with the combination;

(e) adding an inorganic halide compound or inorganic sulfide compound and a sorbent to a contained combination;

(f) covering a surface of the substance with a layer comprising an inorganic halide compound and a sorbent or an inorganic sulfide compound and a sorbent;

(g) placing an inorganic halide compound or an inorganic sulfide compound and a sorbent into a cap;

(h) adding an inorganic halide compound or inorganic sulfide compound and a sorbent to a reactive barrier;

(i) forming a reactive barrier containing an inorganic halide compound or inorganic sulfide compound and a sorbent;

(j) placing an inorganic halide compound or inorganic sulfide compound and a sorbent within a geotextile mat; and/or

(k) placing an inorganic halide compound or inorganic sulfide compound and a sorbent in a vacuum well in which the combination is treated.

12. A process according to claim 11 wherein the adding and/or applying comprises:

(a) injecting an inorganic halide compound or inorganic sulfide compound and a sorbent into the solid;

(b) applying an inorganic halide compound or inorganic sulfide compound and a sorbent to a surface of the solid; and/or (c) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with at least a portion of a surface of the solid.

13. A process according to claim 11 wherein the combination is sediment, wherein the adding and/or applying comprises:

(a) injecting an inorganic halide compound or inorganic sulfide compound and a sorbent into the combination;

(b) applying an inorganic halide compound or inorganic sulfide compound and a sorbent to a surface of the combination;

(c) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with at least a portion of a surface of the combination; and/or

(d) combining an inorganic halide compound or inorganic sulfide compound and a sorbent with the combination.

14. A process according to claim 1 wherein the substance is soil or sediment, and wherein the inorganic halide compound is sodium bromide or calcium bromide and the sorbent is an activated carbon, or the inorganic sulfide compound is hydrogen sulfide or sodium sulfide and the sorbent is an activated carbon.

Assignments (2)

Continuity (2)

References Cited (47)