Room temperature curable resin composition, coating agent, adhesive, sealing agent, and article
The present invention is a room temperature curable resin composition comprising: as the main agent, an organic polymer in which both molecular chain terminals are sealed by a silanol group and/or a hydrolyzable silyl group; and an organic silicon compound of a specific structure having, in a molecule, an organosiloxane structure, a hydrolyzable silyl group, and a hindered amine skeleton. This resin composition produces a cured product in which the degradation over time associated with the effects of light such as UV rays can be suppressed.
1. A room temperature curable resin composition comprising
an organopolymer having both ends of the molecular chain blocked with a silanol group and/or a hydrolyzable silyl group as a main component, and
an organosilicon compound having the structural formula (3) described below:
wherein R 1 independently represents an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms or represents an unsubstituted or substituted aryl group having 6 to 10 carbon atoms, R 2 independently represents an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms or represents an unsubstituted or substituted aryl group having 6 to 10 carbon atoms, R 3 independently represents a hydrogen atom, an unsubstituted or substituted alkyl group having 1 to 20 carbon atoms, an unsubstituted or substituted alkoxy group having 1 to 20 carbon atoms, or an oxy radical (O·), R 4 independently represents a hydrogen atom or an unsubstituted or substituted alkyl group having 1 to 10 carbon atoms, each of R 5 and R 6 independently represents an unsubstituted or substituted alkyl group having 1 to 20 carbon atoms or represents an aryl group having 6 to 10 carbon atoms, A 1 independently represents an unsubstituted or substituted alkylene group having 1 to 20 carbon atoms and free of a heteroatom, A 2 independently represents a single bond or a divalent linking group containing a heteroatom, A 3 independently represents an unsubstituted or substituted alkylene group having 2 to 20 carbon atoms and free of a heteroatom, and m is a number of 1 to 3.
2. The room temperature curable resin composition of claim 1 , comprising
(A) 100 parts by weight of an organopolymer having both of the molecular chain blocked with a silanol group and/or a hydrolyzable silyl group,
(B) 0.1 to 30 parts by weight of a hydrolyzable (organo)silane compound and/or a partial hydrolytic condensate thereof,
(C) 0.001 to 20 parts by weight of a curing catalyst, and
(D) 0.01 to 10 parts by weight of an organosilicon compound having the average structural formula (3).
3. The room temperature curable resin composition of claim 2 , further comprising one or more components per 100 parts by weight of the component (A) selected from
(E) 1 to 1,000 parts by weight of a filler,
(F) 0.1 to 30 parts by weight of an adhesion promoter other than the component (B), and
(G) 1 to 1,000 parts by weight of a plasticizer.
4. A coating agent comprising the room temperature curable resin composition of claim 1 .
5. An adhesive agent comprising the room temperature curable resin composition of claim 1 .
6. A sealing agent comprising the room temperature curable resin composition of claim 1 .
7. An article comprising a coating layer including a cured product of the room temperature curable resin composition of claim 1 .
8. An article adhered and/or sealed with a cured product of the room temperature curable resin composition of claim 1 .