IP Library › Granted Patent US 12,345,417

Granted Patent B2

US 12,345,417 · App. 17/645,583 · Granted Jul 1, 2025

High temperature carbon monoxide sensor for in-situ combustion monitoring

Inventors: Xingbo Liu (Morgantown, WV); Yi Wang (Morgantown, WV); Liang Ma (Morgantown, WV); Wenyuan Li (Morgantown, WV)

Assignee: THE WEST VIRGINIA UNIVERSITY BOARD OF GOVERNORS ON BEHALF OF WEST VIRGINIA UNIVERSITY

F23N5/006 F23N5/025 G01N27/30 G01N27/4073 G01N27/4075 G01N33/004 F23N2900/05004 F23N2900/05005

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Quick Facts

Patent No.: US 12,345,417
App. No.: 17/645,583
Granted: Jul 1, 2025
Kind: B2

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Abstract

A high temperature carbon monoxide sensor for in-situ combustion monitoring is provided having a yttrium-stabilized zirconia interface based emf-measuring electrochemical sensor and a nickel oxide (NiO) first sensing electrode for targeting carbon monoxide gas at a temperature range from between about 1000 degrees Centigrade to about 1200 degrees Centigrade. A method of measuring carbon monoxide using this sensor is provided.

Claims (26)

1. A high temperature carbon monoxide sensor comprising:

2. The high temperature carbon monoxide sensor of claim 1 including a platinum second sensing electrode for targeting oxygen gas.

3. The high temperature carbon monoxide sensor of claim 1 wherein said yttrium-stabilized zirconia is in the form of a solid electrolyte.

4. A high temperature carbon monoxide sensor comprising:

(i) a housing having a first end and a second end and a middle section disposed between said first end of said housing and said second end of said housing, said housing having an external wall and an internal wall; (ii) a chamber having an internal wall and an external wall, and wherein said chamber having a first open end and a second open end and wherein the second open end of said chamber is opposite to said first open end of said chamber, and wherein said external wall of said chamber is surrounded at least in part by said internal wall of said housing; (iii) a first alumina tube having an external wall and an internal wall, said first alumina tube has a first open end and a second open end, and a middle section disposed between said first open end and said second open end of said first alumina tube, wherein at least a portion of said first alumina tube is located within said chamber; (iv) a thermocouple wherein at least a portion of said thermocouple is located within said chamber; (v) a sensor probe wherein said sensor probe is located within and is in sealed engagement with said second open end of said first alumina tube wherein said sensor probe comprises a first sensing electrode and a reference electrode, and a yttrium-stabilized zirconia interface, and optionally a second sensing electrode, wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and (b) said reference electrode, or optionally wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and said second sensing electrode and (b) said reference electrode; (v) a porous ceramic element, wherein said porous ceramic element is located within said second open end of said chamber; and (vi) wherein said first sensing electrode is in communication with a first sensing electrode wire, wherein said second sensing electrode is in communication with a second sensing electrode wire, wherein said reference electrode is in communication with a reference electrode wire, and wherein a thermocouple wire is in communication with said thermocouple, and wherein at least a portion of each of said first sensing electrode wire, said second sensing electrode wire, said thermocouple wire, and said reference electrode wire are located in an interior of said middle section of said first alumina tube.

5. The high temperature carbon monoxide sensor of claim 4 that includes an insulating layer wherein the insulating layer is in juxtaposition to at least a portion of said internal wall of said housing and at least a portion of said external wall of said chamber.

6. The high temperature carbon monoxide sensor of claim 4 wherein each of said first sensing electrode wire, said second sensing electrode wire, said thermocouple wire, and said reference electrode wire are made of a heat-resistant material.

7. The high temperature carbon monoxide sensor of claim 4 wherein said yttrium-stabilized zirconia interface is in the form of a solid electrolyte.

8. The high temperature carbon monoxide sensor of claim 4 wherein said first sensing electrode is a nickel oxide sensing electrode.

9. The high temperature carbon monoxide sensor of claim 4 wherein said second sensing electrode is a platinum sensing electrode.

10. The high temperature carbon monoxide sensor of claim 4 wherein said reference electrode is a platinum reference electrode.

11. A high temperature carbon monoxide sensor system comprising:

a high temperature carbon monoxide sensor comprising (i) a housing having a first end and a second end and a middle section disposed between said first end of said housing and said second end of said housing, said housing having an external wall and an internal wall; (ii) a chamber having an internal wall and an external wall, and wherein said chamber having a first open end and a second open end and wherein the second open end of said chamber is opposite to said first open end of said chamber, and wherein said external wall of said chamber is surrounded at least in part by said internal wall of said housing; (iii) a first alumina tube having an external wall and an internal wall, said first alumina tube has a first open end and a second open end, and a middle section disposed between said first open end and said second open end of said first alumina tube, wherein at least a portion of said first alumina tube is located within said chamber; (iv) a thermocouple wherein at least a portion of said thermocouple is located within said chamber; (v) a sensor probe wherein said sensor probe is located within and is in sealed engagement with said second open end of said first alumina tube wherein said sensor probe comprises a first sensing electrode and a reference electrode, and a yttrium-stabilized zirconia interface, and optionally a second sensing electrode, wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and (b) said reference electrode, or optionally wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and said second sensing electrode and (b) said reference electrode; (v) a porous ceramic element, wherein said porous ceramic element is located within said second open end of said chamber; and (vi) wherein said first sensing electrode is in communication with a first sensing electrode wire, wherein said second sensing electrode is in communication with a second sensing electrode wire, wherein said reference electrode is in communication with a reference electrode wire, and wherein a thermocouple wire is in communication with said thermocouple, and wherein at least a portion of each of said first sensing electrode wire, said second sensing electrode wire, said thermocouple wire, and said reference electrode wire are located in an interior of said middle section of said first alumina tube; and (B) a data collector system comprising a first voltmeter, a second voltmeter, and a thermometer, and wherein said first sensing electrode is in communication with said first voltmeter via a first sensing electrode wire, wherein said second sensing electrode is in communication with said second voltmeter via said second sensing electrode wire, wherein said reference electrode is in communication with said first voltmeter and said second voltmeter via a reference electrode wire, and wherein a thermocouple wire is in communication with said thermocouple and said thermometer, and wherein a portion of each of said first sensing electrode wire, said second sensing electrode wire, and said thermocouple wire are located in an interior of said middle section of said first alumina tube.

12. The high temperature carbon monoxide sensor system of claim 11 that includes an insulating layer wherein said insulating layer is in juxtaposition to at least a portion of said internal wall of said housing and at least a portion of said external wall of said chamber.

13. The high temperature carbon monoxide sensor system of claim 11 wherein each of said first sensing electrode wire, said second sensing electrode wire, said thermocouple wire, and said reference electrode wire are made of a heat-resistant material.

14. The high temperature carbon monoxide sensor system of claim 11 wherein said yttrium-stabilized zirconia interface is in the form of a solid electrolyte.

15. A method of measuring carbon monoxide in a combustion process environment comprising placing the high temperature carbon monoxide sensor according to claim 4 in communication with a combustion process environment and reading a result from each of the first sensing electrode and the reference electrode.

16. The method of measuring carbon monoxide of claim 15 wherein said combustion process environment is that of a power plant.

17. The method of measuring carbon monoxide of claim 15 wherein said high temperature carbon monoxide sensor includes a platinum second sensing electrode for targeting oxygen gas.

18. The method of measuring carbon monoxide of claim 15 wherein said yttrium-stabilized zirconia is in the form of a solid electrolyte.

19. A method of measuring carbon monoxide in a combustion process environment comprising using a high temperature carbon monoxide sensor system comprising

(A) a high temperature carbon monoxide sensor comprising (i) a housing having a first end and a second end and a middle section disposed between said first end of said housing and said second end of said housing, said housing having an external wall and an internal wall; (ii) a chamber having an internal wall and an external wall, and wherein said chamber having a first open end and a second open end and wherein the second open end of said chamber is opposite to said first open end of said chamber, and wherein said external wall of said chamber is surrounded at least in part by said internal wall of said housing; (iii) a first alumina tube having an external wall and an internal wall, said first alumina tube has a first open end and a second open end, and a middle section disposed between said first open end and said second open end of said first alumina tube, wherein at least a portion of said first alumina tube is located within said chamber; (iv) a thermocouple wherein at least a portion of said thermocouple is located within said chamber; (v) a sensor probe wherein said sensor probe is located within and is in sealed engagement with said second open end of said first alumina tube wherein said sensor probe comprises a first sensing electrode and a reference electrode, and a yttrium-stabilized zirconia interface, and optionally a second sensing electrode, wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and (b) said reference electrode, or optionally wherein said yttrium-stabilized zirconia interface is disposed between (a) said first sensing electrode and said second sensing electrode and (b) said reference electrode; (v) a porous ceramic element, wherein said porous ceramic element is located within said second open end of said chamber; and (vi) wherein said first sensing electrode is in communication with a first sensing electrode wire, wherein said second sensing electrode is in communication with a second sensing electrode wire, wherein said reference electrode is in communication with a reference electrode wire, and wherein a thermocouple wire is in communication with said thermocouple, and wherein at least a portion of each of said first sensing electrode wire, said second sensing electrode wire, said thermocouple wire, and said reference electrode wire are located in an interior of said middle section of said first alumina tube; and (B) a data collector system comprising a first voltmeter, a second voltmeter, and a thermometer, and wherein said first sensing electrode is in communication with said first voltmeter via a first sensing electrode wire, wherein said second sensing electrode is in communication with said second voltmeter via said second sensing electrode wire, wherein said reference electrode is in communication with said first voltmeter and said second voltmeter via a reference electrode wire, and wherein a thermocouple wire is in communication with said thermocouple and said thermometer, and wherein a portion of each of said first sensing electrode wire, said second sensing electrode wire, and said thermocouple wire are located in an interior of said middle section of said first alumina tube.

20. The method of measuring carbon monoxide in a combustion process environment of claim 19 including wherein said first sensing electrode is a nickel oxide sensing electrode, said second sensing electrode is a platinum sensing electrode, and said reference electrode is a platinum reference electrode.

21. A high temperature carbon monoxide sensor comprising a yttrium-stabilized zirconia interface based emf-measuring electrochemical sensor, a first sensing electrode for targeting carbon monoxide gas at a temperature range from between about 1000 degrees Centigrade to about 1200 degrees Centigrade, and a second sensing electrode, wherein said first sensing electrode is made of a material that is one independently selected from the group consisting essentially of (i) NiO, (ii) NiO doped with the following doping material ZrO2 and doping element stabilized zirconia such as Yttria stabilized Zirconia (YSZ), Samaria Stabilized Zirconia (SSZ), and Calcium stabilized Zirconia (CSZ), (iii) NiO doped with ceria, (iv) NiO doped with ceria that is one selected from the group consisting essentially of Gadolinium doped Ceria (GDC) and Samarium doped Ceria (SDC); (v) NiO doped with CuO, (vi) NiO doped with FeO, (vii) NiO doped with Al2O3, (viii) NiO doped with infiltrated spinel, (ix) NiO doped with NiFe spinel, (x) Ni doped with NiAl spinel, and (xi) NiO doped with platinum, and

wherein said second sensing electrode is made of a material that is selected from the group consisting essentially of (i) NiO, (ii) NiO doped with the following doping material ZrO2 and doping element stabilized zirconia such as Yttria stabilized Zirconia (YSZ), Samaria Stabilized Zirconia (SSZ), and Calcium stabilized Zirconia (CSZ), (iii) NiO doped with ceria, (iv) NiO doped with ceria that is one selected from the group consisting essentially of Gadolinium doped Ceria (GDC) and Samarium doped Ceria (SDC); (v) NiO doped with CuO, (vi) NiO doped with FeO, (vii) NiO doped with Al2O3, (viii) NiO doped with infiltrated spinel, (ix) NiO doped with NiFe spinel, (x) NiO doped with NiAl spinel, and (xi) NiO doped with platinum.

Assignments (2)

CONFIRMATORY LICENSE Recorded Jun 1, 2022

From: WEST VIRGINIA UNIVERSITY

To: UNITED STATES DEPARTMENT OF ENERGY

Reel/Frame 060063/0092 →

ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 22, 2021

From: LIU, XINGBO; WANG, YI; MA, LIANG; LI, WENYUAN

To: THE WEST VIRGINIA UNIVERSITY BOARD OF GOVERNORS ON BEHALF OF WEST VIRGINIA UNIVERSITY,

Reel/Frame 058566/0909 →

Continuity (2)

Provisional Application 63199401 · Dec 23, 2020

Related Publication 20220196239A1 · Jun 23, 2022

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