IP Library Granted Patent US 11,369,992
Granted Patent B1
US 11,369,992 · App. 17/652,707 · Granted Jun 28, 2022

Methods for preparing coating compositions for protecting oilfield operational components

Inventors: Greg Andrews (Wilmington, DE); George D. Andrews (Wilmington, DE); Jeff Capell (Wilmington, DE)
Assignee: FORMULA NO. 37, LLC
B05D7/586B05D1/02B05D1/18B05D1/38B05D3/12B05D5/00B05D7/14B05D7/16B05D7/22B05D7/222B05D7/225B05D7/26B05D7/544B05D7/546B05D7/584C08K5/5425C09D5/002C09D5/082C09D5/084C09D7/20C09D7/61C09D7/62C09D7/63C09D159/00C09D163/04C09D183/04C09D183/06C23F11/18E21B33/03E21B34/04E21B34/06E21B41/00E21B43/2607B05D2202/00B05D2202/10B05D2254/00B05D2350/60B05D2401/10B05D2504/00C08G59/022C08G59/063C08K3/11C08K3/36C08K5/541C08K5/544C08K5/5415C08K5/5435C09D163/00E21B17/02E21B43/26
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Quick Facts
Patent No.
US 11,369,992
App. No.
17/652,707
Granted
Jun 28, 2022
Kind
B1
Abstract

Coating compositions for coating an oilfield operational component, and related methods, may include in some aspects a coating composition having a trifunctional silane, a silanol, and a filler. The coating composition may be applied to a surface of the oilfield operational component that is configured to be exposed to a fluid. The coating composition may be applied to at least partially cover or coat the surface. The coating composition may be configured to chemically bond with a cured primer composition that includes an epoxy.

Claims (49)

1. A method for preparing a coating composition for application to at least a portion of an oilfield component to reduce damage induced by flow of a fluid within the oilfield component when passing therethrough, the method comprising:

providing trifunctional silane;

providing silanol fluid;

providing filler;

providing titanium dioxide;

combining the trifunctional silane, the silanol fluid, the titanium oxide, and the filler; and

mixing one or more of the trifunctional silane, the silanol fluid, the titanium dioxide, or the filler to obtain the coating composition, the coating composition being configured to form a coating layer on an inner surface of the at least a portion of the oilfield component, the coating layer configured to reduce damage induced by flow of a fluid, such that the oilfield component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, the comparison factor being indicative of a first amount of time during which a portion of the coating layer wears to a first depth divided by a second amount of time during which the inner surface of the at least a portion of the oilfield component without the coating wears to a second depth equal to the first depth.

2. The method of claim 1 , further comprising providing pigment, and mixing the pigment with one or more of the trifunctional silane, the silanol fluid, titanium dioxide, or the filler to obtain the coating composition.

3. The method of claim 1 , wherein mixing comprises mixing the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain a substantially homogeneous coating composition.

4. The method of claim 1 , further comprising providing a solvent and mixing the solvent with the coating composition, and wherein the solvent comprises at least one of xylene or mineral spirits.

5. The method of claim 1 , further comprising providing a solvent and mixing the solvent with the coating composition, and wherein the solvent comprises from about 10 parts to about 300 parts by weight for 100 parts by weight of non-solvent components.

6. The method of claim 1 , further comprising providing a catalyst and mixing the catalyst with the coating composition, and wherein catalyst comprises a tin catalyst.

7. The method of claim 1 , wherein the trifunctional silane comprises at least one of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, or alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethyl-ketoximino) silane, or vinyl tris (methyl-ethyl-ketoximino) silane.

8. The method of claim 1 , wherein the silanol fluid comprises at least one of polydialkylated siloxane, polydimethylsiloxane, or hydroxyl-terminated polydimethylsiloxane.

9. The method of claim 1 , wherein the filler comprises fumed silica, glass fiber, mica, wollastonite, kaolin, or phylosilicates.

10. The method of claim 1 , wherein the filler comprises fumed silica, and the method further comprises treating the fumed silica with a treatment agent prior to mixing the fumed silica with the coating composition.

11. The method of claim 10 , wherein the treatment agent comprises at least one of hexamethylenedisilazane, divinyltetramethylenedisilazane, chlorosilane, or polydimethylsiloxane.

12. The method of claim 1 , wherein:

the trifunctional silane comprises from about 0.01 wt. % to about 20 wt. % of the coating composition on the basis of non-solvent components;

the silanol fluid comprises from about 40 wt. % to about 99 wt. % of the coating composition on the basis of non-solvent components; and

the filler comprises from about 0.01 wt. % to about 25 wt. % of the coating composition on the basis of non-solvent components.

13. The method of claim 1 , wherein one or more of the trifunctional silane, the silanol fluid, or the filler are configured to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, fillers, or pigments.

14. The method of claim 13 , wherein the coating composition comprises an amount of ethyl T-resin units ranging from about 1.5 wt % to about 5.0 wt % of the coating composition on the basis of non-solvent components.

15. The method of claim 1 , further comprising providing pigment, and mixing the pigment with one or more of the trifunctional silane, the silanol fluid, the titanium dioxide, or the filler to obtain the coating composition, and wherein the coating composition comprises an amount of pigment ranging from about 1.0 wt % to about 5.0 wt % of the coating composition on the basis of non-solvent components.

16. The method of claim 1 , wherein the filler comprises fumed silica, and the method further comprises treating the fumed silica with a treatment agent prior to mixing the fumed silica with the coating composition.

17. The method of claim 16 , wherein the treatment agent comprises at least one of hexamethylenedisilazane, divinyltetramethylenedisilazane, chlorosilane, or polydimethylsiloxane.

18. A method for preparing a coating composition for application to at least a portion of an oilfield component to reduce damage induced by flow of a fluid through the oilfield component, the method comprising:

providing trifunctional silane;

providing silanol fluid;

providing titanium dioxide;

providing filler;

providing pigment;

combining the trifunctional silane, the silanol fluid, the titanium dioxide, the filler, and the pigment; and

mixing the pigment with one or more of the trifunctional silane, the silanol fluid, or the filler to obtain the coating composition, the coating composition being configured to form a coating layer on an inner surface of the at least a portion of the oil field component, the coating layer configured to reduce damage induced by flow of a fluid, such that the inner surface of the oilfield component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2, the comparison factor being indicative of a first amount of time during which a portion of the coating layer wears to a first depth divided by a second amount of time during which the inner surface of the at least a portion of the oilfield component without the coating wears to a second depth equal to the first depth.

19. The method of claim 18 , wherein the coating composition comprises an amount of pigment ranging from about 1.0 wt % to about 5.0 wt % of the coating composition on the basis of non-solvent components.

20. The method of claim 18 , wherein the coating composition comprises an amount of silanol fluid ranging from about 75.0 wt % to about 85.0 wt % of the coating composition on the basis of non-solvent components.

21. The method of claim 18 , wherein the filler comprises fumed silica, and the coating composition comprises an amount of fumed silica ranging from about 13.0 wt % to about 17.0 wt % of the coating composition on the basis of non-solvent components.

22. The method of claim 18 , wherein mixing comprises mixing the pigment, the trifunctional silane, the silanol fluid, the titanium dioxide, and the filler to obtain a substantially homogeneous coating composition.

23. The method of claim 18 , further comprising providing a solvent and mixing the solvent with the coating composition, and wherein the solvent comprises at least one of xylene or mineral spirits.

24. The method of claim 18 , further comprising providing a solvent and mixing the solvent with the coating composition, and wherein the solvent comprises from about 10 parts to about 300 parts by weight for 100 parts by weight of non-solvent components.

25. The method of claim 18 , further comprising providing a catalyst and mixing the catalyst with the coating composition, and wherein catalyst comprises a tin catalyst.

26. The method of claim 18 , wherein the trifunctional silane comprises at least one of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, or alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethyl-ketoximino) silane, or vinyl tris (methyl-ethyl-ketoximino) silane.

27. The method of claim 18 , wherein the silanol fluid comprises at least one of polydialkylated siloxane, polydimethylsiloxane, or hydroxyl-terminated polydimethylsiloxane.

28. The method of claim 18 , wherein the filler comprises fumed silica, glass fiber, mica, wollastonite, kaolin, or phylosilicates.

29. The method of claim 18 , wherein:

the trifunctional silane comprises from about 0.01 wt. % to about 20 wt. % of the coating composition on the basis of non-solvent components;

the silanol fluid comprises from about 40 wt. % to about 99 wt. % of the coating composition on the basis of non-solvent components; and

the filler comprises from about 0.01 wt. % to about 25 wt. % of the coating composition on the basis of non-solvent components.

30. The method of claim 18 , wherein one or more of the trifunctional silane, the silanol fluid, or the filler are configured to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, fillers, or pigments, and wherein the coating composition comprises an amount of ethyl T-resin units ranging from about 1.5 wt % to about 5.0 wt % of the coating composition on the basis of non-solvent components.

Assignments (3)
CHANGE OF NAME Recorded Jun 29, 2022
From: S+S INDUSTRIES LLC
To: S+S INDUSTRIES TECHNOLOGY LLC
Reel/Frame 060529/0987 →
CHANGE OF NAME Recorded Jun 10, 2022
From: FORMULA NO. 37, LLC
To: S+S INDUSTRIES LLC
Reel/Frame 060333/0728 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 28, 2022
From: ANDREWS, GREG; ANDREWS, GEORGE D.; CAPELL, JEFF
To: FORMULA NO. 37, LLC
Reel/Frame 059112/0565 →
Continuity (14)
Continuation 17453753 · Nov 5, 2021
Continuation 17351388 · Jun 18, 2021
Continuation 17225684 · Apr 8, 2021
Provisional Application 63008035 · Apr 10, 2020
Provisional Application 63008038 · Apr 10, 2020
Provisional Application 63008042 · Apr 10, 2020
Provisional Application 63008046 · Apr 10, 2020
Provisional Application 63008049 · Apr 10, 2020
Provisional Application 63065542 · Aug 14, 2020
Provisional Application 63065545 · Aug 14, 2020
Provisional Application 63065565 · Aug 14, 2020
Provisional Application 63065577 · Aug 14, 2020
Provisional Application 63065591 · Aug 14, 2020
Provisional Application 63198044 · Sep 25, 2020