Zeolite synthesis with alkaline earth metal
Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.
1. A method for increasing the number of Al pairs in a zeolite that is at least twice the number of aluminum pairs in a reference aluminosilicate zeolite comprising the same framework, where the reference aluminosilicate is synthesized using a reaction media comprising an alkali metal and an alkaline earth metal source, the method comprising increasing the ratio of alkaline earth metal source to the alkali metal.
2. The method of claim 1 , wherein the step of increasing the ratio of alkaline earth metal source to the alkali comprises reacting a synthesis gel comprising at least one zeolite or an alkali free alumina source, a structure directing agent, an alkaline earth metal source, and an optional silica source at a temperature of at least about 100° C. until crystals of the small pore zeolite form.
3. The method of claim 2 , wherein the at least one zeolite can be ammonium-form zeolites, hydrogen-form zeolites, or alkaline earth metal exchanged zeolites.
4. The method of claim 2 , wherein the silica source is selected from silica powders, colloid silica, or tetraalkyl silicates.
5. The method of claim 2 , wherein the synthesis gel has a ratio of SDA 2 O/SiO 2 of less than about 1.5.
6. The method of claim 2 , wherein the synthesis gel has one or more of the following molar compositional ratios:
SiO 2 /Al 2 O 3 of about 10 to about 80;
Na 2 O/Al 2 O 3 of about 0 to about 2;
M AE O/Al 2 O 3 of about 0.3 to about 1.5 (M AE can be Ca, Sr, or Ba);
SDA 2 O/Al 2 O 3 of about 0.7 to about 20;
H 2 O/Al 2 O 3 of about 300 to about 3000; and
OH − /SiO 2 of about 0.25 to about 0.5.
7. The method of claim 2 , wherein the synthesis gel is free of alkali metal.
8. The method of claim 1 , wherein the alkaline earth metal source is in salt form.
9. The method of claim 1 , wherein the alkaline earth metal source is in alkaline earth metal exchanged zeolite form.
10. The method of claim 1 , wherein the alkaline earth metal source is selected from Sr(OH) 2 , Ba(OH) 2 , Ca(OH) 2 , Sr exchanged zeolite, and Ba exchanged zeolite.