IP Library › Granted Patent US 12,319,385
Granted Patent B2
US 12,319,385 · App. 17/663,001 · Granted Jun 3, 2025

Process for establishing uniform liquid films on polar and non-polar substrates

Inventors: Leon G. Higley (Lincoln, NE); Robert K. D. Peterson (Bozeman, MT)
Assignees: Montana State University; Board of Regents of the University of Nebraska
B63B1/36B41F13/22B81B1/006F16C19/00B81B2201/058B81B2203/0323F16C2240/54
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Quick Facts
Patent No.
US 12,319,385
App. No.
17/663,001
Granted
Jun 3, 2025
Kind
B2
Abstract

Wettable structures that retain liquid layers are defined at surfaces of substrates. The wettable structures include grooves or ridges that are spaced apart by between 10 nm and 10 μm and can be defined in substrate or in a layer formed on a surface of the substrate. In typical examples, wettable structures are defined with hydrophobic materials or at hydrophobic surfaces and produce hydrophilic surfaces.

Claims (45)

1. A substrate, comprising:

a surface formed by a non-wetting material; and

a wettable structure formed at the surface, wherein the wettable structure comprises a plurality of grooves, wherein the grooves are between 1 μm and 1 nm deep and have separations between 1 nm and 2 μm.

2. The substrate of claim 1 , wherein the grooves of the plurality of grooves are periodic.

3. The substrate of claim 1 , wherein the wettable structure covers a portion of the surface of the non-wetting material leaving a non-wetting surface portion exposed.

4. The substrate of claim 3 , further comprising a surface layer situated on a surface of the substrate, wherein at least one of the non-wetting surface portion and the wetting structure are defined by the surface layer.

5. The substrate of claim 3 , further comprising a surface layer situated on a surface of the substrate, wherein the non-wetting surface portion and the wettable structure are defined by the surface layer.

6. The substrate of claim 1 , wherein the grooves are between 1 nm and 2 μm wide.

7. The substrate of claim 6 , wherein a groove width is at least as large as a groove depth.

8. The substrate of claim 1 , wherein a groove width is at least a groove depth.

9. The substrate of claim 1 , wherein the grooves have rectangular, triangular, or hemispherical cross sections.

10. A substrate, comprising:

a surface formed by a non-wetting material;

a wettable structure formed at the surface; and

a liquid layer situated at the surface, the liquid layer including a trapped layer situated within the wettable structure and a free layer situated on the trapped layer.

11. The substrate of claim 1 , wherein the surface is a biosurface, a bearing surface, a hull of ship, or a print drum.

12. The substrate of claim 1 , wherein the surface is a hydrophobic surface.

13. The substrate of claim 1 , wherein the grooves have separations of between 10 nm and 2 μm.

14. A printing device, comprising:

an ink transfer member; and

a substrate, comprising:

a surface formed by a non-wetting material; and

a wettable structure formed at the surface, wherein the wettable structure comprises a plurality of grooves, wherein the grooves are between 1 μm and 1 nm deep and have separations between 1 nm and 2 μm, wherein the substrate is situated at a surface of the ink transfer member and is operable to retain ink at the surface.

15. The printing device of claim 14 , further comprising an ink layer situated at the surface, wherein the wettable structure is defined in a hydrophobic material and the ink layer includes a polar solvent.

16. A method, comprising:

providing a substrate having:

a surface formed by a non-wetting material, and

a wettable structure formed at the surface and defining a bearing surface, wherein the wettable structure comprises a plurality of grooves, wherein the grooves are between 1 μm and 1 nm deep and have separations between 1 nm and 2 μm; and

retaining a lubricant at the bearing surface with the wettable structure.

17. The method of claim 16 , wherein the bearing surface is a surface of a hydrophobic material, and wherein the lubricant includes a polar solvent.

18. The method of claim 16 , wherein the bearing surface comprises a surface of a ball and a surface of a corresponding socket, wherein at least one of the surface of the ball and the surface of the socket is provided with the wettable structure.

19. A cooler, comprising:

a substrate having:

a surface formed by a non-wetting material;

a wettable surface that is operable to retain a liquid, wherein the surface is formed by a non-wetting material, and a wettable structure formed at the surface, wherein the wettable structure comprises a plurality of grooves, wherein the grooves are between 1 μm and 1 nm deep and have separations between 1 nm and 2 μm, and

a thermal transfer surface;

a capillary coupled to provide the liquid to the wettable surface; and

a container coupled to provide the liquid to the capillary.

20. A bearing, comprising:

a roller member;

a support surface having a recess configured to receive the roller member; and

a substrate situated at a surface of the recess, wherein the substrate includes:

a surface formed by a non-wetting material; and

a wettable structure formed at the surface, wherein the wettable structure comprises a plurality of grooves, wherein the grooves are between 1 μm and 1 nm deep and have separations between 1 nm and 2 μm and the roller member is situated against the wettable structure.

21. The substrate of claim 2 , wherein a groove width is at least as large as a groove depth.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 31, 2022
From: HIGLEY, LEON G.
To: BOARD OF REGENTS OF THE UNIVERSITY OF NEBRASKA
Reel/Frame 060058/0744 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 31, 2022
From: PETERSON, ROBERT K. D.
To: MONTANA STATE UNIVERSITY
Reel/Frame 060058/0755 →
Continuity (2)
Provisional Application 63187817 · May 12, 2021
Related Publication 20220363343A1 · Nov 17, 2022
References Cited (12)
US 8859090B2 · Angelescu et al. · 2014 [cited by applicant]
US 10876193B2 · Guo et al. · 2020 [cited by applicant]
EP 2806466B1 · 2016 [cited by applicant]
JP H11508611A · 1999 [cited by examiner]
JP 2008028164A · 2008 [cited by applicant]
Chen et al., “Experimental investigation and visualization on capillary and boiling limits of micro-grooves made by different processes,” Sensors and actuators A: Physical, 139 (1-2) pp. 78-87 (2007). [cited by applicant]
Feng et al., “Design and Creation of Superwetting/Antiwetting Surfaces,” Advanced Materials, 18 (23) pp. 3063-3078 (2006). [cited by applicant]
Murakami et al., “Wetting transition from the Cassie-Baxter state to the Wenzel state on textured polymer surfaces,” Langmuir, 30 (8) pp. 2061-2067 (2014). [cited by applicant]
Seiwert et al., “Coating of a textured solid,” Journal of Fluid Mechanics, 669 pp. 55-63 (2011). [cited by applicant]
Wilke et al., “Turning traditionally nonwetting surfaces wetting for even ultra-high surface energy liquids,” Proceedings of the National Academy of Sciences, 119 (4) 7 pp. (2022). [cited by applicant]
Xiao et al., “Modeling the Effects of Nanopatterned Surfaces on Wetting States of Droplets,” Nanoscale Research Letters, 12 (1) pp. 1-9 (2017). [cited by applicant]
International Search Report and Written Opinion dated Oct. 7, 2022, from International Patent Application No. PCT/US2022/028753, 13 pp. [cited by applicant]