IP Library Granted Patent US 12,247,279
Granted Patent B2
US 12,247,279 · App. 17/669,850 · Granted Mar 11, 2025

Method for preparing a conductive, transparent and flexible membrane

Inventors: Abdel-Aziz El Mel (Nantes, FR); Pierre-Yves Tessier (Nantes, FR); Adrien Chauvin (Pouance, FR)
Assignees: Centre national de la recherche scientifique; Nantes University
C23C14/0005C23C14/165C23C14/24C23C14/35C23C16/06C23F1/12H01B1/02H01B13/0036G06F3/0412G06F3/047G06F2203/04112H01L31/022491H01L31/1888
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Quick Facts
Patent No.
US 12,247,279
App. No.
17/669,850
Granted
Mar 11, 2025
Kind
B2
Abstract

The technique relates to a method for preparing a nanomesh metal membrane 5 transferable on a very wide variety of supports of different types and shapes comprising at least one step of de-alloying 1 a thin layer 6 of a metal alloy deposited on a substrate 7 , said method being characterized in that said thin layer 6 has a thickness less than 100 nm, and in that said de-alloying step 1 is carried out by exposing said thin layer 6 to an acid vapor in the gas phase 8 , in order to form said nanomesh metal membrane 5.

Claims (8)

1. A continuous nanomesh metal membrane, having a thickness between 1 and 20 nm, wherein the nanomesh metal membrane comprises an interconnected network of nanomesh metal domains, wherein each nanomesh metal domain has a size less than 10,000 square micrometers, wherein the nanomesh metal domains are interconnected by metallic nanoligaments and wherein the continuous nanomesh metal membrane has a first nanometric scale that defines interconnections within the nanomesh metal domains by nanoligaments and a second micrometric scale that defines interconnections between the nanomesh metal domains.

2. The continuous nanomesh metal membrane according to claim 1 , wherein the nanomesh metal domains comprises pores have nanometric sizes varying between 10 and 100 nm and wherein interconnections between the nanomesh metal domains produce micro-scale pores between the nanomesh metal domains.

3. The continuous nanomesh metal membrane according to claim 1 , wherein its transparency in the visible spectrum varies between 78% and 85%.

4. The continuous nanomesh metal membrane according to claim 1 , wherein its sheet resistance varies between 44 and 1700 Ohm/square.

5. The continuous nanomesh metal membrane according to claim 1 , comprising a first metal element chosen from the group consisting of gold, platinum, silver, zinc, nickel and copper or at least two elements chosen from the group consisting of gold, platinum, silver, zinc, nickel and copper.

6. The continuous nanomesh metal membrane according to claim 1 , having a Haacke merit factor of 2.13×10 −3 Ω −1 .

7. A method of conducting electricity comprising coating an object with the continuous nanomesh metal membrane of claim 1 , wherein the continuous nanomesh metal membrane is a transparent coating.

8. A method of detecting cracks or tears on a surface comprising coating the surface with the continuous nanomesh metal membrane of claim 1 .

Assignments (3)
MERGER Recorded Sep 7, 2023
From: UNIVERSITE DE NANTES
To: NANTES UNIVERSITE
Reel/Frame 064824/0596 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 11, 2022
From: EL MEL, ABDEL-AZIZ; TESSIER, PIERRE-YVES; CHAUVIN, ADRIEN
To: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE; UNIVERSITE DE NANTES
Reel/Frame 058994/0860 →
CHANGE OF NAME Recorded Feb 11, 2022
From: UNIVERSITE DE NANTES
To: NANTES UNIVERSITY
Reel/Frame 059122/0560 →
Priority Claims (1)
FR 17 54647 · May 24, 2017 · national
Continuity (2)
Continuation 16615387
Related Publication 20220162736A1 · May 26, 2022
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