Sintered R-T-B based magnet and method for producing the same
A method for producing a sintered R-T-B based magnet includes: preparing a sintered R-T-B based magnet work (R is a rare-earth element; and T is at least one selected from the group consisting of Fe, Co, Al, Mn and Si, and contains Fe with no exception); preparing an RL-RH-B-M based alloy; and a diffusion step of performing heat treatment while at least a portion of the RL-RH-B-M based alloy is attached to at least a portion of a surface of the sintered R-T-B based magnet work. In the RL-RH-B-M based alloy, the content of RL is 50 mass % or higher and 95 mass % or lower, the content of RH is 45 mass % or lower (including 0 mass %), the content of B is 0.1 mass % or higher and 3.0 mass % is lower; and the content of M is 4 mass % or higher and 49.9 mass % or lower.
1. A sintered R-T-B based magnet, comprising:
R (R is a rare-earth element and contains, with no exception, at least one selected from the group consisting of Nd, Pr and Ce);
T (T is at least one selected from the group consisting of Fe, Co, Al, Mn and Si, and contains Fe with no exception);
B; and
at least one selected from the group consisting of Cu, Ga, Ni, Ag, Zn and Sn,
wherein a molar ratio [T]/[B] of T with respect to B in a surface region of the sintered R-T-B based magnet is lower than a molar ratio [T]/[B] of T with respect to B in a central region of the sintered R-T-B based magnet.
2. The sintered R-T-B based magnet of claim 1 , wherein the sintered R-T-B based magnet includes a portion in which a concentration of B gradually decreases from a surface toward an interior of the sintered R-T-B based magnet.
3. The sintered R-T-B based magnet of claim 1 , wherein the molar ratio [T]/[B] of T with respect to B in the surface region of the sintered R-T-B based magnet is lower, by 0.2 or more, than the molar ratio [T]/[B] of T with respect to B in the central region of the sintered R-T-B based magnet.
4. The sintered R-T-B based magnet of claim 1 , wherein the sintered R-T-B based magnet contains Tb at a content lower than 0.5 mass % (including 0 mass %).
5. The sintered R-T-B based magnet of claim 2 , wherein the sintered R-T-B based magnet contains Tb at a content lower than 0.5 mass % (including 0 mass %).
6. The sintered R-T-B based magnet of claim 3 , wherein the sintered R-T-B based magnet contains Tb at a content lower than 0.5 mass % (including 0 mass %).