Positive electrode active material for secondary battery, manufacturing method thereof, and secondary battery including same
The present invention provides a positive electrode active material for a secondary battery, which includes a lithium transition metal oxide including nickel (Ni) and cobalt (Co), and at least one selected from the group consisting of aluminum (Al), manganese (Mn), and a combination thereof. The lithium transition metal oxide is characterized in that the content of nickel (Ni) in the total transition metal elements is 80 mol % or more, and the cation mixing ratio of Ni cations in a lithium layer in the lithium transition metal oxide structure is 1.1% or less.
1. A positive electrode active material for a secondary battery, comprising:
a lithium transition metal oxide including nickel (Ni) and cobalt (Co), and at least one selected from the group consisting of aluminum (Al), manganese (Mn), and a combination thereof, wherein
the lithium transition metal oxide is characterized in that the content of nickel (Ni) in the total transition metal elements is 80 mol % or more,
wherein the lithium transition metal oxide is represented by Formula 1 below:
Li a Ni 1-x1-y1-z1 Co x1 M 1 y1 M 2 z1 M 3 q1 O 2 [Formula 1]
in Formula 1, M 1 is at least one selected from the group consisting of Mn, Al, and a combination thereof, and M 2 and M 3 are each independently at least one selected from the group consisting of Ba, Ca, Zr, Ti, Mg, Ta, Nb, W, Mo, and a combination thereof, and 1.0≤a≤1.5, 0<x1≤0.2, 0<y1≤0.2, 0≤z1≤0.1, 0≤q1≤0.1, and 0<x1+y1+z1≤0.2; and
the cation mixing ratio of Ni cations in a lithium layer in the lithium transition metal oxide structure is less than 1%,
wherein the positive electrode active material exhibits a maximum value of heat flow of less than 200 mW determined with differential scanning calorimetry (DSC) based on 15 mg sample.
2. The positive electrode active material of claim 1 , wherein the content of lithium by-products present in the positive active material is greater than 0.3 wt % to 1 wt % or less.
3. The positive electrode active material of claim 1 , wherein the lithium transition metal oxide comprises a layered structural phase and a spinel-like structural phase.
4. The positive electrode active material of claim 1 , wherein the positive active material has a crystal density of 4.76 g/cm 3 or more.
5. The positive electrode active material of claim 1 , wherein the positive active material has a BET specific surface area of 0.5 m 2 /g or less.
6. A positive electrode for a secondary battery comprising the positive electrode active material for a secondary battery of claim 1 .
7. A lithium secondary battery comprising the positive electrode for a secondary battery of claim 6 .
8. The positive electrode active material of claim 1 , wherein the positive electrode active material exhibits a maximum peak in a temperature range of 220 to 250° C. determined with differential scanning calorimetry (DSC) based on 15 mg sample.