THERMALLY CONDUCTIVE SILICONE COMPOSITION, SHEET USING THE SAME, AND METHOD FOR PRODUCING THE SHEET
A composition of the present invention contains the following components A to C: A. a linear terminal-reactive polydimethylsiloxane; B. a thermally conductive filler including the following B1, B2, and B3 in an amount of 800 to 2500 parts by mass with respect to 100 parts by mass of the component A; and C. a curing catalyst in a catalytic amount. The component B includes the following: B1. a thermally conductive filler that has an average particle size of 0.1 to 1.0 μm and is surface treated with a surface treatment agent containing a reactive group having no unsaturated bond; B2. a thermally conductive filler that has an average particle size of 1.0 to 10 μm and is surface treated with a surface treatment agent containing a reactive group having an unsaturated bond; and B3. a thermally conductive filler that has an average particle size of 10 to 100 μm and is surface treated with the surface treatment agent containing a reactive group having no unsaturated bond or the surface treatment agent containing a reactive group having an unsaturated bond. Thus, the thermally conductive silicone composition and the sheet formed by using this composition have a high strength.
1 . A thermally conductive silicone composition comprising the following components A to C:
A. a linear organopolysiloxane having a reactive group at each end of a molecular chain;
B. a thermally conductive filler including the following B-1, B-2, and B-3 in an amount of 800 to 2500 parts by mass with respect to 100 parts by mass of the component A; and
C. a curing catalyst in a catalytic amount,
the component B including:
B-1. a thermally conductive filler that has an average particle size of 0.1 μm or more and less than 1.0 μm and is surface treated with a surface treatment agent containing a reactive group having no unsaturated bond;
B-2. a thermally conductive filler that has an average particle size of 1.0 μm or more and less than 10 μm and is surface treated with a surface treatment agent containing a reactive group having an unsaturated bond; and
B-3: a thermally conductive filler that has an average particle size of 10 μm or more and 100 μm or less and is surface treated with at least one selected from the surface treatment agent containing a reactive group having no unsaturated bond and the surface treatment agent containing a reactive group having an unsaturated bond.
2 . The thermally conductive silicone composition according to claim 1 , wherein the surface treatment agent containing a reactive group having no unsaturated bond is a silane coupling agent that does not contain an alkenyl group.
3 . The thermally conductive silicone composition according to claim 1 , wherein the surface treatment agent containing a reactive group having no unsaturated bond is a silane coupling agent that contains an alkyl group.
4 . The thermally conductive silicone composition according to claim 1 , wherein the surface treatment agent containing a reactive group having an unsaturated bond is at least one selected from the group consisting of a silane coupling agent containing an alkenyl group, a silane coupling agent containing an acrylic group, a silane coupling agent containing a methacryloxy group, a silane coupling agent containing a vinyl group, and a silane coupling agent containing a styrene group.
5 . The thermally conductive silicone composition according to claim 1 , wherein a degree of plasticity of the thermally conductive silicone composition before curing is 1 to 50.
6 . The thermally conductive silicone composition according to claim 1 , wherein a linear terminal-reactive polysiloxane of the component A is represented by the following general formula (1):
X[Si(CH 3 ) 2 —O—] n Si(CH) 2 —Y (1)
(where a degree of polymerization n is in the range of 5 to 2100 and end groups X, Y are vinyl groups.)
7 . The thermally conductive silicone composition according to claim 1 , wherein a mixing ratio of B-1, B-2, and B-3 is determined by (total surface area of B-3+total surface area of B-2)=k×(total crass section of B-1), where k is 1 to 5.
8 . The thermally conductive silicone composition according to claim 1 , wherein the curing catalyst is an organic peroxide.
9 . The thermally conductive silicone composition according to claim 1 , wherein the thermally conductive filler of the component B contains at least one selected from the group consisting of aluminum oxide, zinc oxide, silicon oxide, silicon carbide, aluminum nitride, and boron nitride.
10 . The thermally conductive silicone composition according to claim 1 , wherein a mixing ratio of B-1, B-2, and B-3 is such that 150 to 450 parts by mass of B-1, 250 to 550 parts by mass of B-2, and 400 to 1500 parts by mass of B-3 are blended with respect to 100 parts by mass of the component A.
11 . A thermally conductive silicone sheet comprising a thermally conductive silicone composition,
the thermally conductive silicone composition comprising the following components A to C:
A. a linear organopolysiloxane having a reactive group at each end of a molecular chain;
B. a thermally conductive filler including the following B-1, B-2, and B-3 in an amount of 800 to 2500 parts by mass with respect to 100 parts by mass of the component A; and
C. a curing catalyst in a catalytic amount,
the component B including:
B-1. a thermally conductive filler that has an average particle size of 0.1 μm or more and less than 1.0 μm and is surface treated with a surface treatment agent containing a reactive group having no unsaturated bond;
B-2. a thermally conductive filler that has an average particle size of 1.0 μm or more and less than 10 μm and is surface treated with a surface treatment agent containing a reactive group having an unsaturated bond; and
B-3: a thermally conductive filler that has an average particle size of 10 μm or more and 100 μm or less and is surface treated with at least one selected from the surface treatment agent containing a reactive group having no unsaturated bond and the surface treatment agent containing a reactive group having an unsaturated bond,
wherein the thermally conductive silicone composition is molded into a sheet and the sheet is thermally cured, and
a tensile strength of the thermally conductive silicone sheet is 5 MPa or more.
12 . The thermally conductive silicone sheet according to claim 11 , wherein a thermal conductivity of the thermally conductive silicone sheet is 1 W/m·K or more.
13 . The thermally conductive silicone sheet according to claim 11 , wherein the thermally conductive silicone sheet does not include a reinforcement sheet.
14 . A method for producing a thermally conductive silicone sheet, comprising:
uniformly mixing a composition comprising the following components A to C;
molding the composition into a sheet; and
thermally curing the sheet,
A. a linear organopolysiloxane having a reactive group at each end of a molecular chain;
B. a thermally conductive filler including the following B-1, B-2, and B-3 in an amount of 800 to 2500 parts by mass with respect to 100 parts by mass of the component A; and
C. a curing catalyst in a catalytic amount,
the component B including:
B-1. a thermally conductive filler that has an average particle size of 0.1 μm or more and less than 1.0 μm and is surface treated with a surface treatment agent containing a reactive group having no unsaturated bond;
B-2. a thermally conductive filler that has an average particle size of 1.0 μm or more and less than 10 μm and is surface treated with a surface treatment agent containing a reactive group having an unsaturated bond; and
B-3: a thermally conductive filler that has an average particle size of 10 μm or more and 100 μm or less and is surface treated with at least one selected from the surface treatment agent containing a reactive group having no unsaturated bond and the surface treatment agent containing a reactive group having an unsaturated bond.
15 . The thermally conductive silicone sheet according to claim 11 , wherein the surface treatment agent containing a reactive group having no unsaturated bond is a silane coupling agent that does not contain an alkenyl group.
16 . The thermally conductive silicone sheet according to claim 11 , wherein the surface treatment agent containing a reactive group having no unsaturated bond is a silane coupling agent that contains an alkyl group.
17 . The thermally conductive silicone sheet according to claim 11 , wherein the surface treatment agent containing a reactive group having an unsaturated bond is at least one selected from the group consisting of a silane coupling agent containing an alkenyl group, a silane coupling agent containing an acrylic group, a silane coupling agent containing a methacryloxy group, a silane coupling agent containing a vinyl group, and a silane coupling agent containing a styrene group.
18 . The thermally conductive silicone sheet according to claim 11 , wherein a degree of plasticity of the thermally conductive silicone composition before curing is 1 to 50.
19 . The thermally conductive silicone sheet according to claim 11 , wherein a linear terminal-reactive polysiloxane of the component A is represented by the following general formula (1):
X[Si(CH 3 ) 2 —O—] n Si(CH 3 ) 2 —Y (1)
(where a degree of polymerization n is in the range of 5 to 2100 and end groups X, Y are vinyl groups.)
20 . The thermally conductive silicone sheet according to claim 11 , wherein a mixing ratio of B-1, B-2, and B-3 is determined by (total surface area of B-3+total surface area of B-2)=k×(total cross section of B-1), where k is 1 to 5.