Polycarbonate fibers, fiber structure and resin composite body
Provided are a polycarbonate fiber having a specific orientation degree and/or a specific birefringence value, a fiber structure as well as a resin composite body. The polycarbonate fiber may have an orientation degree (ft) of lower than 0.70, the orientation degree (ft) being defined by the following formula: ft=1−(1.0/C) 2 , C: obtained sonic velocity (km/sec), and may have a birefringence value of 0.04 or lower. The polycarbonate fiber may comprise a polycarbonate resin having a number-average molecular weight (Mn) of from 12000 to 40000 and/or a weight-average molecular weight (Mw) of from 25000 to 80000.
1 . A polycarbonate fiber having an orientation degree (ft) of lower than 0.70 and comprising a polycarbonate resin having a weight-average molecular weight (Mw) of from 45000 to 80000, wherein the orientation degree (ft) is defined by the following formula:
ft= 1−(1.0/ C ) 2
where C is sonic velocity in terms of km/see of the polycarbonate fiber.
2 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has a birefringence value of 0.040 or lower.
3 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate resin having has a number-average molecular weight (Mn) of from 12000 to 40000.
4 . The polycarbonate fiber according to claim 3 , wherein the polycarbonate resin has a molecular weight distribution (Mw/Mn) of from 2.0 to 4.0.
5 . A polycarbonate fiber having a birefringence value of 0.040 or lower and comprising a polycarbonate resin having a weight-average molecular weight (Mw) of from 45000 to 80000.
6 . The polycarbonate fiber according to claim 5 , wherein the polycarbonate resin has a molecular weight distribution (Mw/Mn) of from 2.0 to 4.0.
7 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has an elastic modulus of 30 cN/dtex or lower.
8 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has a coefficient of variation in a fiber diameter of 15% or lower.
9 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has a single fiber fineness of 10 dtex or smaller.
10 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has an elongation at break of 20% or higher.
11 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate resin includes bisphenol-A units at a molar proportion of 65% or higher based on a total amount of monomer units in the polycarbonate resin.
12 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber comprises a phosphorus-based flame retardant.
13 . The polycarbonate fiber according to claim 12 , wherein the polycarbonate fiber comprises at least one phosphorus-based flame retardant selected from the group consisting of a phosphoric acid ester-based flame retardant, a phosphoric acid salt-based flame retardant, and a phosphazene-based flame retardant.
14 . A fiber structure, comprising the polycarbonate fiber according to claim 1 .
15 . A fiber structure, comprising the polycarbonate fiber according to claim 5 .
16 . The fiber structure according to claim 14 , wherein the fiber structure is commingled fibers, a woven fabric, or a non-woven fabric.
17 . A method for producing the polycarbonate fiber according to claim 1 , the method comprising:
melt-kneading the polycarbonate resin at a temperature of 305° C. or higher to give a molten polymer;
discharging the molten polymer through a spinning nozzle at a predetermined rate to give as-spun fibers; and
winding the as-spun fibers at a predetermined winding speed.
18 . The polycarbonate fiber according to claim 5 , wherein the polycarbonate resin has a number-average molecular weight (Mn) of from 12000 to 40000.
19 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate resin has a branching degree of less than 0.1 mol %.
20 . The polycarbonate fiber according to claim 1 , wherein the polycarbonate fiber has an elongation at break of 80% or higher.