Lithiation of electrodes for energy storage devices and method for making same
A method for lithiation of an electrode includes providing an electrode to be lithiated, providing a piece of lithium metal with predetermined weight attached to a conductive material, attaching the conductive material to a current collector of the electrode to be lithiated or to a metal tab connected to or from the electrode to be lithiated, placing the electrode to be lithiated, the piece of lithium, and the conductive material in a container, and filling the container with an electrolyte containing a lithium salt.
1. A method for lithiation of an electrode for use in an energy storage device, the method comprising:
providing a cell assembly including a negative electrode, at least one separator, and a positive electrode, the negative electrode or the positive electrode being an electrode to be lithiated, the cell assembly being disposed in and electrically connected to a cell packaging case;
providing a piece of lithium metal with predetermined weight;
electrically connecting the piece of lithium metal to an inner wall of the cell packaging case; and,
after said electrically connecting the piece of lithium metal to the inner wall of the cell packaging case, and with the cell assembly being disposed in and electrically connected to the cell packaging case, filling the cell packaging case with an electrolyte containing a lithium salt.
2. The method of claim 1 , further comprising assembling the cell assembly without a dry box or dry room.
3. The method of claim 1 , wherein the cell assembly includes a plurality of negative electrodes, a plurality of separators, and a plurality of positive electrodes.
4. The method of claim 1 , wherein said electrically connecting includes positioning the piece of lithium metal above or below the cell assembly.
5. The method of claim 4 , wherein said electrically connecting includes positioning the piece of lithium metal on a longitudinal axis of the cell assembly.
6. The method of claim 1 , wherein the electrode to be lithiated includes a current collector formed from a solid metal foil.
7. The method of claim 1 , further comprising, after lithiation of the electrode to be lithiated, removing the remains of the piece of lithium metal from the cell packaging case.
8. The method of claim 1 , wherein said electrically connecting includes attaching the piece of lithium metal to the inner wall of the cell packaging case.
9. The method of claim 1 , wherein said electrically connecting includes attaching a conductive material that is attached to the piece of lithium metal to the inner wall of the cell packaging case.
10. The method of claim 9 , further comprising, after lithiation of the electrode to be lithiated, removing the conductive material and the remains of the piece of lithium metal on the conductive material from the cell packaging case.