METHOD OF MAKING COMPOSITE POLYMER ELECTROLYTE FOR ALL SOLID-STATE LITHIUM-ION BATTERY
Making a composite solid polymer electrolyte includes mixing a slurry of lithiated ionomer and a doped inorganic ceramic electrolyte and coating the slurry onto a lithiated ionomer membrane. The lithiated ionomer can be provided by exchanging protons of an ionomer membrane with lithium ions to form a lithiated ionomer membrane and dissolving the lithiated ionomer membrane to produce the lithiated ionomer. Various composite solid polymer electrolytes can be made for use in solid-state lithium-ion batteries. Ways of making a dispersion for use in a solid-state electrolyte include lithiating an ionomer by heating and dissoluting to form the dispersion. An ionic liquid and ceramic particles can be added to the dispersion. Ways of making a reinforced solid-state electrolyte for a solid-state lithium-ion battery include infusing a porous membrane with the dispersion.
1 . A method of making a composite solid polymer electrolyte for a solid-state lithium-ion battery, comprising:
mixing a lithiated ionomer and a doped inorganic ceramic electrolyte to form a slurry; and
coating the slurry onto a lithiated ionomer membrane to produce the composite solid polymer electrolyte.
2 . The method of claim 1 , wherein the lithiated ionomer is provided by:
exchanging protons of an ionomer membrane with lithium ions to form a lithiated ionomer membrane; and
dissolving the lithiated ionomer membrane to produce the lithiated ionomer.
3 . The method of claim 2 , wherein the ionomer membrane includes protonated perfluorosulfonic acid and dissolving the lithiated ionomer membrane to produce the lithiated ionomer includes dissolving the lithiated ionomer membrane using N-methyl pyrrolidone.
4 . The method of claim 1 , wherein the doped inorganic ceramic electrolyte includes lithium lanthanum zirconium oxide doped with one of Al, Nb, and Ta.
5 . The method of claim 1 , wherein mixing the lithiated ionomer and the doped inorganic ceramic electrolyte to form the slurry includes homogenization and high pressure mixing to provide a particle size from about 0.1 microns to about 0.3 microns.
6 . The method of claim 1 , wherein coating the slurry onto the lithiated ionomer membrane to produce the composite solid polymer electrolyte includes forming a coating layer having a thickness of about 5 microns to about 15 microns.
7 . The method of claim 6 , wherein the lithiated ionomer membrane has a thickness of about 15 microns to about 30 microns.
8 . A solid-state lithium-ion battery including a composite solid polymer electrolyte made according to the method of claim 1 .
9 . A method of making a dispersion for use in a solid-state electrolyte, comprising:
lithiating an ionomer; and
heating the lithiated ionomer to dissolute the lithiated ionomer, thereby forming the dispersion for use in a solid-state electrolyte.
10 . The method of claim 9 , wherein the ionomer includes a sulfonated tetrafluoroethylene-based fluoropolymer-copolymer.
11 . The method of claim 9 , wherein heating the lithiated ionomer to dissolute the lithiated ionomer into the dispersion includes heating the lithiated ionomer under a pressure greater than atmospheric pressure.
12 . The method of claim 11 , wherein heating the lithiated ionomer under the pressure greater than atmospheric pressure includes use of an autoclave.
13 . The method of claim 9 , further comprising adding an ionic liquid to the dispersion.
14 . The method of claim 9 , further comprising adding ceramic particles to the dispersion.
15 . A method of making a reinforced solid-state electrolyte for a solid-state lithium-ion battery, comprising:
infusing a porous membrane with a dispersion made according to the method of claim 9 .
16 . The method of claim 15 , wherein the porous membrane includes expanded polytetrafluoroethylene.
17 . The method of claim 15 , wherein the dispersion further includes ceramic particles.
18 . A reinforced solid-state electrolyte for a solid-state lithium-ion battery, comprising:
a porous membrane;
ceramic particles disposed as one of
a coating on the porous membrane, and
a coating on the porous membrane and infused into the porous membrane; and
a dispersion of a dissoluted lithiated ionomer infused into the porous membrane and the coating.
19 . The reinforced solid-state electrolyte for a solid-state lithium-ion battery of claim 18 , wherein the dispersion further includes an ionic liquid.
20 . A solid-state lithium-ion battery including the reinforced solid-state electrolyte according to claim 18 .