Negative electrode and electrochemical apparatus containing same, and electronic apparatus
A negative electrode includes a negative current collector, a first negative active material layer and a second negative active material layer. The first negative active material layer is arranged on one side of a first portion of the negative current collector, and the second negative active material layers are arranged on two sides of a second portion, different from the first portion, of the negative current collector. A ratio of a weight per unit area of the first negative active material layer to a weight per unit area of the second negative active material layer on the negative current collector is 0.47 to 0.52, and a ratio of a compacted density of the first negative active material layer to a compacted density of the second negative active material layer is 0.9 to 1.1.
1. A negative electrode, comprising:
a negative current collector;
a first negative active material layer, wherein the first negative active material layer is arranged on one side of a first portion of the negative current collector; and
a second negative active material layer, wherein the second negative active material layer is arranged on two sides of a second portion of the negative current collector, wherein the second portion of the negative current collector is different from the first portion of the negative current collector;
wherein a ratio of a weight per unit area of the first negative active material layer to a weight per unit area of the second negative active material layer on the negative current collector is 0.47 to 0.52, and a ratio of a compacted density of the first negative active material layer to a compacted density of the second negative active material layer is 0.9 to 1.1;
wherein a thickness of the first negative active material layer is 40 μm to 60 μm, and a thickness of the second negative active material layer on each of the two sides of the second portion is 40 μm to 60 μm.
2. The negative electrode according to claim 1 , the weight per unit area of the first negative active material layer on the first portion is 65 g/m 2 to 130 g/m 2 , and the weight per unit area of the second negative active material layer on the second portion is 130 g/m 2 to 260 g/m 2 .
3. The negative electrode according to claim 1 , wherein the first negative active material layer and the second negative active material layer each independently comprise a silicon-based material and graphite, wherein the silicon-based material is selected from the group consisting of silicon oxide, silicon carbon, and a combination thereof.
4. The negative electrode according to claim 3 , wherein a weight of the silicon-based material in the first negative active material layer and the second negative active material layer is greater than or equal to 5% and less than 100%, based on a total weight of the silicon-based material and the graphite.
5. The negative electrode according to claim 3 , wherein a form of the silicon-based material comprises a crystalline state, an amorphous state, or a combination thereof, wherein the first negative active material layer has a particle size Dv50 of 8.0 μm to 20 μm, and the second negative active material layer has a particle size Dv50 of 8.0 μm to 20 μm.
6. The negative electrode according to claim 3 , wherein for the silicon-based material, a ratio of a peak height at a wavenumber of 500 cm −1 ±−10 cm −1 to a peak height at a wavenumber of 1350 cm −1 ±10 cm −1 in a Raman spectrum is greater than 0.
7. The negative electrode according to claim 3 , wherein the silicon-based material further comprises a carbon coating layer.
8. The negative electrode according to claim 3 , wherein the first negative active material layer and the second negative active material layer each independently comprise a binder and a conductive agent; wherein the binder comprises a material selected from the group consisting of polyacrylate, polyimide, polyamide, polyamideimide, polyvinylidene fluoride, styrene-butadiene rubber, sodium alginate, polyvinyl alcohol, polytetrafluoroethylene, polyacrylonitrile, sodium carboxymethyl cellulose, potassium carboxymethyl cellulose, and a combination thereof; and the conductive agent comprises a material selected from the group consisting of conductive carbon black, acetylene black, Ketjen black, graphene, and a combination thereof.
9. The negative electrode according to claim 8 , wherein based on a total weight of the first negative active material layer, the total weight of the silicon-based material and the graphite in the first negative active material layer is 94% to 96%, a weight of the binder is 2.8% to 5.0%, and a weight of the conductive agent is 0.4% to 1.6%; and
based on a total weight of the second negative active material layer, the total weight of the silicon-based material and the graphite in the second negative active material layer is 94% to 96%, the weight of the binder is 2.8% to 4.0%, and the weight of the conductive agent is 0.4% to 1.6%.
10. An electrochemical apparatus, comprising:
a positive electrode;
a separator; and
a negative electrode;
wherein the negative electrode comprises a negative current collector; a first negative active material layer, wherein the first negative active material layer is arranged on one side of a first portion of the negative current collector; and a second negative active material layer, wherein the second negative active material layers are arranged on two sides of a second portion of the negative current collector, wherein the second portion of the negative current collector is different from the first portion of the negative current collector,
wherein a ratio of a weight per unit area of the first negative active material layer to a weight per unit area of the second negative active material layer on the negative current collector is 0.47 to 0.52, and a ratio of a compacted density of the first negative active material layer to a compacted density of the second negative active material layer is 0.9 to 1.1;
wherein a thickness of the first negative active material layer is 40 μm to 60 μm, and a thickness of the second negative active material layer on each of the two sides of the second portion is 40 μm to 60 μm.
11. An electronic apparatus, comprising the electrochemical apparatus according to claim 10 .
12. The electrochemical apparatus according to claim 10 , the weight per unit area of the first negative active material layer on the first portion is 65 g/m 2 to 130 g/m 2 , and the weight per unit area of the second negative active material layer on the second portion is 130 g/m 2 to 260 g/m 2 .