EDIBLE BARRIER FILM COMPOSITION
Presented herein are barrier film compositions that can be used, for example, as protective coatings for plant matter (e.g., agricultural products). In some embodiments, the compositions delay moisture loss and/or decrease respiration to extend the shelf life of the plant matter. In one embodiment, the barrier film composition comprises a first component comprising a charged long chain alkyl and a second component having an opposing charge. The barrier film composition can be used to prevent or delay spoilage due to, for instance, desiccation and ripening.
1 . A barrier film composition, comprising:
a first component has a first ionic charge and a carbon chain length of C12 to C30; and
a second component has a second ionic charge opposite in sign to the first ionic charge, wherein a molar ratio of the first component to the second component is about 1:3 to about 3:1.
2 . The barrier film composition of claim 1 , wherein the first component is a phosphate.
3 . The barrier film composition of claim 2 , wherein the phosphate comprises monoalkyl phosphate, dialkyl phosphate, or combinations thereof.
4 . The barrier film composition of claim 2 , wherein the first component is a fatty acid.
5 . The barrier film composition of claim 4 , wherein the fatty acid comprises lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, oleic acid, or a combination thereof.
6 . The barrier film composition of 1, wherein the second component comprises L-arginine, L-histidine, L-lysine, guanidine, choline hydroxide, betaine, diethanolamine, glutamic acid and salts thereof, fumaric acid and salts thereof, a-ketoglutaric acid and salts, L-ornithine and salts, pyruvic acid and salts thereof, or a combination thereof.
7 . The barrier film composition of claim 1 , wherein the second component is a positively charged amino acid.
8 . The barrier film composition of claim 1 , further comprising a nonionic amphiphile having a carbon chain length of C12 to C30.
9 . The barrier film composition of claim 8 , wherein the nonionic amphiphile comprises a monoglyceride.
10 . A barrier film composition, comprising:
a first component comprises a nonionic amphiphile having a carbon chain length of C10-C20; and
a second component has an ionic charge, wherein the barrier film composition comprises about 1% w/v to about 15% w/v of the second component.
11 . The barrier film composition of claim 10 , wherein the first component comprises a monoglyceride.
12 . The barrier film composition of claim 10 , wherein the second component comprises L-arginine, L-histidine, L-lysine, guanidine, choline hydroxide, betaine, diethanolamine, glutamic acid and salts thereof, fumaric acid and salts thereof, a-ketoglutaric acid and salts, L-ornithine and salts, pyruvic acid and salts thereof, or a combination thereof.
13 . The barrier film composition of claim 10 , wherein the second component is an ionically charged amino acid.
14 . A method of making a barrier film composition, comprising:
combining a first component having a first ionic charge and a carbon chain length of C12 to C30, a second component having a second ionic charge opposite in sign to the first ionic charge, and water to form an aqueous dispersion, wherein a molar ratio of the first component to the second component is about 1:3 to about 3:1.
15 . The method of claim 14 , wherein the first component is a phosphate.
16 . The method of claim 15 , wherein the phosphate comprises monoalkyl phosphate, dialkyl phosphate, and hydrogen phosphate or combinations thereof.
17 . The method of claim 14 , wherein the first component is a fatty acid.
18 . The method of claim 17 , wherein the fatty acid comprises lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, oleic acid, or a combination thereof.
19 . The method of claim 14 , wherein the second component comprises L-arginine, L-histidine, L-lysine, guanidine, choline hydroxide, betaine, diethanolamine, glutamic acid and salts thereof, fumaric acid and salts thereof, a-ketoglutaric acid and salts, L-ornithine and salts, pyruvic acid and salts thereof, or a combination thereof.
20 . The method of claim 19 , wherein the second component is a positively charged amino acid.