Durable magnet wires and lubricating fluids for electric and hybrid vehicle applications

1. A driveline for an electric or hybrid-electric vehicle, the driveline comprising:

an electric motor including an insulated magnet wire having an insulation coating thereon with a thermal rating of about 190° C. to about 210° C., wherein the insulation coating of the magnet wire includes one or more layers and wherein the layer in contact with the lubricating and cooling fluid includes a polyamide, a polyimide, a poly(amide/imide), combinations thereof, blends thereof, or copolymers thereof;

a lubricating and cooling fluid in contact with the insulation coating of the insulated magnet wire of the electric motor;

wherein the lubricating and cooling fluid includes a detergent system providing at least about 50 ppm metal to the fluid and a base oil system including a first base oil of lubricating viscosity blended with an ester base oil, wherein the base oil system includes at least about 20 weight percent of the ester base oil, and a ratio of the metal provided by the detergent system to mol percent of ester groups in the base oil system of the lubricating and cooling fluid of about 70 or less; and

wherein the insulated magnet wire in contact with the lubricating and cooling fluid has a breakdown voltage of about 10,000 volts or higher.

2. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the magnet wire has an AWG gauge of 14 to 30.

3. The driveline for a hybrid or hybrid-electric vehicle of claim 2 , wherein the magnet wire is copper.

4. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the ester base oil includes a branched diester.

5. The driveline for a hybrid or hybrid-electric vehicle of claim 4 , wherein the branched diester is a reaction product of one or more dicarboxylic acids having an internal carbon chain length of 6 to 10 and one or more alcohols having a branched carbon chain length of 6 to 12 carbons.

6. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the ester base oil includes a monoester and/or a diester having the structure of Formula I:

wherein R 1 is a carbon chain having m−2 carbons with m being an integer from 6 to 10, R 2 and R 3 are the same or different and include C8 to C20 linear or branched alkyl chains, and n is an integer of 0 or 1.

7. The driveline for a hybrid or hybrid-electric vehicle of claim 6 , wherein n is 1 and R 2 and R 3 are the same or different and include C8 to C10 branched alkyl chains.

8. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the ester base oil is selected from a dibasic ester based on bi(6-methylheptyl)adipate; a dibasic ester based on bis(8-methylnonyl)adipate; or a linear monoester having about 16 to about 18 carbons in an acid moiety thereof and about 20 linear carbons in an alcohol moiety thereof; or combinations thereof.

9. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the detergent system includes alkali or alkaline metal salts of phenates, sulfonates, calixarates, salixrates, salicylates, carboxylic acids, sulfurized derivatives thereof, or combinations thereof.

10. The driveline for a hybrid or hybrid-electric vehicle of claim 9 , wherein the alkali or alkaline metal includes calcium, magnesium, potassium, sodium, lithium, barium, or mixtures thereof.

11. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the detergent system provides no more than 800 ppm of the metal.

12. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the first base oil of the base oil system is a mineral or synthetic base oil.

13. The driveline for a hybrid or hybrid-electric vehicle of claim 1 , wherein the first base oil of the base oil system is a polyalphaolefin.

14. A driveline for a hybrid or hybrid-electric vehicle, the driveline comprising:

an electric motor including an insulated magnet wire having an insulation coating thereon, wherein the insulation coating include a polyamide, a polyimide, a poly(amide/imide), a combination thereof, blends thereof, or copolymers thereof, wherein the insulation coating of the magnet wire has a thermal rating of about 190° C. to about 200° C.;

a lubricating and cooling fluid in contact with the coating of the insulated magnet wire of the electric motor;

wherein the lubricating and cooling fluid includes a detergent system providing at least about 50 ppm metal to the fluid and a base oil system including a first base oil of lubricating viscosity blended with an ester base oil, wherein the base oil system includes at least about 20 weight percent of the ester base oil, wherein the ester base oil is selected from a dibasic ester based on bi(6-methylheptyl)adipate; a dibasic ester based on bis(8-methylnonyl)adipate; or a linear monoester having about 16 to about 18 carbons in an acid moiety thereof and about 20 linear carbons in an alcohol moiety thereof; or combinations thereof and wherein a ratio of the metal provided by the detergent system to the mol percent of ester groups in the base oil system of about 70 or less; and

wherein the insulated magnet wire in contact with the lubricating and cooling fluid has a breakdown voltage of about 10,000 volts or higher.

15. The driveline for a hybrid or hybrid-electric vehicle of claim 14 , wherein the ester base oil includes a branched diester.

16. The driveline for a hybrid or hybrid-electric vehicle of claim 15 , wherein the branched diester is a reaction product of one or more dicarboxylic acids having an internal carbon chain length of 6 to 10 and one or more alcohols having a branched carbon chain length of 6 to 12 carbons.

17. The driveline for a hybrid or hybrid-electric vehicle of claim 14 , wherein the ester base oil includes a monoester and/or a diester having the structure of Formula I:

wherein R 1 is a carbon chain having m−2 carbons with m being an integer from 6 to 10, R 2 and R 3 are the same or different and include C8 to C20 linear or branched alkyl chains, and n is an integer of 0 or 1.

18. The driveline for a hybrid or hybrid-electric vehicle of claim 17 , wherein n is 1 and R 2 and R 3 are the same or different and include C8 to C10 branched alkyl chains.

19. The driveline for a hybrid or hybrid-electric vehicle of claim 14 , wherein the detergent system includes alkali or alkaline metal salts of phenates, sulfonates, calixarates, salixrates, salicylates, carboxylic acids, sulfurized derivatives thereof, or combinations thereof.

20. The driveline for a hybrid or hybrid-electric vehicle of claim 19 , wherein the alkali or alkaline metal includes calcium, magnesium, potassium, sodium, lithium, barium, or mixtures thereof.

21. The driveline for a hybrid or hybrid-electric vehicle of claim 14 , wherein the detergent system provides no more than 800 ppm of the metal.