Non conductive rubber hose
A non-conductive rubber hose is provided exhibiting lower conductivity compared to conventional EPDM hose, and reduced stiffness compared to conventional non-conductive thermoplastic hose. The hose is useful for applications such as in hydraulics for boom trucks, and for coolant in plasma cutting tools.
1. A method of making a non-conductive rubber hose comprising
blending a first composition comprising an ethylene propylene diene monomer (EPDM) polymer, wherein the EPDM polymer comprises low ethylene EPDM polymer having no more than 60 wt % ethylene by ASTM 3900 and high ethylene EPDM polymer having at least 69 wt % ethylene by ASTM 3900, in a weight ratio of about 10:1 to about 1:1, an electrically-resistive filler, and a silane-treated filler;
extruding the first composition onto a mandrel to form an EPDM rubber tube layer;
applying a textile braid over the EPDM tube layer to form reinforcement layer;
extruding a second composition over the reinforcement layer to form a cover layer in a green hose;
vulcanizing the green hose; and
expelling the hose from the mandrel.
2. The method according to claim 1 , wherein the first composition comprises a low ethylene EPDM polymer and a high ethylene EPDM polymer in a weight ratio of about 5:1 to about 2:1.
3. The method according to claim 1 , wherein the non-conductive rubber hose passes the dielectric strength test according to IEC 60974-7 (torch standard), and wherein the hose passes the insulation resistance and Hipot test to 30 kV peak for 1 minute.
4. The method according to claim 1 , wherein the second composition comprises one or more chloropolyethylene (CPE) polymers.
5. The method according to claim 4 , wherein the second composition comprises about 20-50 wt % of the one or more chloropolyethylene (CPE) polymers.
6. The method according to claim 1 , wherein the first composition further comprises a filler activator.
7. The method of claim 6 , wherein the filler activator is selected from the group consisting of a vinyl silane and a polysiloxane containing vinyl-, propyl- and ethoxy groups.
8. The method according to claim 6 , wherein the first composition comprises a weight ratio of the resistive filler to the filler activator from about 100:1 to about 5:1.
9. The method according to claim 6 , wherein the first composition further comprises an additional filler.
10. The method according to claim 9 , wherein the weight ratio of silane-treated filler to additional filler is from about 1:10 to about 10:1.
11. The method according to claim 1 , wherein the first composition further comprises each of a peroxide donor curative, a plasticizer, and an antioxidant.
12. The method according to claim 11 , wherein the first composition further comprises one or more of the group consisting of process aid, acid scavenger, paraffin wax, and zinc activator.
13. The rubber hose according to claim 1 , wherein the resistive filler is a carbon black filler having low surface area of from about 16-27 mg/g, or no more than 20 mg/g Iodine adsorption by ASTM D 1510.
14. The rubber hose according to claim 13 , wherein the resistive filler has medium to high structure of from 92-120 DBP cm3/100 g as determined by absorption of dibutylphthalate (DBP) by ASTM 2414-90.
15. The method according to claim 1 , wherein the reinforcement layer is a textile braid, wherein the textile is selected from the group consisting of aramid, rayon, nylon, cotton, and polyester braid.
16. The method according to claim 1 , wherein the first composition comprises
the EPDM polymer at 90-100 Pph;
the resistive filler at 30-60 Phr;
a filler activator at 0.1-10 Phr;
the silane-treated filler at 10-30 Phr; and
an additional filler at 20-80 Phr.
17. The method according to claim 1 , wherein the cured first composition exhibits one or more physical parameters selected from the group consisting of
Tensile strength of 2000-2500 psi when tested according to ASTM D412;
Percent elongation of 275-350% when tested according to ASTM D412;
100% Modulus of from 800-1000 psi when tested according to ASTM D412;
Shore A Hardness of from 75-80 pts when tested according to ASTM D2240; and
Minimum burst strength of 1200 psi or higher.